缓蚀水溶性聚苯胺的性能及聚合工艺的研究
PROPERTIES AND SYNTHESIS OF INHIBITIVE WATER-SOLUBLE POLYANILINE
摘 要
采用苯胺及其衍生物进行共聚制备缓蚀水溶性聚苯胺,用腐蚀浸泡失重法研究了苯胺衍生物比例、单体浓度、氧化剂浓度、酸度、反应温度及时间对其缓蚀性能的影响.研究结果表明,苯胺衍生物比例、单体浓度、氧化剂浓度、酸度、反应温度对缓蚀水溶性聚苯胺的缓蚀性能都具有较大的影响,而反应时间对聚合产物的缓蚀性能没有显著影响.
聚合
水溶性
缓蚀性能
Polyaniline
Synthesis
Water-soluble
Inhibitive performance
Abstract
Polyaniline was synthesized by aniline and derivative aniline.The weight lost of immersion corrosion was used to investigate the effects of the ratio of aniline to its derivative,concentration of aniline,oxidant,acidity,reaction temperature and time on the inhition of synthesized products.The ratio of aniline to its derivative,concentration of aniline,oxidant,acidity,reaction temperature showed remarkable effects on inhibition,but the reaction time had little effect.
中图分类号 TG174.41
所属栏目 试验研究
基金项目
收稿日期 2005/11/30
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引用该论文: LIN Wei-li,DU Mei-li,DENG Yu-qiang,LIU Deng-feng,WU Jian. PROPERTIES AND SYNTHESIS OF INHIBITIVE WATER-SOLUBLE POLYANILINE[J]. Corrosion & Protection, 2006, 27(9): 443～446
被引情况:
【1】程雨,吴广峰,夏刚,张会轩, "水溶性聚苯胺对铸铁的缓蚀作用",腐蚀与防护 33, 1072-1075(2012)
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参考文献
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【2】王光国.国外聚苯胺防腐涂料工业研发概况[J].全面腐蚀控制,2002,16(2):23-24.
【3】张金勇,李季,王献红,等.聚苯胺在防腐领域的应用[J].功能高分子学报,1999,12(3):350-356.
【4】苏慈生.导电聚苯胺在防腐涂料中的应用[J].现代涂料与涂装,2001,(1):1-4.
【5】Talo A,Passiniemi P,Forsen O,et et al.Polyaniline epoxy coating with good anticorrosion properties[J].Synthetic Metal,1997,85:1333-1334.
【6】Wessling B.Passivation of metals by coating with polyaniline:corrosion potential shift and morphological changes[J].Advanced Materials,1994,(6):226-228.
【7】Yen Wei,Jianguo Wang,Xinru Jia,et al.Polyaniline as corrosion protection coatings on cold rolled steel[J].Polymer,1995,36:4535-4537.
【8】Lu WK,Elsenbaumer RL,Wessling B.Corrosion protection of mild steel by coatings containing polyaniline[J].Synthetic Metal,1995,71:2163-2166.
【9】张其锦,翟 焱.聚苯胺的电化学合成实验[J].大学化学,1998,13(4):41-43.
【10】Osterholm S E,Cao Y,Klaveter F,et al.Emulsion polymerization of aniline[J].Synthetic Metals,1993,55-57:1034-1038.
【11】Angelopoulos M,Maric,Gelorme,et al.Water-soluble electrically conduction polymer,their synthesis and use[P].USE:5370825,1994.
【12】Samudson L A,Anaynostopoulos A,Alva K S,et al.Biologically derived conducting and water soluble polyaniline[J].Macromolecules,1998,31:4376.
【13】Anton J,Dominis,Geoffreg,et al.A de-doping/re-doping study of organic soluble polyaniline[J].Synthetic Metals,2002,129:165-172.
【14】Kwan Sik Jang,Hoosung Lee,Bonyjin Moon,et al.Synthesis and characterization of water soluble polypyrrole doped with functional dopants[J].Synthetic Metals,2004,143:289-294.
【15】Shoji Ito,Kazuhiko,Seiichi Jeshima,et al.Simple synthesis of water-soluble conducting polyaniline[J].Synthetic Metals,1998,96:161-163.
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