NiFe2O4基金属陶瓷惰性阳极的腐蚀研究进展
Progress in Studies on Corrosion of NiFe2O4 Based Cermet Inert Anodes
摘 要
综述了近年来国内外铝电解用NiFe2O4基金属陶瓷惰性阳极在阳极组元的溶解与分布、腐蚀率的预测与测定以及氧化物和金属相对阳极腐蚀的影响三个方面所做的研究工作.
铝电解
惰性阳极
腐蚀
金属陶瓷
NiFe2O4
aluminum electrolysis
inert anode
corrosion
cermet
Abstract
The progress in studies on corrosion of NiFe2O4 based cermet inert anodes in the recent years is reviewed,including the dissolution and distribution of inert anode constituents,the prediction and measurement of corrosion rates,the effect of oxides and metals on inert anode corrosion.
中图分类号 TG148 TB304
所属栏目 综述
基金项目 国家重点基础研究发展规划资助项目(2005CB623703);国家自然科学基金资助项目(50474051)
收稿日期 2007/5/28
修改稿日期 2007/7/10
网络出版日期
作者单位点击查看
引用该论文: HE Han-bing,ZHOU Ke-chao,LI Zhi-you. Progress in Studies on Corrosion of NiFe2O4 Based Cermet Inert Anodes[J]. Corrosion & Protection, 2008, 29(7): 359～364
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参考文献
【1】张磊,焦万丽,姚广春,等.NiFe2O4惰性阳极的制备及其电解腐蚀机理[J].硅酸盐学报,2005,33(12):1431-1436.
【2】J Hives,O-A Lorentsen,J Thonstad.Inert anode under electrochemical impedance spectroscopy stucy[C]//G M Haarberg,A Solheim,eds.Eleventh International Aluminium Symposium.Norway,September,2001:137-143.
【3】D H DeYong.Solubilities of oxides for inert anode in cryolite-based melts[C]//R E Miller,eds.Light Metals 1986.Warreudale PA:TMS,1986:299-307.
【4】R Keller,S Rolseth,J Thonstad.Mass transport considerations for the development of oxygen-evolving anodes in aluminum electrolysis[J].Electrochemical Acta,1997,42(12):1809-1817.
【5】王兆文,罗涛,高炳亮,等.大型铁酸镍基金属陶瓷惰性电极电解腐蚀研究[J].东北大学学报(自然科学版),2004,25(10):991-993.
【6】Wang Huazhang,J Thonstad.The behavior of inert anodes as a functin of some operating parameters[C]//G.C.Paul,eds.Light metals 1989.Warreudale PA:TMS,1989:283-290.
【7】P C Chin.The behavior of impurity species in hall-heroult aluminum Cells[D].Canada:Carnegie Mellon University,1992.
【8】P C Chin,P J Sides,R Keller.The transfer of nickel,iron,and copper from hall cell melts to molten aluminum[J].Canada.Metall.Q,1996:35-61.
【9】E Olsen,J Thonstad.Nickel ferrite as inert anodes in aluminum electrolysis:Part Ⅱ material performance and long-term testing[J].Journal of Applied Electrochemistry,1999,29(3):301-311.
【10】E Olsen,J Thonstad.Nickel ferrite as inert anodes in aluminum electrolysis:PartⅠMaterial fabrication and Preliminary Testing[J].Journal of Applied Electrochemistry,1999,29(3):293-299.
【11】赖延清,田忠良,秦庆伟,等.复合氧化物陶瓷在Na3AlF6-Al2O3熔体中的溶解性[J].中南工业大学学报(自然科学版),2003,34(3):245-247.
【12】秦庆伟,赵恒勤,赖延清,等.NiFe2O4陶瓷的制备及其在Na3AlF6-Al2O3中的溶解性研究[J].矿产保护与利用,2003,3:39-43.
【13】LAI Yan-qing,TIAN Zhong-liang,LI Jie,et al.Results from 100 h electrolysis testing of NiFe204 based cermet as inert anode in aluminum reduction[J].Trans.Nonferrous Met.SOC.China,2006,16:970-974.
【14】赖延清,秦庆伟,段华南,等.NiFe2O4基金属陶瓷材料的制备及其耐腐蚀性能[J].中南大学学报(自然科学版),2004,35(6):885-890.
【15】johansen H G,thonstad J,sterten A.Iron as contaminant in a VS soderberg cell[C]//In:Light Metal 1977,Proceedings of the Technical Seesions Presented by the TMS Aluminum Committee at the 106st Meeting.Ga Atlanta:TMS.1977:253-261.
【16】Q B Diep,E W Dewing,A Sterten.The solubility of Fe2O3 in cryolite-alumina metls[J].Metallurgical and Material Transactions B,2002,33B(1):140-142.
【17】王兆文,罗 涛,高炳亮,等.NiAl2O4基惰性阳极的制备及电解腐蚀研究[J].矿冶工程,2004,24(5):61-63.
【18】赖延清,陈湘涛,秦庆伟,等.NiFe2O4基金属陶瓷耐腐蚀因素分析及腐蚀率预测[J].中南大学学报(自然科学版),2004,35(6):896-901.
【19】石忠宁,徐君莉,邱竹贤,等.Ni-Fe-Cu惰性金属阳极的抗氧化和耐蚀性能[J].中国有色金属学报,2004,14(4):591-594.
【20】J D Weyand,D H DeYoung,S P Ray,et al.Inert Anodes for aluminium smelting[R].Washington DC:Aluminum Company of America,1986:1-516.
【21】席锦会,姚广春,刘宜汉,等.V2O5对镍铁尖晶石烧结机理及性能的影响[J].硅酸盐学报,2005,33(6):683-687.
【22】席锦会,刘宜汉,姚广春.MnO2对镍铁尖晶石惰性阳极材料性能的影响[J].功能材料,2005,36(3):374-376.
【23】焦万丽,张磊,姚广春.MnO2添加剂对镍铁尖晶石基惰性阳极耐腐蚀性的影响[J].过程工程学报,2005,5(3):309-312.
【24】Wang Huazhang,J Thonstad.The behavior of inert anodes as a functin of some operating parameters[C].G.C.Paul,eds.Light metals 1989.Warreudale PA:TMS,1989:283-290.
【25】G P Tracy.Corrosion and passivation of cermet inert anodes in cryolite-type electrolyte[C]//R.E.Miller,eds.Light Metals 1986.Warreudale PA:TMS,1986:309-320.
【26】C F Windisch Jr,C M Steven.Electrochemical polarization studies on cu and Cu-containing cermet anodes for the aluminum industry[C]//R.D.Zabreznik,eds.Light Metals 1987.Warrendale,PA,USA:TMS,1987:351-355.
【27】S P Ray,D A Weirauch,X Liu.Inert anode containing oxides of nickel,iron and zinc useful for the electrolytic production of metals[P].US,6423195,April 4,2000.
【28】S P Ray,X H Liu,D A Weirauch,et al.Electrolytic production of high purity aluminium using ceramic inert anodes[P].US,6416649,April 16,2001.
【29】O-A Lorentsen,J Thonstad.Electrolysis and post-testing of inert cermet anodes[C]//W.Schneider,eds.Light Metals 2002.Warreudale PA:TMS,2002:457-462.
【30】V Blinov,P Polyakov,J Thonstad et al.Behaviour of cermet inert anodes for aluminium electrolysis in a low temperature electrolyte[C]//G.M.Haarberg,A.Solheim,eds.Eleventh international aluminium symposium.Norway,September,2001:123-131.
【2】J Hives,O-A Lorentsen,J Thonstad.Inert anode under electrochemical impedance spectroscopy stucy[C]//G M Haarberg,A Solheim,eds.Eleventh International Aluminium Symposium.Norway,September,2001:137-143.
【3】D H DeYong.Solubilities of oxides for inert anode in cryolite-based melts[C]//R E Miller,eds.Light Metals 1986.Warreudale PA:TMS,1986:299-307.
【4】R Keller,S Rolseth,J Thonstad.Mass transport considerations for the development of oxygen-evolving anodes in aluminum electrolysis[J].Electrochemical Acta,1997,42(12):1809-1817.
【5】王兆文,罗涛,高炳亮,等.大型铁酸镍基金属陶瓷惰性电极电解腐蚀研究[J].东北大学学报(自然科学版),2004,25(10):991-993.
【6】Wang Huazhang,J Thonstad.The behavior of inert anodes as a functin of some operating parameters[C]//G.C.Paul,eds.Light metals 1989.Warreudale PA:TMS,1989:283-290.
【7】P C Chin.The behavior of impurity species in hall-heroult aluminum Cells[D].Canada:Carnegie Mellon University,1992.
【8】P C Chin,P J Sides,R Keller.The transfer of nickel,iron,and copper from hall cell melts to molten aluminum[J].Canada.Metall.Q,1996:35-61.
【9】E Olsen,J Thonstad.Nickel ferrite as inert anodes in aluminum electrolysis:Part Ⅱ material performance and long-term testing[J].Journal of Applied Electrochemistry,1999,29(3):301-311.
【10】E Olsen,J Thonstad.Nickel ferrite as inert anodes in aluminum electrolysis:PartⅠMaterial fabrication and Preliminary Testing[J].Journal of Applied Electrochemistry,1999,29(3):293-299.
【11】赖延清,田忠良,秦庆伟,等.复合氧化物陶瓷在Na3AlF6-Al2O3熔体中的溶解性[J].中南工业大学学报(自然科学版),2003,34(3):245-247.
【12】秦庆伟,赵恒勤,赖延清,等.NiFe2O4陶瓷的制备及其在Na3AlF6-Al2O3中的溶解性研究[J].矿产保护与利用,2003,3:39-43.
【13】LAI Yan-qing,TIAN Zhong-liang,LI Jie,et al.Results from 100 h electrolysis testing of NiFe204 based cermet as inert anode in aluminum reduction[J].Trans.Nonferrous Met.SOC.China,2006,16:970-974.
【14】赖延清,秦庆伟,段华南,等.NiFe2O4基金属陶瓷材料的制备及其耐腐蚀性能[J].中南大学学报(自然科学版),2004,35(6):885-890.
【15】johansen H G,thonstad J,sterten A.Iron as contaminant in a VS soderberg cell[C]//In:Light Metal 1977,Proceedings of the Technical Seesions Presented by the TMS Aluminum Committee at the 106st Meeting.Ga Atlanta:TMS.1977:253-261.
【16】Q B Diep,E W Dewing,A Sterten.The solubility of Fe2O3 in cryolite-alumina metls[J].Metallurgical and Material Transactions B,2002,33B(1):140-142.
【17】王兆文,罗 涛,高炳亮,等.NiAl2O4基惰性阳极的制备及电解腐蚀研究[J].矿冶工程,2004,24(5):61-63.
【18】赖延清,陈湘涛,秦庆伟,等.NiFe2O4基金属陶瓷耐腐蚀因素分析及腐蚀率预测[J].中南大学学报(自然科学版),2004,35(6):896-901.
【19】石忠宁,徐君莉,邱竹贤,等.Ni-Fe-Cu惰性金属阳极的抗氧化和耐蚀性能[J].中国有色金属学报,2004,14(4):591-594.
【20】J D Weyand,D H DeYoung,S P Ray,et al.Inert Anodes for aluminium smelting[R].Washington DC:Aluminum Company of America,1986:1-516.
【21】席锦会,姚广春,刘宜汉,等.V2O5对镍铁尖晶石烧结机理及性能的影响[J].硅酸盐学报,2005,33(6):683-687.
【22】席锦会,刘宜汉,姚广春.MnO2对镍铁尖晶石惰性阳极材料性能的影响[J].功能材料,2005,36(3):374-376.
【23】焦万丽,张磊,姚广春.MnO2添加剂对镍铁尖晶石基惰性阳极耐腐蚀性的影响[J].过程工程学报,2005,5(3):309-312.
【24】Wang Huazhang,J Thonstad.The behavior of inert anodes as a functin of some operating parameters[C].G.C.Paul,eds.Light metals 1989.Warreudale PA:TMS,1989:283-290.
【25】G P Tracy.Corrosion and passivation of cermet inert anodes in cryolite-type electrolyte[C]//R.E.Miller,eds.Light Metals 1986.Warreudale PA:TMS,1986:309-320.
【26】C F Windisch Jr,C M Steven.Electrochemical polarization studies on cu and Cu-containing cermet anodes for the aluminum industry[C]//R.D.Zabreznik,eds.Light Metals 1987.Warrendale,PA,USA:TMS,1987:351-355.
【27】S P Ray,D A Weirauch,X Liu.Inert anode containing oxides of nickel,iron and zinc useful for the electrolytic production of metals[P].US,6423195,April 4,2000.
【28】S P Ray,X H Liu,D A Weirauch,et al.Electrolytic production of high purity aluminium using ceramic inert anodes[P].US,6416649,April 16,2001.
【29】O-A Lorentsen,J Thonstad.Electrolysis and post-testing of inert cermet anodes[C]//W.Schneider,eds.Light Metals 2002.Warreudale PA:TMS,2002:457-462.
【30】V Blinov,P Polyakov,J Thonstad et al.Behaviour of cermet inert anodes for aluminium electrolysis in a low temperature electrolyte[C]//G.M.Haarberg,A.Solheim,eds.Eleventh international aluminium symposium.Norway,September,2001:123-131.
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