青铜器腐蚀研究现状
Research Status of Corrosion of Bronze Wares
摘 要
简述了影响青铜器腐蚀的主要因素,介绍了青铜器腐蚀的主要产物以及研究青铜器腐蚀的主要方法,综述了目前国内外对青铜器腐蚀机理和缓蚀剂研究的最新进展,提出了加速青铜器腐蚀的氯化亚铜多孔氧电极机理.
铜锈
腐蚀机理
缓蚀剂
bronze ware
rust
corrosion mechanism
inhibitor
Abstract
The main affecting factors,corrosion products and advanced investigation methods for bronze corrosion are reviewed.A mechanism of porous oxygen electrode,which can interpret the acceleration of bronze ware corrosion is proposed.
中图分类号 TG172 G264
所属栏目 综述
基金项目 国家自然科学基金(批准号:20576126),河南省科技攻关项目(批准号:524490018)
收稿日期 2008/3/26
修改稿日期 2008/4/22
网络出版日期
作者单位点击查看
引用该论文: FENG Shao-bin,HU Fang-hong,FENG Li-ting. Research Status of Corrosion of Bronze Wares[J]. Corrosion & Protection, 2009, 30(1): 7～10
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】王煊.三星堆青铜器“酥粉锈”腐蚀机理的研究与探讨[J].四川文物,2002(3):83-89.
【2】K P Fitz Gerald,J Nairn,et al.Atmospheric corrosion of copper and the colour,structure and composition of natural patinas on copper[J].Corrosion Science,2006,48:2480-2509.
【3】范崇正,吴佑实,王昌燧,等.粉状锈生成的电化学腐蚀及价电子结构分析[J].化学物理学报,1992,6:479-484.
【4】王蕙贞,魏国锋,朱虹,等.商代青铜戈腐蚀机理与保护研究[J].考古与文物,2001(3):93-96.
【5】范崇正,王昌燧,王胜君,等.青铜器粉状锈生成机理研究[J].中国科学(B辑),1991,21(3):239-245.
【6】周剑虹,刘成,何朝晖.出土青铜器是否带有原生“粉状锈”的探讨[J].文物保护与考古科学,2006,18(2):51-56.
【7】张展适,陈少华,陈障茹,等.青铜文物腐蚀过程的模拟研究[J].中国腐蚀与防护学报,2006,26(2):94-99.
【8】钟庆东.采用丝束电极研究金属的缝隙腐蚀[J].中国腐蚀与防护学报,1999,19(3):189-192.
【9】王菊琳,许淳淳,于淼.已锈蚀青铜在大气环境中的腐蚀发展及其保护研究[J].腐蚀科学与防护技术,2005,17(5):324-327.
【10】王菊琳,许淳淳,于淼.青铜文物表面腐蚀产物的组成及深度分布研究[J].中国腐蚀与防护学报,2005,25(3):163-166.
【11】Gabriela P Cicileo,Miguel A Crespo,et al.Comparative study of patinas formed on statuary alloys by means of electrochemical and surface analysis techniques[J].Corrosion Science,2004,46:929-953.
【12】C Chiavari,K Rahmouni,et al.Composition and electrochemical properties of natural patinas of outdoor bronze monuments[J].Electrochimica Acta,2007,52:7760-7769.
【13】Nebil Souissi,Emmanuel Sidot,et al.Corrosion behaviour of Cu-10Sn bronze in aerated NaCl aqueous media electrochemical investigation[J].Corrosion Science,2007,49:3333-3347.
【14】祝鸿范,周浩,蔡兰坤.青铜病的闭塞孔穴腐蚀特征的研究[J].文物保护与考古科学,2004,14(增刊):29-49.
【15】祝鸿范.青铜病的发生与小孔腐蚀的关系[J].文物保护与考古科学,1998,10(1):7-14.
【16】祝鸿范,周浩.青铜器文物腐蚀受损原因的研究[J].电化学,1999,5(3):214-318.
【17】冯丽婷,刘清,包祥,等.青铜器加速腐蚀的多孔氧电极研究[J].中国腐蚀与防护学报,2006,16(3):184-187.
【18】Maria Cristina Squarcialupi,Gian Piero Bernardini,et al.Characterisation by XPS of the corrosion patina formed on bronze surfaces[J].Journal of Cultural Heritage,2002,3:199-204.
【19】He Ling,Zhao Qingrong,et al.Characterization of corroded bronze Ding from the Yin Ruins of China[J].Corrosion Science,2007,49:2534-2546.
【20】C Vazquez-Calvo,M Alvarez de Buergo,et al.Characterization of patinas by means of microscopic techniques[J].Materials Characterization,2007,58:1119-1132.
【21】A Dermaj,N Hajjaji,S Joiret.Electrochemical and spectroscopic evidences of corrosion inhibition of bronze by a triazole derivative[J].Electrochimica Acta 2007,52:4654-4462.
【22】D de la Fuente,J Simancas,M Morcillo.Morphological study of 16-year patinas formed on copper in a wide range of atmospheric exposures[J].Corrosion Science,2008,50:268-285.
【23】魏国峰,秦颍,王昌燧,等.古代青铜器基体与其锈蚀产物铅同位素对比研究[J].中国科学技术大学学报,2006,36(7):771-774.
【24】罗武干,秦颍,黄凤春,等.湖北省出土的若干青铜器锈蚀产物研究[J].腐蚀科学与防护技术,2007,19(3):157-161.
【25】李涛,秦颍,罗武干,等.蓬莱出土古代青铜器锈蚀产物的显微拉曼光谱分析[J].光散射学报,2007,19(1):16-32.
【26】朱一帆,付海涛,李瑛,等.青铜表面膜的红外光谱和原子力显微镜分析[J].南京工业大学学报,2004,26(4):49-52.
【27】陈善华,刘思维,孙杰.青铜文物的光电子能谱分析[J].材料保护,2007,40(2):67-70.
【28】杨小林,李艳萍,王建平.新干商代大墓青铜器腐蚀分析研究[J].文物保护与考古科学,2006,18(4):33-38.
【29】冯绍彬,商士波,张巍,等.应用电位活化理论研究青铜器的腐蚀与保护[J].文物保护与考古科学,2005,17(1):5-8.
【30】H Brinch Madson.A preliminary note on the use of benzotriazole for stabilizing bronze objects[J].Studies in Conservation,1967,12(4):163-167.
【31】朱一帆,万俐.AMT及其复合物在青铜表面形成保护膜的耐蚀性研究[J].南京化工大学学报,1999,21(2):16-20.
【32】Julin Wang,Chunchun Xu,Guocheng Lv.Formation processes of CuCl and regenerated Cu crystals on bronze surfaces in neutral and acidic media[J].Applied Surface Science,2006,252:6294-6303.
【33】L Muresan,S Varvara,E Stupnisek-Lisac.Protection of bronze covered with patina by innoxious organic substances[J].Electrochimica Acta 2007,50:7770-7779.
【34】Rosa Vera,Francisco Bastidas,et al.Corrosion inhibition of copper in chloride media by 1,5-bis(4-dithiocarboxylate-1-dodecyl-5-hydroxy-3-methylpyrazolyl)pentane[J].Corrosion Science,2008,50:729-736.
【35】EI-Sayed M Sherif,A M EI Shamy,et al.5-(Phenyl)-4H-1,2,4-triazole-3-thiol as a corrosion inhibitor for copper in 3.5% NaCl solution[J].Materials Chemistry and Physics,2007,102:231-239.
【36】Christopher J Mc Namara,Margaret Breuker,et al.Biodeterioration of Incralac used for the protection of bronze monuments[J].Journal of Cultural Heritage,2004,5:361-364.
【2】K P Fitz Gerald,J Nairn,et al.Atmospheric corrosion of copper and the colour,structure and composition of natural patinas on copper[J].Corrosion Science,2006,48:2480-2509.
【3】范崇正,吴佑实,王昌燧,等.粉状锈生成的电化学腐蚀及价电子结构分析[J].化学物理学报,1992,6:479-484.
【4】王蕙贞,魏国锋,朱虹,等.商代青铜戈腐蚀机理与保护研究[J].考古与文物,2001(3):93-96.
【5】范崇正,王昌燧,王胜君,等.青铜器粉状锈生成机理研究[J].中国科学(B辑),1991,21(3):239-245.
【6】周剑虹,刘成,何朝晖.出土青铜器是否带有原生“粉状锈”的探讨[J].文物保护与考古科学,2006,18(2):51-56.
【7】张展适,陈少华,陈障茹,等.青铜文物腐蚀过程的模拟研究[J].中国腐蚀与防护学报,2006,26(2):94-99.
【8】钟庆东.采用丝束电极研究金属的缝隙腐蚀[J].中国腐蚀与防护学报,1999,19(3):189-192.
【9】王菊琳,许淳淳,于淼.已锈蚀青铜在大气环境中的腐蚀发展及其保护研究[J].腐蚀科学与防护技术,2005,17(5):324-327.
【10】王菊琳,许淳淳,于淼.青铜文物表面腐蚀产物的组成及深度分布研究[J].中国腐蚀与防护学报,2005,25(3):163-166.
【11】Gabriela P Cicileo,Miguel A Crespo,et al.Comparative study of patinas formed on statuary alloys by means of electrochemical and surface analysis techniques[J].Corrosion Science,2004,46:929-953.
【12】C Chiavari,K Rahmouni,et al.Composition and electrochemical properties of natural patinas of outdoor bronze monuments[J].Electrochimica Acta,2007,52:7760-7769.
【13】Nebil Souissi,Emmanuel Sidot,et al.Corrosion behaviour of Cu-10Sn bronze in aerated NaCl aqueous media electrochemical investigation[J].Corrosion Science,2007,49:3333-3347.
【14】祝鸿范,周浩,蔡兰坤.青铜病的闭塞孔穴腐蚀特征的研究[J].文物保护与考古科学,2004,14(增刊):29-49.
【15】祝鸿范.青铜病的发生与小孔腐蚀的关系[J].文物保护与考古科学,1998,10(1):7-14.
【16】祝鸿范,周浩.青铜器文物腐蚀受损原因的研究[J].电化学,1999,5(3):214-318.
【17】冯丽婷,刘清,包祥,等.青铜器加速腐蚀的多孔氧电极研究[J].中国腐蚀与防护学报,2006,16(3):184-187.
【18】Maria Cristina Squarcialupi,Gian Piero Bernardini,et al.Characterisation by XPS of the corrosion patina formed on bronze surfaces[J].Journal of Cultural Heritage,2002,3:199-204.
【19】He Ling,Zhao Qingrong,et al.Characterization of corroded bronze Ding from the Yin Ruins of China[J].Corrosion Science,2007,49:2534-2546.
【20】C Vazquez-Calvo,M Alvarez de Buergo,et al.Characterization of patinas by means of microscopic techniques[J].Materials Characterization,2007,58:1119-1132.
【21】A Dermaj,N Hajjaji,S Joiret.Electrochemical and spectroscopic evidences of corrosion inhibition of bronze by a triazole derivative[J].Electrochimica Acta 2007,52:4654-4462.
【22】D de la Fuente,J Simancas,M Morcillo.Morphological study of 16-year patinas formed on copper in a wide range of atmospheric exposures[J].Corrosion Science,2008,50:268-285.
【23】魏国峰,秦颍,王昌燧,等.古代青铜器基体与其锈蚀产物铅同位素对比研究[J].中国科学技术大学学报,2006,36(7):771-774.
【24】罗武干,秦颍,黄凤春,等.湖北省出土的若干青铜器锈蚀产物研究[J].腐蚀科学与防护技术,2007,19(3):157-161.
【25】李涛,秦颍,罗武干,等.蓬莱出土古代青铜器锈蚀产物的显微拉曼光谱分析[J].光散射学报,2007,19(1):16-32.
【26】朱一帆,付海涛,李瑛,等.青铜表面膜的红外光谱和原子力显微镜分析[J].南京工业大学学报,2004,26(4):49-52.
【27】陈善华,刘思维,孙杰.青铜文物的光电子能谱分析[J].材料保护,2007,40(2):67-70.
【28】杨小林,李艳萍,王建平.新干商代大墓青铜器腐蚀分析研究[J].文物保护与考古科学,2006,18(4):33-38.
【29】冯绍彬,商士波,张巍,等.应用电位活化理论研究青铜器的腐蚀与保护[J].文物保护与考古科学,2005,17(1):5-8.
【30】H Brinch Madson.A preliminary note on the use of benzotriazole for stabilizing bronze objects[J].Studies in Conservation,1967,12(4):163-167.
【31】朱一帆,万俐.AMT及其复合物在青铜表面形成保护膜的耐蚀性研究[J].南京化工大学学报,1999,21(2):16-20.
【32】Julin Wang,Chunchun Xu,Guocheng Lv.Formation processes of CuCl and regenerated Cu crystals on bronze surfaces in neutral and acidic media[J].Applied Surface Science,2006,252:6294-6303.
【33】L Muresan,S Varvara,E Stupnisek-Lisac.Protection of bronze covered with patina by innoxious organic substances[J].Electrochimica Acta 2007,50:7770-7779.
【34】Rosa Vera,Francisco Bastidas,et al.Corrosion inhibition of copper in chloride media by 1,5-bis(4-dithiocarboxylate-1-dodecyl-5-hydroxy-3-methylpyrazolyl)pentane[J].Corrosion Science,2008,50:729-736.
【35】EI-Sayed M Sherif,A M EI Shamy,et al.5-(Phenyl)-4H-1,2,4-triazole-3-thiol as a corrosion inhibitor for copper in 3.5% NaCl solution[J].Materials Chemistry and Physics,2007,102:231-239.
【36】Christopher J Mc Namara,Margaret Breuker,et al.Biodeterioration of Incralac used for the protection of bronze monuments[J].Journal of Cultural Heritage,2004,5:361-364.
相关信息
