氨基酸类绿色酸洗缓蚀剂的研究进展
Progress in Research on Amino Acids as Corrosion Inhibitors in Acid Solutions
摘 要
氨基酸类缓蚀剂具有无毒、可生物降解、价格低、纯度高等特点,是一类很有发展潜力的绿色缓蚀剂.本文总结了国内外氨基酸类缓蚀剂在酸性介质中的研究进展,探讨了它们的缓蚀作用机理,并对其发展趋势进行了展望.
绿色缓蚀剂
氨基酸
pickling
green corrosion inhibitor
amino acid
Abstract
Amino acids are non-toxic,biodegradable,relatively cheap and easy to produce with purities higher than 99％.Researches on corrosion inhibition and involved mechanism of amino acid inhibitors in acid media at home and abroad are reviewed.The prospects of the development trend are also disscussed.
中图分类号 TG174.42
所属栏目 专论
基金项目
收稿日期 2008/3/10
修改稿日期 2008/5/18
网络出版日期
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引用该论文: TIAN Hui-juan,LIU Xin-hua,RUI Yu-lan. Progress in Research on Amino Acids as Corrosion Inhibitors in Acid Solutions[J]. Corrosion & Protection, 2009, 30(3): 186～189
被引情况:
【1】杜芳,蔡婷婷,谢黎,华万森,傅佳骏, "洛尔类药物的合成及其缓蚀作用机理",腐蚀与防护 35, 562-567(2014)
【2】李美明,徐群杰,韩杰,张志国, "绿色铜缓蚀剂的研究进展",腐蚀与防护 35, 1243-1247(2014)
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参考文献
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【28】E E Oguzie,Y Li,F H Wang.Effect of 2-amino-3-mercaptopropanoic acid(cysteine)on the corrosion behaviour of low carbon steel in sulphuric acid[J].Electrochimica Acta,2007,53 :909-914.
【29】M S Morad.Effect of sulfur-containing amino acids on the corrosion of mild steel in sulfide-polluted sulfuric acid solution[J].Journal of Applied Electrochemistry,2007,37:1191-1200.
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【2】E E Oguzie.Studies on the inhibitive effect of occimum viridis extract on the acid corrosion of mild steel[J].Materials Chemistry and Physics,2006,99:441-446.
【3】E E Oguzie.Corrosion inhibition of aluminium in acidic and alkaline media by sansevieria trifasciata extract[J].Corrosion Science,2007,49(3):1527-1539.
【4】G Moretti,F Guidi,G Grion.Tryptamine as a green iron corrosion inhibitor in 0.5 M deaerated sulphuric acid[J].Corrosion Science,2004,46(2):387-403.
【5】E E Oguzie,C Unaegbu,C N Ogukwe,et al.Inhibition of mild steel corrosion in sulphuric acid using indigo dye and synergistic halide additives[J].Materials Chemistry and Physics,2004,84:363-368.
【6】S M A Shibli,V S Saji.Co-inhibition characteristics of sodium tungstate with potassium iodate on mild steel corrosion[J].Corrosion Science,2005,47(9):2213-2224.
【7】Guannan Mu,Xianghong Li.Inhibition of cold rolled steel corrosion by Tween-20 in sulfuric acid:Weight loss,electrochemical and AFM approaches[J].Journal of Colloid and Interface Science,2005,289(1):184-192.
【8】B D 黑姆斯,N M 胡珀.生物化学[M].王镜岩,张新跃等译.北京:科学出版社,2004.
【9】M I Khaled.Evaluation of cysteine as environmentally friendly corrosion inhibitor for copper in neutral and acidic chloride solutions[J].Electrochimica Acta,2007,52:7811-7819.
【10】E E Oguzie,Y Li,F H Wang.Corrosion inhibition and adsorption behavior of methionine on mild steel in sulfuric acid and synergistic effect of iodide ion[J].Journal of Colloid and Interface Science,2007,310:90-98.
【11】韶晖,冷一欣.聚天冬氨酸阻垢性能的研究[J].油田化学,2001,18(2):181-183.
【12】徐群杰,曹敏,周国定.聚天冬氨酸及其复配对3％ NaCl溶液中黄铜的缓蚀作用[J].华北电力技术,2005(9):1-3.
【13】徐群杰,董孔祥,周国定.聚天冬氨酸和钨酸钠复配对模拟水中铜的缓蚀作用研究[J].腐蚀与防护,2005,26(10):415-417,421.
【14】杨士林,黄君礼,陶虎春,等.马来酸酐合成聚天冬氨酸及其分子质量对阻垢性能的影响[J].现代化工,2003,23(12):26-29.
【15】霍宇凝,刘珊,陆柱.聚天冬氨酸对硫酸钙阻垢性能的研究[J].水处理技术,2001,27(1):26-28.
【16】荆国林,赵海,王晓玉.绿色阻垢剂聚天冬氨酸的合成及性能评价[J].工业用水与废水,2006,37(5):81-83.
【17】李燕,陆柱.钨酸盐与聚天冬氨酸对碳钢协同缓蚀作用的研究[J].腐蚀与防护,2001,22(9):371-374.
【18】李春梅,谷宁,崔荣静,等.聚天冬氨酸在盐酸中对碳钢的缓蚀作用研究[J].河北师范大学学报(自然科学版),2004,28(6):602-604.
【19】李春梅,谷宁.酸性体系中聚天冬氨酸对碳钢的缓蚀作用初探[J].腐蚀与防护,2007,28(1):21-22,39.
【20】黎新,胡立新,颜肖慈,等.脂肪族氨基酸对铝缓蚀机理的研究[J].材料保护,2005,33(5):3-4.
【21】刘晓轩,袁朗白,李向红,等.氨基酸类有机物在硫酸介质中对钢的缓蚀作用[J].云南大学学报(自然科学版),2003,25(4):355-357.
【22】M S Morad.Effect of amino acids containing sulfur on the corrosion of mild steel in phosphoric acid solutions containing Cl-,F- and Fe3+ ions:Behavior under polarization conditions[J].Journal of Applied Electrochemistry,2005,35:889-895.
【23】A B Waheed,M I Khaled,M F Ahlam.Environmentally safe corrosion inhibition of the Cu-Ni alloys in acidic sulfate solutions[J].Journal of Applied Electrochemistry,2005,35:879-888.
【24】B Gómez,N V Likhanova,M A Domìnguez Aguilar.Theoretical study of a new group of corrosion inhibitors[J].Journal of Physics and Chemistry A,2005,109:8950-8957.
【25】M Zerfaoui,H Oudda,B Hammouti,et al.Inhibition of corrosion of iron in citric acid media by amino acids[J].Progress in Organic Coatings,2004,51:134-138.
【26】H Ashassi-Sorkhabi,M R Majidi,K Seyyedi.Investigation of inhibition effect of some amino acids against steel corrosion in HCl solution[J].Applied Surface Science,2004,225:176-185.
【27】H Ashassi-Sorkhabi,Z Ghasemi,D Seifzadeh.The inhibition effect of some amino acids towards the corrosion of aluminum in 1 M HCl + 1 M H2SO4 solution[J].Applied Surface Science,2005,249:408-418.
【28】E E Oguzie,Y Li,F H Wang.Effect of 2-amino-3-mercaptopropanoic acid(cysteine)on the corrosion behaviour of low carbon steel in sulphuric acid[J].Electrochimica Acta,2007,53 :909-914.
【29】M S Morad.Effect of sulfur-containing amino acids on the corrosion of mild steel in sulfide-polluted sulfuric acid solution[J].Journal of Applied Electrochemistry,2007,37:1191-1200.
【30】O Olivares,N V Likhanova,B Go′mez,et al.Electrochemical and XPS studies of decylamides of α-amino acids adsorption on carbon steel in acidic environment[J].Applied Surface Science,2006,252:2894-2909.
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