涂料用铝粉的表面改性研究进展
A Review of Surface Modification of Aluminum Pigments Applied in Coatings
摘 要
铝粉作为重要的金属颜料之一,当其用于水性涂料时,易被腐蚀而逐渐失去金属光泽,因此需要对其进行表面改性.目前的表面改性方法主要有添加缓蚀剂法和包覆膜法,较多的是添加缓蚀剂来保护铝颜料,而包覆膜法对铝颜料能起到更好的保护作用,被认为是一种较有发展前景的方法.本文对铝颜料表面改性机理及改性方法的研究进展进行了介绍,指出了目前改性方法中存在的不足,并提出了改进措施.
表面改性
缓蚀剂
包覆膜
aluminum pigment
surface modification
corrosion inhibitor
encapsulation
Abstract
Aluminum,as one of the important metal pigments,can be easily corroded and tarnished when it is utilized in the waterborne paints.Therefore it is necessary to modify its surface.Now,two methods have been adopted,i.e,corrosion inhibitor and encapsulation.It is reported that the encapsulation could protect the aluminum pigments more efficiently,and is a prospect method for protection of aluminum pigments.The mechanism,methods and development of the aluminum pigment modification are reviewed in this paper.The deficiency of the present methods is pointed out and the improving ways are also suggested.
中图分类号 TG179 TQ633
所属栏目 专论
基金项目 广东省自然科学基金项目资助项目(07006528)
收稿日期 2008/7/15
修改稿日期 2008/8/4
网络出版日期
作者单位点击查看
备注李利君,博士.
引用该论文: LI Li-jun,PI Pi-hui,WANG Lian-shi,WEN Xiu-fang,CHENG Jiang,YANG Zhuo-ru. A Review of Surface Modification of Aluminum Pigments Applied in Coatings[J]. Corrosion & Protection, 2009, 30(8): 519～522
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参考文献
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【3】A Kiehl,K Greiwe.Encapsulated aluminium pigments[J].Progress in Organic Coatings,1999,37(3/4):179-183.
【4】Anthony.Paint pretreatment for aluminum[J].Metal Finishing,2000,98(6):74-79.
【5】K C Emregül,A A Aksüt.The effect of sodium molybdate on the pitting corrosion of aluminum[J].Corrosion Science,2003,45:2415-2433.
【6】A K Maayta,N A F,Al-Rawashdeh.Inhibition of acidic corrosion of pure aluminum by some organic compounds[J].Corrosion Science,2004,46(5):1129-1140.
【7】B Müller.Corrosion inhibition of aluminium and zinc pigments by saccharides[J].Corrosion Science,2002,44(7):1583-1591.
【8】Sayed S Abd El Rehim,Hamdy H Hassan,Mohammed A Amin.Corrosion inhibition of aluminum by 1,1(lauryl amido)propyl ammonium chloride in HCl solution[J].Materials Chemistry and Physics,2001(70):64-72.
【9】B Müller,M Shahid,G Kinet.Nitro-and aminopenols as corrosion inhibitors for aluminium and zinc pigments[J].Corrosion Science,1999(41):1323-1331.
【10】Bodo Müller.Polymeric corrosion inhibitors for aluminum pigment[J].Reactive & Functional Polymers,1999,39:165-177.
【11】Shoichiro Yano,Keisuke Iwata,Kimio Kurita.Physical properties and structure of organic-inorganic hybrid materials produced by sol-gel process[J].Materials Science and Engineering C,1998,6:75-90.
【12】李利君,皮丕辉,文秀芳,等.溶胶-凝胶法制备纳米SiO2包覆的铝颜料[J].华南理工大学学报(自然科学版),2007,35(11):72-76.
【13】Li-jun Li,Pi-hui Pi,Xiu-fang Wen,et al.Optimization of sol-gel coatings on the surface of aluminum pigments for corrosion protection[J].Corrosion Science,2008,50(3):795-803.
【14】Li-jun Li,Pi-hui Pi,Xiu-fang Wen,et al.Aluminum pigments encapsulated by inorganic-organic hybrid coatings and their stability in alkaline aqueous media[J].Journal of Coatings Technology and Research,2008,5(1):77-83.
【15】Y Iriyama,T Ihara,M Kiboku.Plasma polymerization of tetraethoxysilane on aluminum granules for corrosion protection[J].Thin Solid Films,1996,287(1/2):169-173.
【16】Hui Liu,Hongqi Ye,Yingchao Zhang.Preparation and characterization of PMMA/flaky aluminum composite particle in the presence of MPS[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2008,315(1/3):1-6.
【17】曹同玉,刘庆普,胡金生.聚合物乳液合成原理、性能及应用[M].北京:化学工业出版社,1997.
【18】Isao Kimura,Yoshinari Taguchi,Haruyuki Yoshii,et al.Encapsulation of aluminum flakes by dispersion polymerization of styrene in a nonaqueous system with reactive surfactants[J].Journal of Applied Polymer Science,2001,81:675-683.
【19】Hui Liu,Hongqi Ye,Xinde Tang.Aluminum pigment encapsulated by in situ copolymerization of styrene and maleic acid[J].Applied Surface Science,2007,254(2):616-620.
【20】王树文,荆进国.铝颜料表面改性技术及其进展[J].涂料工业,2001(10):29-31.
【21】Richard Knowles.汽车漆和修补漆用铝颜料[J].涂料工业,1997(6):16-18.
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