Corrosion-resistant Properties of Hot-dip Galvannealed Steel Sheets
摘 要
通过中性盐雾试验(NSST)和电化学试验对DX56热镀锌钢板及其合金化钢板进行耐腐蚀性能试验,得到了GI板和GA板产生红锈面积和失重随时间的变化关系,以及GI板和GA板在2% NaCl溶液中的Tafel极化曲线和电化学阻抗图谱(EIS).NSST结果显示,GA板出现红锈的时间明显早于GI板,且红锈面积增加迅速,但GA板的失重明显小于GI板.Tafel极化曲线表明GI板和GA板在2% NaCl溶液中均表现为活化溶解,未出现钝化,GA板的自腐蚀电位明显较GI板正移,在相同阳极电位下,GA板的极化电流密度小于GI板;由EIS及其等效电路拟合结果得到GA板镀层的电荷转移电阻明显大于GI板.试验结果表明GA板比GI板具有更好的耐腐蚀性能,用失重法衡量GA板的耐腐蚀性能比用红锈出现的时间及红锈面积增长速度更准确.
Abstract
Neutral salt spray test(NSST) and electrochemical test of DX56 were performed to study its corrosion properties.The changes of red rust area and weightloss of GI sheet and GA sheet as well as the Tafel polarization curves and electrochemical impedance spectroscopy (EIS) in 2 wt.% NaCl solution were obtained.NSST showed that the red rust on GA sheet occurred much earlier than GI sheet and the weightloss of GA sheet was less than GI sheet obviously.Tafel curves showed that both of GI sheet and GA sheet′s corrosion behaved to be activated dissolution without passivation and that GA sheet′s corrosion potential moved to positive direction in contrast with GI sheet′s.At the same anodic potential,GA sheet′s polarization current density was obviously lower than GI sheet′s.It was obtained from the EIS diagrams and the simulation results of their equivalent circuits that the charge transfer resistance of GA sheet was obviously higher than that of GI sheet.It is shown that GA sheet has better corrosion resistance than GI sheet and using weightloss to judge the corrosion resistance of GA sheet is more accurate than using the time for red rust to occur or the growth rate of red rust area.
中图分类号 TG174.3
所属栏目 试验研究
基金项目 科技部十一五科技支撑项目(项目编号:2006BAE03A13)
收稿日期 2009/1/22
修改稿日期 2009/4/4
网络出版日期
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备注刘昕,硕士研究生.
引用该论文: LIU Xin,JIANG She-ming,YUAN Xun-hua,YANG Xing-liang,LI Ya-dong,HE Ming-yi,ZHANG Qi-fu,ZHANG Jian. Corrosion-resistant Properties of Hot-dip Galvannealed Steel Sheets[J]. Corrosion & Protection, 2009, 30(11): 768~771
被引情况:
【1】刘昕,江社明,张启富, "自润滑镀锌板的主要性能",腐蚀与防护 35, 124-127(2014)
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参考文献
【1】Shigeru Wakano,Atsuyoshi Shibuya,Yoshihiko Hobo,et al.Corrosion performance of Zn alloy precoated steels for automotive body[J].ISIJ International,1983,23(11):967-973.
【2】Shingo Nomura,Hirohiko Sakai,Hidetoshi Nishimoto,et al.Zn-Fe/Zn-Ni Double-layer Electroplated Steel Sheet[J].ISIJ International,1983,23:930-938.
【3】V Barranco,S Feliu Jr,S Feliu.EIS Study of the corrosion behavior of zinc-based coatings on steel in quiescent 3% NaCl solution.Part 1:directly exposed coatings[J].Corrosion Science,2004,46:2203-2220.
【4】Cao Fa-he,Zhang Zhao,Li Jin-feng,et al.Corrosion behavior of two heat treatment Al-Zn-Mg-Cu alloys in different intergranular corrosion solution[J].Trans Nonferrous Met Soc China,2004,14(3):619-625.
【5】姜莉莉,李谋成,张文麒,等.纳米晶镀锌层在3.5% NaCl溶液中的腐蚀电化学行为[J].中国腐蚀与防护学报,2008,28(5):303-306.
【6】Sun Hu-yuan,Hou Bao-rong,Ma Shi-de,et al.Electrochemical corrosion behavior of hot-dip coating in artificial seawater[J].Chin J Oceanol Limnol,1999,17(2):181-186.
【7】曹楚南,张鉴清.电化学阻抗谱导论[M].北京:科学出版社,2002.
【8】程东妹.高强度IF钢合金化镀锌板镀层结构与性能的研究[D].钢铁研究总院,2006.
【9】Ozga P,Bielanska E.Determination of the corrosion rate of Zn and Zn-Ni layers by the EDS technique[J].Materials Chemistry and Physics,2003,81(2/3):562-565.
【2】Shingo Nomura,Hirohiko Sakai,Hidetoshi Nishimoto,et al.Zn-Fe/Zn-Ni Double-layer Electroplated Steel Sheet[J].ISIJ International,1983,23:930-938.
【3】V Barranco,S Feliu Jr,S Feliu.EIS Study of the corrosion behavior of zinc-based coatings on steel in quiescent 3% NaCl solution.Part 1:directly exposed coatings[J].Corrosion Science,2004,46:2203-2220.
【4】Cao Fa-he,Zhang Zhao,Li Jin-feng,et al.Corrosion behavior of two heat treatment Al-Zn-Mg-Cu alloys in different intergranular corrosion solution[J].Trans Nonferrous Met Soc China,2004,14(3):619-625.
【5】姜莉莉,李谋成,张文麒,等.纳米晶镀锌层在3.5% NaCl溶液中的腐蚀电化学行为[J].中国腐蚀与防护学报,2008,28(5):303-306.
【6】Sun Hu-yuan,Hou Bao-rong,Ma Shi-de,et al.Electrochemical corrosion behavior of hot-dip coating in artificial seawater[J].Chin J Oceanol Limnol,1999,17(2):181-186.
【7】曹楚南,张鉴清.电化学阻抗谱导论[M].北京:科学出版社,2002.
【8】程东妹.高强度IF钢合金化镀锌板镀层结构与性能的研究[D].钢铁研究总院,2006.
【9】Ozga P,Bielanska E.Determination of the corrosion rate of Zn and Zn-Ni layers by the EDS technique[J].Materials Chemistry and Physics,2003,81(2/3):562-565.
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