国内外耐液态锌腐蚀材料的研究现状
Research Status of Materials Resistant to Molten Zinc Corrosion at Home and Abroad
摘 要
针对熔锌锅内加热器套管材料问题,根据近些年国内外对耐液锌腐蚀材料的研究成果,可将耐锌蚀材料分为采用自身耐蚀的材料或利用金属表面处理技术提高耐蚀性两大类.由于熔融锌几乎对所有的金属都能产生强烈的腐蚀,所以整体金属材料的耐熔融锌腐蚀性较差；无机材料和粉末冶金材料虽然都具有较强的耐熔融锌腐蚀性,但是其脆性大,制备成本高昂,在实际生产中的应用受到限制.因此采用金属表面处理方法提高耐熔融锌腐蚀性将成为今后的研究重点.诸如热喷涂、渗硼法、表面涂覆等表面处理技术,均可以在保持原有金属特性的基础上提高材料表面的耐锌蚀性.最后指出了今后耐熔融锌腐蚀材料的研究发展方向.
热镀锌
内加热器
热喷涂
molten zinc corrosion
hot dip galvaninzing
inner heater
thermal spraying
Abstract
According to the recent research at home and abroad,corrosion resistant materials for inner heater in molten zinc could be divided into two kinds i.e,self corrosion resistant materials and metallic materials modified by surface treatments.The corrosion resistance of metal materials in molten zinc is not good,and inorganic materials and sintered powder metal products have a strong corrosion resistance but they are brittle and have a high cost,so that the metal surface treatment method will attract more and more interest in the future.Surface treatment techniques,such as thermal spraying,boronizing and surface coating,are able to enhance the corrosion resistance in molten zinc,and thus could maintain the original characteristics of the metal substrate.The research trend of corrosion resistant materials in molten zinc in the future is pointed out.
中图分类号 TG174.2
所属栏目 专论
基金项目 河北省自然科学基金资助项目(E2007000051);天津市重点自然科学基金资助项目
收稿日期 2008/12/26
修改稿日期 2009/3/13
网络出版日期
作者单位点击查看
备注张志彬,硕士研究生.
引用该论文: ZHANG Zhi-bin,YAN Dian-ran,HE Ji-ning,LI Sha,WANG Shi. Research Status of Materials Resistant to Molten Zinc Corrosion at Home and Abroad[J]. Corrosion & Protection, 2010, 31(1): 75～77
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【9】高扩农,李守荣.抗液态锌腐蚀材料综述[J].金属制品,2001,27(3):50-52.
【10】刘铭,肖俊明,李志强,等.我国热镀锌锅的发展[J].金属制品,1999,25(1):9-11.
【11】Tsipas D N.Degradation behaviour of boronized carbon and high alloy steels in molten aluminium and zinc[J].Mater Lett,1998,37:128.
【12】曹晓明,温鸣,韩文祥,等.稀土元素对固体渗硼层的改性作用[J].中国稀土学报,1997,15(4):350-353.
【13】李定夷,彭明华,张诗林.锌锅防腐涂料的研制与应用[J].金属制品,1989,15(2):39-42.
【14】Nippon Parkerizing Co.,Ltd..Material having corrosion resistance to molten zinc[P].JP 56016645,1981.
【15】Taiyo Steel Co.,Ltd.(JP).Immersion member for hot dip galvanizing bath and method for preparing the same[P].US 5116431,1992.
【16】Yan Dianran,He Jining,Tian Boran.The corrosion behavior of plasma sprayed Fe2Al5 coating in molten Zn[J].Surface and Coatings Technology,2006,201(6):2455.
【17】Tomoki Tomita,Yasuyuki Takatan.Durability of WC/Co sprayed coatings in molten pure zinc[J].ISIJ International,1993,33(9):982-983.
【18】Kazumi Tani,Tomoki Tomita,Yoshifumi Kobayashi,et.al.Durability of sprayed WC/Co coating in Al-added zinc bath[J].ISIJ International,1994,34(10):828-829.
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