不同表面活性剂对锌系磷化膜的影响
Influence of Different Kinds of Surfactants on Zinc Phosphate Coating
摘 要
通过测试膜重、结合力和耐碱性,研究了表面活性剂对锌系磷化膜的影响.结果表明,在磷化液中添加表面活性剂,锌系磷化膜的膜重减轻,所形成的磷化膜更加致密,晶粒更小,其结合力和耐碱性得到增强.
表面活性剂
膜重
结合力
耐碱性
zinc phosphating coating
surfactant
coating weight
adhesion
alkali resistance
Abstract
Influence of different kinds of surfactants on zinc phosphate coating was investigated by means of coating weight tests,adhesion and alkali resistance.The results showed that the surfactants in zinc phosphate solution could decrease the weight of phosphate coating.The phosphate coating formed was more compact and the crystals of the coating were finer,the adhesion and alkali resistance were enhanced after adding surfactants in zine phosphare solution.
中图分类号 TG178
所属栏目 应用技术
基金项目 河南省自然科学研究项目(2008A150016);新乡市科技发展计划(07G058)
收稿日期 2009/9/30
修改稿日期 2010/11/3
网络出版日期
作者单位点击查看
备注张圣麟,博士.
引用该论文: ZHANG Sheng-lin,ZHANG Xiao-lin,MA Qiang,LI Wei-wei,NIU Kai-li,YAO Yuan. Influence of Different Kinds of Surfactants on Zinc Phosphate Coating[J]. Corrosion & Protection, 2010, 31(8): 642～644
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参考文献
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【2】杨喜云,陈范才,赵常就.常温磷化促进剂的研究[J].表面技术,1998,27(4):18-20.
【3】Sun X,Susac D,Li R,et al.Some observations for effects of copper on zinc phosphate conversion coatings on aluminum surfaces[J].Surf Coat Technol,2002,155(4):46-50.
【4】Akhtar A S,Wong K C,Mitchell K A R.The effect of pH and role of Ni2+ in zinc phosphating of 2024-Al alloy Part I:Macroscopic studies with XPS and SEM[J].App Surf Sci,2006,253(5):493-502.
【5】Akhtar A S,Susac D,Wong P C,et al.The effect of pH and role of Ni2+ in zinc phosphating of 2024-Al alloy Part II: Microscopic studies with SEM and SAM[J].App Surf Sci,2006,253(5):502-509.
【6】Sankara Narayanan T S N,Subbaiyan M.Influence of various factors on phosphatability[J].Metal Finishing,1991,89(9):39.
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【9】张丕俭,胡玉才,殷平,等.混晶型磷化膜的制备及其耐蚀性能[J].材料保护,2008,41(12):57-58,64.
【10】李保松,林安,甘复兴,等.阴极电泳涂装用锌镍锰三元磷化液的研究[J].中国表面工程,2005,18(4):22-26.
【2】杨喜云,陈范才,赵常就.常温磷化促进剂的研究[J].表面技术,1998,27(4):18-20.
【3】Sun X,Susac D,Li R,et al.Some observations for effects of copper on zinc phosphate conversion coatings on aluminum surfaces[J].Surf Coat Technol,2002,155(4):46-50.
【4】Akhtar A S,Wong K C,Mitchell K A R.The effect of pH and role of Ni2+ in zinc phosphating of 2024-Al alloy Part I:Macroscopic studies with XPS and SEM[J].App Surf Sci,2006,253(5):493-502.
【5】Akhtar A S,Susac D,Wong P C,et al.The effect of pH and role of Ni2+ in zinc phosphating of 2024-Al alloy Part II: Microscopic studies with SEM and SAM[J].App Surf Sci,2006,253(5):502-509.
【6】Sankara Narayanan T S N,Subbaiyan M.Influence of various factors on phosphatability[J].Metal Finishing,1991,89(9):39.
【7】Nair U B,Subbaiyan M.Effect of surface treatment on a black phosphate coating for steel[J].Plating and Surface Finishing,1993,80(1):66.
【8】陈同云,古绪鹏.常温薄型轻铁-锌系磷化液及其应用[J].腐蚀与防护,1995,16(4):186-187,191.
【9】张丕俭,胡玉才,殷平,等.混晶型磷化膜的制备及其耐蚀性能[J].材料保护,2008,41(12):57-58,64.
【10】李保松,林安,甘复兴,等.阴极电泳涂装用锌镍锰三元磷化液的研究[J].中国表面工程,2005,18(4):22-26.
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