苯并三氮唑羧酸衍生物和磷酸三丁酯的摩擦学协同性能
Tribological Synergy Study of a Benzotrizole Ester Derivative and Tributhyl Phosphate
摘 要
合成了一种新型无磷苯并三氮唑衍生物(BTB),利用四球摩擦磨损试验机考察了单剂BTB、磷酸三丁酯(TBP)以及不同配比的BTB和TBP的复合添加剂在液体石蜡中的摩擦磨损性能;用带散射能谱的扫描电镜分析了磨损表面形貌和元素分布.结果表明：所合成的BTB添加剂能提高基础油的承载能力和减摩、抗磨性能,并且与TBP具有协同作用;在摩擦过程中发生物理、化学吸附的同时,与金属表面发生摩擦化学反应,生成一层复合膜,从而起到了极压抗磨作用.
磷酸三丁酯
摩擦学性能
协同作用
benzotrizole derivative
tributhyl phosphate
tribological property
synergistic effect
Abstract
A novel non-phosporus benzotrizole derivative ( BTB) was synthesized,and the tribological properties of BTB,commercial additive tributhyl phosphate (TBP) and mixtures of BTB and TBP with different mole ratios as additives in liquid paraffin were examined with four-ball tester.Worn surface morphology and element chemistry configuration of steel ball were analyzed by scanning electron microscopy with EDS.Results indicate that all additives increased the load-carrying capacity of the base oil,and possess antiwear and antifriction performances of the base oil.Combination of BTB and TBP showed synergistic effect in load-carrying,antiwear and friction-reducing in base oil.The additives reacted with counterface metal and generated a boundary lubricating and protecting film which improved tribological properties of the base oil.
中图分类号 O623.626 TH117.3
所属栏目
基金项目 江西省自然科学基金资助项目(0520091);江西省教育厅科研基金资助项目(2005120)
收稿日期 2005/5/23
修改稿日期 2005/8/29
网络出版日期
作者单位点击查看
备注刘红(1964-),女,甘肃兰州人,副教授,硕士研究生.
引用该论文: LIU Hong,XIONG Li-ping,SHI Qiu-jie. Tribological Synergy Study of a Benzotrizole Ester Derivative and Tributhyl Phosphate[J]. Materials for mechancial engineering, 2006, 30(6): 80～82
刘红,熊丽萍,石秋杰. 苯并三氮唑羧酸衍生物和磷酸三丁酯的摩擦学协同性能[J]. 机械工程材料, 2006, 30(6): 80～82
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】Zhou Guoding,Cai Shengmin,Song Liqun,et al.A comparative study of the inhibition effects of benzotriazole and 6-aniline-1,3,5-triazine-2,4-dithiol monosodium salt on the corrosion of copper by potentiodynamic polarization,AC impedance and surface-enhanced Raman spectroscopic techniques [J].Applied Surface Science,1991,52:227-234.
【2】张哓峰,韩雪峰.苯并三氮唑(BTA)在铜器文物缓蚀中的应用[J].博物馆学研究,2001,(2):98-100.
【3】张思规.精细化学品技术手册[M].北京:北京科学出版社,1992.
【4】李久盛,任天辉,张雁燕,等.苯并三氮唑及其衍生物在菜籽油中的摩擦学性能研究[J].摩擦学学报,2001,21(3):187-190.
【5】任天辉,薛群基.含氮杂环化合物及其衍生物用作多功能润滑油添加剂的研究发展现状[J].摩擦学学报,1994,14(4):370-381.
【6】苏克曼,潘铁英,张玉兰.波谱解析[M].上海:华东理工大学出版社,2002.80-132.
【7】王汝霖.润滑剂摩擦化学[M].北京:中国石化出版社,1994.
【8】Zhan W Q,Song Y P,Ren T H,et al.The tribological behaviors of some triazine-dithiocarbamate derivatives as additives in vegetable oil[J].Wear,2004,256:268-274.
【9】He Zhongyi,Xiong Liping,Zen Xiangqun,et al.Synthesis and tribology study of bi-alkoxy mono-thiophosphate triazine derivatives as additives in rapeseed oil[J].Chinese Science Bulletin,2005,50(12):1174-1179.
【2】张哓峰,韩雪峰.苯并三氮唑(BTA)在铜器文物缓蚀中的应用[J].博物馆学研究,2001,(2):98-100.
【3】张思规.精细化学品技术手册[M].北京:北京科学出版社,1992.
【4】李久盛,任天辉,张雁燕,等.苯并三氮唑及其衍生物在菜籽油中的摩擦学性能研究[J].摩擦学学报,2001,21(3):187-190.
【5】任天辉,薛群基.含氮杂环化合物及其衍生物用作多功能润滑油添加剂的研究发展现状[J].摩擦学学报,1994,14(4):370-381.
【6】苏克曼,潘铁英,张玉兰.波谱解析[M].上海:华东理工大学出版社,2002.80-132.
【7】王汝霖.润滑剂摩擦化学[M].北京:中国石化出版社,1994.
【8】Zhan W Q,Song Y P,Ren T H,et al.The tribological behaviors of some triazine-dithiocarbamate derivatives as additives in vegetable oil[J].Wear,2004,256:268-274.
【9】He Zhongyi,Xiong Liping,Zen Xiangqun,et al.Synthesis and tribology study of bi-alkoxy mono-thiophosphate triazine derivatives as additives in rapeseed oil[J].Chinese Science Bulletin,2005,50(12):1174-1179.
相关信息
