先驱体法制备连续碳化硅纤维工业化生产的现状与展望
Current Situation of the Industrialized Production of Polymer-derived Continuous SiC Fibers
摘 要
为了满足高性能复合材料的需求,国产连续碳化硅纤维工业化势在必行.综述了国内外先驱体法工业化制备连续碳化硅纤维的现状与产品特性,其中,国产超耐高温连续含铝碳化硅纤维关键技术已经突破,其稳定使用温度为1 600~1 800 ℃;氧质量分数为5%~6%的低氧含量纤维也通过两步烧成工艺制得了性能稳定的连续碳化硅纤维,其强度为2.2~2.7 GPa;并指出了连续碳化硅纤维的发展趋势.
连续碳化硅纤维
工业化生产
polymer-derived method
continuous silicon carbide fiber
industrialized production
Abstract
The continuous SiC fibers made in China must be industrialized for meeting the huge demands of high performance composites.The current situation and the properties of polymer-derived continuous SiC fibers are reviewed.Specially,the key technology of the domestic ultra high temperature resistant continuous SiC fibers had been mastered.They can be used at 1 600-1 800 ℃ steadily.That the low oxygen content continuous SiC fibers with 5%-6% oxygen content,can be prepared through two-step sintering program.Their tensile modulus with stable 2.2-2.7 GPa had been improved.The development trends of polymer-derived continuous SiC fibers are clarified.
中图分类号 TQ343
所属栏目
基金项目 国家自然科学基金重点资助项目(50532010)
收稿日期 2006/1/12
修改稿日期 2006/6/6
网络出版日期
作者单位点击查看
备注杨大祥(1977-),男,重庆人,博士研究生.
引用该论文: YANG Da-xiang,SONG Yong-cai. Current Situation of the Industrialized Production of Polymer-derived Continuous SiC Fibers[J]. Materials for mechancial engineering, 2007, 31(1): 1～4
杨大祥,宋永才. 先驱体法制备连续碳化硅纤维工业化生产的现状与展望[J]. 机械工程材料, 2007, 31(1): 1～4
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参考文献
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【2】Herzog A,Thunemann M,Vogt U,et al.Novel application of ceramic precursors for the fabrication of composites[J].J Euro Ceram Soc,2005(25):187-192.
【3】Laine R M,Babonneau F.Preceramic polymer routes to SiC[J].Chem Mater,1993,5:260-279.
【4】Naslain R.Design,preparation and properties of non-oxide CMCs for application in engines and nuclear reactors:an overview[J].Composites Science and Technology,2004(64):155-170.
【5】Fishchbach D B,Lemoine P M,Yen G V.Mechanical properties and structure of a new commercial SiC-type fiber Tyranno[J].J Mater Sci,1988,23:987-993.
【6】Kumagawa K,Yamaoka H,Shibuya M,et al.Fabrication and mechanical properties of new improved Si-M-C-(O) Tyranno fiber[J].Ceram Eng Sci Proc,1998,19(1):65-72.
【7】Riedel R,Kienzle A,Dressler W,et al.A siliconboron carbonitride ceramic stable to 2 000 ℃[J].Nature,1996,382:796-799.
【8】Baldus P,Jansen M,Sporn D.Ceramic fibers for matrix composites in high-temperature engine applications[J].Science,1999,285:699-703.
【9】Ishikawa T,Kohtoku Y,Kumagawa K,et al.High-strength alkali-resistant sintered SiC fiber stable to 2 200 ℃[J].Nature,1998,391(19):773-775.
【10】Toreki W,Batich C D,Sacks M D,et al.Polymer-derived SiC fibers with low oxygen content and improved thermomechanical stability[J].Comp Sci Technol,1994,51(2):145- 59.
【11】Zhang Z F,Scotto C S,Laine R M.Processing stoichiometric silicon carbide fibers from polymethylsilane.Part 1 Precursor fiber processing[J].J Mater Chem,1998,8:2715-2724.
【12】Hemida A,Tazi P R,Naslain R.Continuous SiC-based model monofilaments with a low free carbon content[J].J Mater Sci,1997,32(9):2359-2366.
【13】Yu Y X,Li X D,Cao F,et al.Preparation and properties of continuous Al-containing silicon carbide fibers[J].Trans Nonferrous Met Soc China,2005,15(3):510-514.
【14】Song Y C,Feng C,Tan Z,et al.Structure and properties of polytitanocarbosilane as the precursor of SiC-TiC fibre[J].J Mater Sci Lett,1990,9(11):1310-1313.
【15】Cao F,Li X D,Peng P,et al.Structural evolution and associated properties on conversion from Si-C-O-Al ceramic fibers to Si-C-Al fibers by sintering[J].J Mater Chem,2002,12(3):306-310.
【16】Chu Z Y,Song Y C,Feng C X,et al.A model SiC-based fiber with a low oxygen content prepared from a vinyl-containing polycarbosilane precursor[J].J Mater Sci Lett,2001,20(7):585-587.
【17】Yang D X,Song Y C,Mao X H,et al.The composition,structure and properties of low oxygen content SiC fibres[C]//Chengdu:CICC-4,2005.
【18】陈江溪,何国梅,何旭敏,等.碳化硅陶瓷纤维高聚物先驱体的研究进展[J].功能材料,2004,35(6):679-682.
【19】Clark T J,Jaffe M,Rabe J,et al.Thermal stability characterization of SiC fibers:I,Mechanical property and chemical structure effects[J].Ceram Eng Sci Proc,1986,7(7/8):901-913.
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