Fabrication of WC-6Co-1.5Al Hardmetals by Electric Current Sintering
摘 要
研究了WC-6Co-1.5Al硬质合金球磨粉末的电流烧结工艺对合金性能的影响.结果表明:在脉冲电流基值、峰值、频率和占空比分别为360 A,3 000 A,50 Hz和50%时,在恒流电流为1 500 A,总烧结时间为6 min,烧结压力为30 MPa的工艺参数下,采用1 min脉冲+5 min恒流电流烧结工艺,WC平均晶粒尺寸约为500 nm,合金的密度、硬度和抗弯强度分别达到最大值14.22 g/cm3,94 HRA和1 660 MPa;与1 min脉冲+5 min恒流烧结工艺相比,采用单一的恒流电流烧结,通过增大恒流强度可进一步提高最大烧结密度,但同时合金的硬度和横向断裂强度均相对降低.
Abstract
The fabrication of WC-6Co-1.5Al (wt%) hardmetals by electric current sintering from milled powders was studied.When the peak,base,repetition frequency and duty ratio of pulse electric current are prechoosed as 3 000 A,360 A,50 Hz and 50%,constant current,sintering pressure and total sintering time are prechoosed at 1 500 A,30 MPa and 6 min,the alloy has optimal properties by sintering of 1min pulse electrical current and subsequent 5 min constant electrical current.The density,hardness and transverse rupture strength of the as sintered alloy are 14.22 g/cm3,94 HRA and 1 660 MPa,respectively.The corresponding average WC grain size is about 500 nm.In the case of single constant current being supplied to sinter milled powders,the sintered density could be increased by intensifying the current,even being more than 14.22 g/cm3.However,too intensive constant current reduces the sintered density reversely.It is proved that the hardness and transverse rupture strength by single constant current sintering are lower than that by the sintering of 1min pulse- and 5min constant current.
中图分类号 TF124
所属栏目
基金项目 国家杰出青年科学基金资助项目(50325516);广东省自然科学基金资助项目(05300305)
收稿日期 2006/11/14
修改稿日期 2007/5/10
网络出版日期
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备注李小强(1972-),男,江苏扬州人,副教授,博士.
引用该论文: LI Xiao-qiang,ZHENG Feng,LI Yuan-yuan,SHAO Ming,ZHANG Jian-bing. Fabrication of WC-6Co-1.5Al Hardmetals by Electric Current Sintering[J]. Materials for mechancial engineering, 2007, 31(9): 34~36
李小强,郑峰,李元元,邵明,张建兵. 电流烧结制备WC-6Co-1.5Al硬质合金[J]. 机械工程材料, 2007, 31(9): 34~36
被引情况:
【1】贾德林,巴爱叶,任云鹏, "镍在机械合金化制备WC粉体中的加速作用",机械工程材料 32, 42-44(2008)
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参考文献
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【2】林启权,朱远志.导卫辊用WC-Co基合金微细晶粒的生成及其磨损机理[J].机械工程材料,2005,29(6):30-32,64.
【3】stberg G,Buss K,Christensen M,et al.Mechanisms of plastic deformation of WC–Co and Ti(C,N)-WC-Co[J].International Journal of Refractory Metals & Hard Materials,2006,24:135-144.
【4】Arenas F J,Matos A,Cabezas M,et al.Densification,mechanical properties and wear behavior of WC-VC-Co-Al hardmetals[J].International Journal of Refractory Metals & Hard Materials,2001,19(4/6):381-387.
【5】李晓东,王兴庆,解迎芳,等.WC-(Co-Al)硬质合金的研究[J].粉末冶金工业,2004,14(1):14-17.
【6】王兴庆,李晓东,郭海亮,等.Al含量对WC-2Co硬质合金耐腐蚀性能的影响[J].粉末冶金材料科学与工程,2006,11(4):219-224.
【7】Groza J R,Garcia M,Schneider J A.Surface effects in field-assisted sintering[J].Journal of Materials Research,2001,16(1):286-292.
【8】Seung I C,Soon H H,Byung K K.Spark plasma sintering behavior of nanocrystalline WC-10Co cemented carbide powders[J].Materials Science & Engineering A,2003,351:31-38.
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