碳纳米管的表面修饰及其应用
Surface Modification of Carbon Nanotubes and Their Application
摘 要
介绍了碳纳米管的性质和表面修饰方法,综述了近年来国内外有关碳纳米管表面修饰的研究现状,并分析了碳纳米管表面修饰的应用现状.碳纳米管具有独特的管状结构和优异的性能,是制备纳米复合材料的理想增强体之一.因为表面修饰可提高碳纳米管的表面活性、分散能力和与基体材料之间的相容性,从而提高其在复合材料中的增强效果,所以碳纳米管的表面修饰成为碳纳米管研究中的热点之一.
纳米复合材料
表面修饰
应用
carbon nanotube
nano-composite
surface modification
application
Abstract
Carbon nanotubes (CNTs) are considered as one of the ideal reinforcements for nano-composites due to their peculiar structures and superior properties.Because surface modification of CNTs can improve their surface activity,dispersion ability,and the compatibility between CNTs and base matrix,the surface modification of CNTs are one of hotspot about CNTs investigation.The properties and modified methods of CNTs are introduced,the progresses of the modification of CNTs are reviewed and its application is analyzed.
中图分类号 TB332
所属栏目
基金项目 国家自然科学基金资助项目(50372020;59972031);湖南省自然科学基金资助项目(01JJY2052)
收稿日期 2007/1/16
修改稿日期 2007/4/28
网络出版日期
作者单位点击查看
备注陈传盛(1972-),男,江西乐安人,讲师,博士.
引用该论文: CHEN Chuan-sheng,LIU Tian-gui,CHEN Xiao-hua,YE Chang,XIA Qing. Surface Modification of Carbon Nanotubes and Their Application[J]. Materials for mechancial engineering, 2007, 31(11): 1～5
陈传盛,刘天贵,陈小华,叶昌,夏靑. 碳纳米管的表面修饰及其应用[J]. 机械工程材料, 2007, 31(11): 1～5
被引情况:
【1】李鹏,刘道新,关艳英,成书民,赵远兴,曹亮,李欢, "喷丸强化对新型7055-T7751铝合金疲劳性能的影响",机械工程材料 39, 86-89(2015)
【2】张文忠,蔡晓兰,周蕾,王子阳,李铮,易峰,余明俊, "碳纳米管短切技术的研究进展",机械工程材料 38, 6-11(2014)
【3】刘华斌, "高导热碳材料研究进展",机械工程材料 37, 1-4(2013)
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参考文献
【1】成会明.纳米碳管制备、结构、物性及应用[M].北京:化学工业出版社,2002.
【2】Lau K T,David H.Effectiveness of using carbon nanotubes as nano-reinforcements for advanced composite structures[J].Carbon,2002,40:1605-1606.
【3】Tsang S C,Chen Y K,Greenm L H,et al.A simple chemical method of opening and filling carbon nanotubes[J].Nature,1994,372:159-162.
【4】Chen J,Hamon M A,Haddon R C,et al.Solution properties of single-walled carbon nanotubes[J].Science,1998,282:95-98.
【5】Huang W J,Lin Y,Taylor S,et al.Sonication-assisted functionalization and solubilization of carbon nanotubes[J].Nano Lett,2002,2(3):231-234.
【6】Qin Y J,Shi J H,Wu W,et al.Concise route to functionalized carbon nanotubes[J].J Phys Chem B,2003,107(47):12899-12901.
【7】Lin Y,Taylor S,Huang W J,et al.Characterization of fractions from repeated functionalization reactions of carbon nanotubes[J].J Phys Chem B,2003,107(47):914-919.
【8】Pompeo F,Resasco D E.Water solubilization of single-walled carbon nanotubes by functionalization with glucosamine[J].Nano Lett,2002,2(4):369-373.
【9】Chen J H,Huang Z P,Wang D Z,et al.Electrochemical synthesis of polypyrrole films over each over each of well-aligned carbon nanotubes[J].Synthetic Metals,2002,125(3):289-294.
【10】Hernadi K,Ljubovic E,Seo J W,et al.Synthesis of MWNT-based composite materials with inorganic coating[J].Acta Materialia,2003,51:1447-1452.
【11】Chen D Q,Dai L M,Gao M,et al.Plasma activation of carbon nanotube for chemical modification[J].J Phys Chem B,2001,105:618-622.
【12】Wang Y B,Iqbal Z,Mitria S.Microwave-induced rapid chemical functionalization of single-walled carbon nanotubes[J].Carbon,2005,43:1015-1020.
【13】Zhang Y,Franklin N,Chen R,et al.Metal coating on suspended carbon nanotubes and its implication to metal-tube interaction[J].Chem Phys Lett,2000,331:35-41.
【14】Ajayan P M,Iijima S.Capillarity induced filling of carbon nanotubes[J].Nature,1993,361:333-335.
【15】张滨,刘畅,成会明,等.纳米碳管内包覆外来物质的研究进展[J].新型炭材料,2003,18:174-180.
【16】Liang C H,Meng G W,Zhang L D,et al.Carbon nanotubes filled partially or completely with nickel[J].J Grys Grow,2000,218:136-139.
【17】Liu Z J,Che R,Xu Z,et al.Preparation of Fe-filled carbon nanotubes by catalytic decomposition of cyclohexane[J].Synthetic Metals,2002,128:191-195.
【18】Leonhardt A,Ritschel M,Kozhuharova R,et al.Synthesis and properties of filled carbon nanotubes[J].Diamond and Related Materials,2003,13:790-793.
【19】Mayne M,Grobert N,Terrones M,et al.Pyrolytic of aligned carbon nanotubes from homogeneously dispersed benzene-based aerosols[J].Chem Phys Lett,2001,338:101-107.
【20】Matsui K,Kyotani T,Tomita A.Hydrothermal synthesis of single crystal Ni(OH)2 nanorods in carbon-coated anodic alumina film[J].Adv Mater,2002,14:1216-1219.
【21】Mickelson E T,Huffman C B,Margrave J L,et al.Fluorination of single-wall carbon nanotubes[J].Chem Phys Lett,1998,296:188-194.
【22】Jiang K Y,Eitan A,Schadler L S,et al.Selective attachment of gold nanoparticles to nitrogen-doped carbon nanotubes[J].Nano Lett,2003,3(3):275-277.
【23】Lim J K,Yun W S,Yoon M,et al.Selectiv thiolation of single-walled carbon nanotubes[J].Synthetic Metals,2003,139:521-527.
【24】Jiang L J,Gao L.Modified carbon nanotubes:an effective way to selective attachment of gold nanoparticles[J].Carbon,2003,41:2923-2929.
【25】Banerjee S,Wong S S.Synthesis and characterization of carbon nanotube-nanocrystal heterostructures[J].Nano Lett,2002,2:195-200.
【26】Yu Y,Ma L L,Huang W Y,et al.Sonication assisted deposition of Cu2O nanoparticles on MWNTs with polyol process[J].Carbon,2005,43:670-673.
【27】Chen C S,Chen X H,Yi B,et al.Zinc oxide nanoparticle decorated multi-walled carbon nanotubes and their properties[J].Acta Materialia,2006,54:5401-5407.
【28】Islam M F,Rojas E,Bergey D M,et al.High weight fraction surfactant solubilization of single-wall carbon nanotubes in water[J].Nano Lett,2003,3(3):269-273.
【29】O′Connell M J,Boul P,Ericson,L M,et al.Reversible water-solubilization of single-walled carbon nanotubes by polymer wrapping[J].Chem Phys Lett,2001,342:265-271.
【30】Star A,Stoddart J F.Dispersion and solubilization of single-walled carbon nanotubes with a hyperbranched polymer[J].Macromolecules,2002,35:7516-7520.
【31】Liu J,Rinzler A G,Smalley R E,et al.Fullerene pipe[J].Science,1998,280:1253-1256.
【32】Chen Y,Haddon R C,Smalley R E,et al.Chemical attachment of organic functional groups to single-walled carbon nanotube materials[J].J Mater Res,1998,13(9):2423-2431.
【33】李博,廉永福,顾镇南,等.单层碳纳米管的化学修饰[J].高等学校化学学报,2000,21(11):1633-1635.
【34】Chen C S,Chen X H,Xu L S,et al.Modification of multi-walled carbon nanotubes with fatty acid and their tribological properties as lubricant additive[J].Carbon,2005,43(8):1660-1666.
【35】Rajidip B,Einat N,Regev O,et al.Noncovalent engineering of carbon nanotube surfaces by rigid,functional conjugated polymers[J].Nano Lett,2002,2(1):25-28.
【36】Qin S H,Qin D Q,Ford W T,et al.Functionalization of single-walled carbon nanotubes with polystyrene via grafting to and grafting from methods[J].Macromolecules,2004,37:752-757.
【37】Zheng M,Jagota A,Semak E,et al.DNA-assisted dispersion and separation of carbon nanotubes[J].Nature Material,2003,2:338-342.
【38】Mamedov A A,Kotov N A,et al.Molecular design of strong single-wall carbon nanotube/polyelectrolyte multilayer composites[J].Nature Materials,2002,1:190-193.
【39】Zhu J,Peng H Q,Rodriguez-Macias F,et al.Reinforcing epoxy polymer composites through covalent integration of functionalized nanotubes[J].Adv Funct Mater,2004,14(7):643-648.
【40】Cui S,Canet R,Derre A,et al.Characterization of multiwall carbon nanotubes and influence of surfactant in the nanocomposite processing[J].Carbon,2003,41:797-809.
【41】Gong X,Liu J,Baskaran S,et al.Surfactant-assisted processing of carbon nanotube/polymer composites[J].Chem Mater,2000,12:1049-1052.
【42】Ning J W,Zhang J J,Pan Y B,et al.Surfactants assisted processing of carbon nanotube-reinforced SiO2 matrix composites[J].Ceramics International,2004,30:63-67.
【43】Gojny F H,Nastalczyk J,Roslaniec Z,et al.Surface modified multi-walled carbon nanotubes in CNT/epoxy-composites[J].Chem Phys Lett,2003,370:820-824.
【44】Careno-Morelli E,Yang J,Couteau E,et al.Carbon nanotube/ magnesium composites[J].Phys Stat Sol(A),2004,201(8):53-58.
【45】Cha S I,Kyung K T,Arshad S N,et al.Extraordinary strengthening effect of carbon nanotubes in metal-matrix nanocomposites processed by molecular-level mixing[J].Adv Mater,2005,17:1377-1381.
【46】Hwang G L,Shieh Y T,Hwang K C.Efficient load transfer to polymer-grafted multi-walled carbon nanotubes in polymer composites[J].Adv Funct Mater,2004,14(5):487-491.
【47】Leonhardt A,Ritschel M,Kozhuharova R,et al.Synthesis and properties of filled carbon nanotubes[J].Diam Relat Mater,2003,12:790-793.
【48】Schneider C M,Zhao B,Kozhuharova R,et al.Towards molecular spintronics:magnetotransport and magnetism in carbon nanotube-based systems[J].Diam Relat Mater,2004,13:215-220.
【49】Yang Z H,Sang S B,Huang K L,et al.Lithium insertion into the raw multi-walled carbon nanotubes pre-doped with lithium-an electrochemical impedance study[J].Diam Relat Mater,2004,13:99-105.
【50】Bavastrello V,Carrara S,Ram M K,et al.Optical and electrochemical properties of poly(o-toluidine) multiwalled carbon nanotubes composite langmuir-schaefer films[J].Langmuir,2004,20:969-973.
【51】Takenobu T,Takano T,Shiraishi M,et al.Stable and controlled amphoteric doping by encapsulation of organic molecules inside carbon nanotubes[J].Nature Materials,2003,12:683-688.
【52】Kumar T P,Ramesh R,Lin Y Y,et al.Tin-filled carbon nanotubes as insertion anode materials for lithium-ion batteries[J].Electr Comm,2004,6:520-525.
【53】Fagan S B,Souza Filho A G,Filho J M,et al.Electronic properties of Ag-and CrO3-filled single-walled carbon nanotubes[J].Chem Phys Lett,2005,406:54-59.
【54】Valentini L,Bavastrello V,Stura E,et al.Sensors for inorganic vapor detection based on carbon nanotubes and poly(o-anisidine) nanocomposite material[J].Chem Phys Lett,2004,383:617-622.
【55】Williams K A,Veenhuizen P T M,Torre B G,et al.Carbon nanotubes with DNA recognition[J].Nature,2002,420:761-764.
【56】Hu H,Ni Y C,Montana V,et al.Chemically functionalized carbon nanotubes as substrates for neuronal growth[J].Nano Lett,2004,4:507-511.
【2】Lau K T,David H.Effectiveness of using carbon nanotubes as nano-reinforcements for advanced composite structures[J].Carbon,2002,40:1605-1606.
【3】Tsang S C,Chen Y K,Greenm L H,et al.A simple chemical method of opening and filling carbon nanotubes[J].Nature,1994,372:159-162.
【4】Chen J,Hamon M A,Haddon R C,et al.Solution properties of single-walled carbon nanotubes[J].Science,1998,282:95-98.
【5】Huang W J,Lin Y,Taylor S,et al.Sonication-assisted functionalization and solubilization of carbon nanotubes[J].Nano Lett,2002,2(3):231-234.
【6】Qin Y J,Shi J H,Wu W,et al.Concise route to functionalized carbon nanotubes[J].J Phys Chem B,2003,107(47):12899-12901.
【7】Lin Y,Taylor S,Huang W J,et al.Characterization of fractions from repeated functionalization reactions of carbon nanotubes[J].J Phys Chem B,2003,107(47):914-919.
【8】Pompeo F,Resasco D E.Water solubilization of single-walled carbon nanotubes by functionalization with glucosamine[J].Nano Lett,2002,2(4):369-373.
【9】Chen J H,Huang Z P,Wang D Z,et al.Electrochemical synthesis of polypyrrole films over each over each of well-aligned carbon nanotubes[J].Synthetic Metals,2002,125(3):289-294.
【10】Hernadi K,Ljubovic E,Seo J W,et al.Synthesis of MWNT-based composite materials with inorganic coating[J].Acta Materialia,2003,51:1447-1452.
【11】Chen D Q,Dai L M,Gao M,et al.Plasma activation of carbon nanotube for chemical modification[J].J Phys Chem B,2001,105:618-622.
【12】Wang Y B,Iqbal Z,Mitria S.Microwave-induced rapid chemical functionalization of single-walled carbon nanotubes[J].Carbon,2005,43:1015-1020.
【13】Zhang Y,Franklin N,Chen R,et al.Metal coating on suspended carbon nanotubes and its implication to metal-tube interaction[J].Chem Phys Lett,2000,331:35-41.
【14】Ajayan P M,Iijima S.Capillarity induced filling of carbon nanotubes[J].Nature,1993,361:333-335.
【15】张滨,刘畅,成会明,等.纳米碳管内包覆外来物质的研究进展[J].新型炭材料,2003,18:174-180.
【16】Liang C H,Meng G W,Zhang L D,et al.Carbon nanotubes filled partially or completely with nickel[J].J Grys Grow,2000,218:136-139.
【17】Liu Z J,Che R,Xu Z,et al.Preparation of Fe-filled carbon nanotubes by catalytic decomposition of cyclohexane[J].Synthetic Metals,2002,128:191-195.
【18】Leonhardt A,Ritschel M,Kozhuharova R,et al.Synthesis and properties of filled carbon nanotubes[J].Diamond and Related Materials,2003,13:790-793.
【19】Mayne M,Grobert N,Terrones M,et al.Pyrolytic of aligned carbon nanotubes from homogeneously dispersed benzene-based aerosols[J].Chem Phys Lett,2001,338:101-107.
【20】Matsui K,Kyotani T,Tomita A.Hydrothermal synthesis of single crystal Ni(OH)2 nanorods in carbon-coated anodic alumina film[J].Adv Mater,2002,14:1216-1219.
【21】Mickelson E T,Huffman C B,Margrave J L,et al.Fluorination of single-wall carbon nanotubes[J].Chem Phys Lett,1998,296:188-194.
【22】Jiang K Y,Eitan A,Schadler L S,et al.Selective attachment of gold nanoparticles to nitrogen-doped carbon nanotubes[J].Nano Lett,2003,3(3):275-277.
【23】Lim J K,Yun W S,Yoon M,et al.Selectiv thiolation of single-walled carbon nanotubes[J].Synthetic Metals,2003,139:521-527.
【24】Jiang L J,Gao L.Modified carbon nanotubes:an effective way to selective attachment of gold nanoparticles[J].Carbon,2003,41:2923-2929.
【25】Banerjee S,Wong S S.Synthesis and characterization of carbon nanotube-nanocrystal heterostructures[J].Nano Lett,2002,2:195-200.
【26】Yu Y,Ma L L,Huang W Y,et al.Sonication assisted deposition of Cu2O nanoparticles on MWNTs with polyol process[J].Carbon,2005,43:670-673.
【27】Chen C S,Chen X H,Yi B,et al.Zinc oxide nanoparticle decorated multi-walled carbon nanotubes and their properties[J].Acta Materialia,2006,54:5401-5407.
【28】Islam M F,Rojas E,Bergey D M,et al.High weight fraction surfactant solubilization of single-wall carbon nanotubes in water[J].Nano Lett,2003,3(3):269-273.
【29】O′Connell M J,Boul P,Ericson,L M,et al.Reversible water-solubilization of single-walled carbon nanotubes by polymer wrapping[J].Chem Phys Lett,2001,342:265-271.
【30】Star A,Stoddart J F.Dispersion and solubilization of single-walled carbon nanotubes with a hyperbranched polymer[J].Macromolecules,2002,35:7516-7520.
【31】Liu J,Rinzler A G,Smalley R E,et al.Fullerene pipe[J].Science,1998,280:1253-1256.
【32】Chen Y,Haddon R C,Smalley R E,et al.Chemical attachment of organic functional groups to single-walled carbon nanotube materials[J].J Mater Res,1998,13(9):2423-2431.
【33】李博,廉永福,顾镇南,等.单层碳纳米管的化学修饰[J].高等学校化学学报,2000,21(11):1633-1635.
【34】Chen C S,Chen X H,Xu L S,et al.Modification of multi-walled carbon nanotubes with fatty acid and their tribological properties as lubricant additive[J].Carbon,2005,43(8):1660-1666.
【35】Rajidip B,Einat N,Regev O,et al.Noncovalent engineering of carbon nanotube surfaces by rigid,functional conjugated polymers[J].Nano Lett,2002,2(1):25-28.
【36】Qin S H,Qin D Q,Ford W T,et al.Functionalization of single-walled carbon nanotubes with polystyrene via grafting to and grafting from methods[J].Macromolecules,2004,37:752-757.
【37】Zheng M,Jagota A,Semak E,et al.DNA-assisted dispersion and separation of carbon nanotubes[J].Nature Material,2003,2:338-342.
【38】Mamedov A A,Kotov N A,et al.Molecular design of strong single-wall carbon nanotube/polyelectrolyte multilayer composites[J].Nature Materials,2002,1:190-193.
【39】Zhu J,Peng H Q,Rodriguez-Macias F,et al.Reinforcing epoxy polymer composites through covalent integration of functionalized nanotubes[J].Adv Funct Mater,2004,14(7):643-648.
【40】Cui S,Canet R,Derre A,et al.Characterization of multiwall carbon nanotubes and influence of surfactant in the nanocomposite processing[J].Carbon,2003,41:797-809.
【41】Gong X,Liu J,Baskaran S,et al.Surfactant-assisted processing of carbon nanotube/polymer composites[J].Chem Mater,2000,12:1049-1052.
【42】Ning J W,Zhang J J,Pan Y B,et al.Surfactants assisted processing of carbon nanotube-reinforced SiO2 matrix composites[J].Ceramics International,2004,30:63-67.
【43】Gojny F H,Nastalczyk J,Roslaniec Z,et al.Surface modified multi-walled carbon nanotubes in CNT/epoxy-composites[J].Chem Phys Lett,2003,370:820-824.
【44】Careno-Morelli E,Yang J,Couteau E,et al.Carbon nanotube/ magnesium composites[J].Phys Stat Sol(A),2004,201(8):53-58.
【45】Cha S I,Kyung K T,Arshad S N,et al.Extraordinary strengthening effect of carbon nanotubes in metal-matrix nanocomposites processed by molecular-level mixing[J].Adv Mater,2005,17:1377-1381.
【46】Hwang G L,Shieh Y T,Hwang K C.Efficient load transfer to polymer-grafted multi-walled carbon nanotubes in polymer composites[J].Adv Funct Mater,2004,14(5):487-491.
【47】Leonhardt A,Ritschel M,Kozhuharova R,et al.Synthesis and properties of filled carbon nanotubes[J].Diam Relat Mater,2003,12:790-793.
【48】Schneider C M,Zhao B,Kozhuharova R,et al.Towards molecular spintronics:magnetotransport and magnetism in carbon nanotube-based systems[J].Diam Relat Mater,2004,13:215-220.
【49】Yang Z H,Sang S B,Huang K L,et al.Lithium insertion into the raw multi-walled carbon nanotubes pre-doped with lithium-an electrochemical impedance study[J].Diam Relat Mater,2004,13:99-105.
【50】Bavastrello V,Carrara S,Ram M K,et al.Optical and electrochemical properties of poly(o-toluidine) multiwalled carbon nanotubes composite langmuir-schaefer films[J].Langmuir,2004,20:969-973.
【51】Takenobu T,Takano T,Shiraishi M,et al.Stable and controlled amphoteric doping by encapsulation of organic molecules inside carbon nanotubes[J].Nature Materials,2003,12:683-688.
【52】Kumar T P,Ramesh R,Lin Y Y,et al.Tin-filled carbon nanotubes as insertion anode materials for lithium-ion batteries[J].Electr Comm,2004,6:520-525.
【53】Fagan S B,Souza Filho A G,Filho J M,et al.Electronic properties of Ag-and CrO3-filled single-walled carbon nanotubes[J].Chem Phys Lett,2005,406:54-59.
【54】Valentini L,Bavastrello V,Stura E,et al.Sensors for inorganic vapor detection based on carbon nanotubes and poly(o-anisidine) nanocomposite material[J].Chem Phys Lett,2004,383:617-622.
【55】Williams K A,Veenhuizen P T M,Torre B G,et al.Carbon nanotubes with DNA recognition[J].Nature,2002,420:761-764.
【56】Hu H,Ni Y C,Montana V,et al.Chemically functionalized carbon nanotubes as substrates for neuronal growth[J].Nano Lett,2004,4:507-511.
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