Anticorrosive Protection Effect of Zinc Coating on Ductile Cast Iron Pipes
摘 要
采用电化学“二电极”方法,定期测定了沥青和喷锌(130 g/m2)球墨铸铁管在5 g/L NaCl溶液中电位的变化规律,并观察记录试样损伤处首次出现红锈的时间及形貌演变.结果表明:铁的保护电位为-0.780 V,试样电位高于-0.780 V即有红锈出现;相对于沥青涂层,喷锌层对铸铁管防腐蚀提供了有效的阴极保护及自愈合保护,能使首次红锈出现的时间显著延迟.
Abstract
Bitumen painted and zinc coated (130 g/m2) ductile cast iron pipe samples with damages were immersed in 5 g/L NaCl solution,the evolution of the electrochemical potential of the samples was measured periodically using electrochemical “two-electrodes” technique,and the time to first red rusting and the morphology evolution of the damaged area were recorded.The results indicate that the protective potential of iron is -0.780 V above which red rusting will appear.Compared to bitumen painting,zinc coating can provide cast iron pipes with effective cathodic and self-healing protection,thus delaying remarkably the time to first red rusting.
中图分类号 TG143.5
所属栏目
基金项目 江苏省高新技术产业化资助项目(JH01-071)
收稿日期 2007/1/11
修改稿日期 2007/4/19
网络出版日期
作者单位点击查看
备注焦俊(1981-),男,江苏泰兴人,硕士研究生.
引用该论文: JIAO Jun,CHEN Feng,CHEN Ming-ji,Gérard NOUAIL,SUN Shu. Anticorrosive Protection Effect of Zinc Coating on Ductile Cast Iron Pipes[J]. Materials for mechancial engineering, 2007, 31(11): 76~79
焦俊,陈锋,陈名佶,Gérard NOUAIL,孙恕. 喷锌涂层对球墨铸铁管的防腐蚀保护效应[J]. 机械工程材料, 2007, 31(11): 76~79
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】罗志翔.大、中口径长距离输水管道防腐蚀技术[J].腐蚀与防护,2000,21(3):109-111.
【2】宋秀丽.国内外管道防腐的现状与发展[J].山西建筑,2002,28(9):88-89.
【3】胡志鹏,杨燕.球墨铸铁管生产、应用及防腐现状[J].中国通报,2004(Z2):38-41.
【4】Muster Tim H,Cole Ivan S.The protective nature of passivation films on zinc:surface charge[J].Corrosion Science,2004,46(9):2319-2335.
【5】张宝宏,丛文博,杨萍.金属电化学腐蚀与防护[M].北京:化学工业出版社,2005:99-163.
【6】火时中.电化学保护[M].北京:化学工业出版社,1988:16-18.
【7】魏宝明.金属腐蚀理论及应用[M].北京:化学工业出版社,1984:10-114.
【8】Barcelo G,Sarret M,Muller C,et al.Corrosion resistance and mechanical properties of zinc electrocoatings[J].Electrochimica Acta,1998,43(1/2):13-20.
【9】Wang X Y,Li D Y.Application of an electrochemical scratch technique to evaluate contributions of mechanical and electrochemical attacks to corrosive wear of materials[J].Wear,2005,259:1490-1496.
【10】Abreu C M,Izquierdo M,Keddam M,et al.Electrochemical behaviour of zinc-rich epoxy paints in 3% NaCl solution[J].Electrochimica Acta,1996,41(15):2405-2415.
【2】宋秀丽.国内外管道防腐的现状与发展[J].山西建筑,2002,28(9):88-89.
【3】胡志鹏,杨燕.球墨铸铁管生产、应用及防腐现状[J].中国通报,2004(Z2):38-41.
【4】Muster Tim H,Cole Ivan S.The protective nature of passivation films on zinc:surface charge[J].Corrosion Science,2004,46(9):2319-2335.
【5】张宝宏,丛文博,杨萍.金属电化学腐蚀与防护[M].北京:化学工业出版社,2005:99-163.
【6】火时中.电化学保护[M].北京:化学工业出版社,1988:16-18.
【7】魏宝明.金属腐蚀理论及应用[M].北京:化学工业出版社,1984:10-114.
【8】Barcelo G,Sarret M,Muller C,et al.Corrosion resistance and mechanical properties of zinc electrocoatings[J].Electrochimica Acta,1998,43(1/2):13-20.
【9】Wang X Y,Li D Y.Application of an electrochemical scratch technique to evaluate contributions of mechanical and electrochemical attacks to corrosive wear of materials[J].Wear,2005,259:1490-1496.
【10】Abreu C M,Izquierdo M,Keddam M,et al.Electrochemical behaviour of zinc-rich epoxy paints in 3% NaCl solution[J].Electrochimica Acta,1996,41(15):2405-2415.
相关信息