Preparation of Co-Mn Composite Conversion Coating on Aluminium Alloy by Cobalt Salt
摘 要
采用钴盐、高锰酸钾作为化学转化处理液的主要成分,在2024铝合金表面制备了钴-锰复合转化膜;通过正交试验优化了处理液的配方,分析了处理液成分对转化膜面密度的影响;并研究了处理液温度、pH值、处理时间等工艺参数以及润湿剂、促进剂等添加剂对转化膜表面形貌的影响.结果表明:添加高锰酸钾可以提高转化膜的成膜速率;最优处理液配方为10 g·L-1 Co(CH3CO2)2·4H2O,3 g·L-1 KMnO4,4 g·L-1 NaNO3,3 g·L-1氟化物,30 g·L-1 CH3CO2Na;最佳成膜工艺参数为处理液温度50 ℃,pH值7,处理时间20 min;润湿剂、氟化物或钒盐成膜促进剂可改善成膜效果.
Abstract
A treating bath containing cobalt salt and potassium permanganate was used to produce an environment-friendly Co-Mn composite conversion coating on 2024 aluminium alloy surface.The fomula of the treating solution was optimized with an orthogonal experiment.The influences of solution components on the coating density were analyzed.The effects of the preparing parameters,such as solution temperature,pH value and immersion time,and the additives of wetting agent and accelerators on the surface morphology of coating were also studied.The results show that the potassium permanganate could accelerate the coating deposition on aluminium alloy.The best coating could be produced in the solution composed of 10 g·L-1Co(CH3CO2)2·4H2O,3 g·L-1 KMnO4,4 g·L-1 NaNO3,3 g·L-1 fluoride and 30 g·L-1 CH3CO2Na,and treated at 50 ℃ for 20 min with the pH value of 7.It was also found that the wetting agent and accelerator of fluoride or V salt could improve the coating effect.
中图分类号 TG174.4
所属栏目 材料性能及其应用
基金项目 广东省科技计划资助项目(2007B000318 00003);佛山市科技发展专项基金资助项目(2005040153);禅城区产学研资助项目(2006B027)
收稿日期 2008/5/5
修改稿日期 2008/12/22
网络出版日期
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备注陈东初(1972-),男,江西崇义人,副教授,博士.
引用该论文: CHEN Dong-chu,GONG Wei-hui,PAN Wei-sheng,WU Jian-feng,LI Wen-fang. Preparation of Co-Mn Composite Conversion Coating on Aluminium Alloy by Cobalt Salt[J]. Materials for mechancial engineering, 2009, 33(5): 33~36
陈东初,龚伟慧,潘炜盛,吴建峰,李文芳. 铝合金表面钴盐法制备钴-锰复合转化膜[J]. 机械工程材料, 2009, 33(5): 33~36
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参考文献
【1】朱祖芳.铝合金化学转化处理技术的进展与工业应用[J].材料保护,2003,36(3):1-4.
【2】付蓉.金属铬酸盐化学转化处理的替代技术[J].汽车工艺与材料,2001(7):71-73.
【3】李国强,李荻,李久清,等.新型铝合金Ce-Mo基转化膜[J].材料工程,2001(3):6-9.
【4】李久青.铝合金表面四价铈盐转化膜及其耐蚀性[J].腐蚀科学与防护技术,1996,8(4):271-275.
【5】王成,江峰,林海潮.LY12铝合金钼酸盐转化膜研究[J].稀有金属材料与工程,2003(2):130-133.
【6】NORDLIEN J H,WALMSLEY J C,TERBERG H,et al.Formation of a zirconium-titanium based conversion layer on AA6060 aluminium[J].Surface and Coatings Technology,2002,153:72-78.
【7】BETHENCOURT M,BOTANA J,CANO J,et al.High protective environmental friendly and short-time developed conversion coatings for Aluminium alloys[J].Applied Surface Science,2002,189(1/2):162-173.
【8】BETHENCOURT M,BOTANA F J,CANO M J,et al.Advanced generation of green conversion coatings for aluminium alloys[J].Applied Surface Science,2004,238:278-281.
【9】LUNDER O,SIMENSEN C,YU Y,et al.Formation and characterization of Ti-Zr based conversion layers on AA6060 aluminium[J].Surface and Coatings Technology,2004,184(2/3):278-290.
【10】谢伟杰,李荻,郭宝兰.铝合金无铬转化膜研究[J].新技术新工艺,1998(1):36-37.
【11】HUGHES A E,GORMAN J,HARVEY T G,et al.SEM and RBS characterization of a cobalt-based conversion coating process on AA2024-T3 and AA7075-T6[J].Surface and Interface Analysis,2004,36:1585-1591.
【12】朱祖芳.铝合金阳极氧化与表面处理技术[M].北京:化学工业出版社,2004.
【2】付蓉.金属铬酸盐化学转化处理的替代技术[J].汽车工艺与材料,2001(7):71-73.
【3】李国强,李荻,李久清,等.新型铝合金Ce-Mo基转化膜[J].材料工程,2001(3):6-9.
【4】李久青.铝合金表面四价铈盐转化膜及其耐蚀性[J].腐蚀科学与防护技术,1996,8(4):271-275.
【5】王成,江峰,林海潮.LY12铝合金钼酸盐转化膜研究[J].稀有金属材料与工程,2003(2):130-133.
【6】NORDLIEN J H,WALMSLEY J C,TERBERG H,et al.Formation of a zirconium-titanium based conversion layer on AA6060 aluminium[J].Surface and Coatings Technology,2002,153:72-78.
【7】BETHENCOURT M,BOTANA J,CANO J,et al.High protective environmental friendly and short-time developed conversion coatings for Aluminium alloys[J].Applied Surface Science,2002,189(1/2):162-173.
【8】BETHENCOURT M,BOTANA F J,CANO M J,et al.Advanced generation of green conversion coatings for aluminium alloys[J].Applied Surface Science,2004,238:278-281.
【9】LUNDER O,SIMENSEN C,YU Y,et al.Formation and characterization of Ti-Zr based conversion layers on AA6060 aluminium[J].Surface and Coatings Technology,2004,184(2/3):278-290.
【10】谢伟杰,李荻,郭宝兰.铝合金无铬转化膜研究[J].新技术新工艺,1998(1):36-37.
【11】HUGHES A E,GORMAN J,HARVEY T G,et al.SEM and RBS characterization of a cobalt-based conversion coating process on AA2024-T3 and AA7075-T6[J].Surface and Interface Analysis,2004,36:1585-1591.
【12】朱祖芳.铝合金阳极氧化与表面处理技术[M].北京:化学工业出版社,2004.
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