超声波对Ni-ZrO2纳米复合镀层微观结构和显微硬度的影响
Effect of Ultrasonic on Microstructure and Microhardness of Ni-ZrO2 Nanocomposite Coating
摘 要
在超声作用条件下以复合电镀法制备了Ni-ZrO2纳米复合镀层,用X射线衍射仪和扫描电镜分别对镀层的结晶取向和表面形貌等微观结构进行了分析,并对镀层的显微硬度进行了测试.结果表明:与不加超声相比,在超声作用下制备的Ni-ZrO2纳米复合镀层也在(2 0 0)晶面形成择优取向,但其晶面相对织构系数明显提高,达到93%;由于超声强力搅拌和超声空化效应,在超声作用下制备的Ni-ZrO2纳米复合镀层的晶粒尺寸细小、组织均匀致密;其显微硬度较高,达到602 HV,比无超声(497 HV)时的有大幅度提高.
纳米复合镀层
ZrO2纳米颗粒
微观结构
显微硬度
ultrasonic
nanocomposite coating
ZrO2 nanoparticle
microstructure
microhardness
Abstract
Ni-ZrO2 nanocomposite coating was prepared by composite electro-plating method under ultrasonic effect condition.The crystal orientation and surface morphology of the composite coating were analyzed by XRD and SEM.The microhardness of the coating was tested.The results show that compared with the coating without ultrasonic the preferential orientation of the Ni-ZrO2 nanocomposite coating prepared under ultrasonic condition was formed in(200)crystal face,the relative texture coefficient of the crystal face was significantly increased which was up to 93%.Owing to ultrasonic violent agitation and ultrasonic cavitation effect,the Ni-ZrO2 nanocomposite coating had refined crystal grain,compact microstructure and high microhardness,which reached 602 HV and was much higher than without ultrasonic(497 HV).
中图分类号 TQ153.4
所属栏目 纳米材料
基金项目 国家自然科学基金资助项目(50775067);教育部科学技术研究重点项目(208079)
收稿日期 2009/6/3
修改稿日期 2009/12/29
网络出版日期
作者单位点击查看
备注申晨(1985-),男,河南商丘人,硕士研究生.
引用该论文: SHEN Chen,XUE Yu-jun,KU Xiang-chen,LIU Yi,LI Ji-shun. Effect of Ultrasonic on Microstructure and Microhardness of Ni-ZrO2 Nanocomposite Coating[J]. Materials for mechancial engineering, 2010, 34(7): 80～83
申晨,薛玉君,库祥臣,刘义,李济顺. 超声波对Ni-ZrO2纳米复合镀层微观结构和显微硬度的影响[J]. 机械工程材料, 2010, 34(7): 80～83
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参考文献
【1】兰明明,薛玉君,段明德,等.脉冲电铸制备纳米CeO2增强镍基复合材料[J].机械工程材料,2009,33(1):33-36.
【2】MOLLER A,HAHN H.Synthesis and characterization of nanocrystalline Ni/ZrO2 composite coatings[J].Nanostructured Materials,1999,12:259-262.
【3】WANG Wei,HOU Feng-yan,WANG Hui,et al.Fabrication and characterization of Ni-ZrO2 composite nano-coatings by pulse electrodeposition[J].Scripta Materialia,2005,53:613-618.
【4】薛玉君,朱荻,靳广虎,等.电沉积Ni-La2O3纳米复合镀层的摩擦磨损性能[J].摩擦学学报,2005,25(1):1-6.
【5】CHANG L M,GUO H F,AN M Z.Electrodeposition of Ni-Co/Al2O3 composite coating by pulse reverse method under ultra-sonic condition[J].Materials Letters,2008,62:3313-3315.
【6】XIA Fa-feng,WU Meng-hua,WANG Fan,et al.Nanocomposite Ni-TiN coatings prepared by ultrasonic electrodeposition[J].Current Applied Physics,2009,9:44-47.
【7】ZHENG Huan-yu,MAO Zhong-an,LU Jun-feng.Surface cha-racterization of the Zn-Ni-Al2O3 nanocomposite coating fabricated under ultrasound condition[J].Applied Surface Science,2008,254:1644-1650.
【8】HOU Feng-yan,WANG Wei,GUO He-tong.Effect of the dispersibility of ZrO2 nanoparticles in Ni-ZrO2 electroplated nanocomposite coatings on the mechanical properties of nanocom-posite coatings[J].Applied Surface Science,2006,252:3812-3817.
【9】GYFTOU P,PAVLATOU E A,SPYRELLIS N.Effect of pulse electrodeposition parameters on the properties of Ni/nano-SiC composites[J].Applied Surface Science,2008,254:5910-5916.
【10】VAEZI M R,SADRNEZHAAD S K,NIKZAD L.Electrodeposition of Ni-SiC nano-composite coatings and evaluation of wear and corrosion resistance and electroplating characte-ristics[J].Colloids and Surfaces,2008,315:176-182.
【11】YUE G H,PENG D L,YAN P X,et al.Structure and optical properties of SnS thin film prepared by pulse electrodeposition[J].Alloys and Compounds,2009,468:254-257.
【12】杨艳玲,申勇峰,陈进耿,等.超声波搅拌脉冲电镀法制备纳米镍[J].金属学报,2007,43(8):883-888.
【13】ZHENG Huan-yu,AN Mao-zhong.Electrodeposition of Zn-Ni-Al2O3 nanocomposite coatings under ultrasound conditions[J].Alloys and Compounds,2008,459:548-552.
【14】李济顺,薛玉君,兰明明,等.超声波对Ni-CeO2纳米复合电铸层微观结构和性能的影响[J].中国有色金属学报,2009,19(3):517-522.
【15】GORDON L M,BOUWHUIS B A,SURALVO M,et al.Micro-truss nanocrystalline Ni hybrids[J].Acta Materialia,2009,57:932-939.
【16】ZHENG Yan-zhen,DING Hai-yang,ZHANG Mi-lin.Preparation and electrochemical properties of nickel oxide as a super-capacitor electrode material[J].Materials Research Bulletin,2009,44:403-407.
【2】MOLLER A,HAHN H.Synthesis and characterization of nanocrystalline Ni/ZrO2 composite coatings[J].Nanostructured Materials,1999,12:259-262.
【3】WANG Wei,HOU Feng-yan,WANG Hui,et al.Fabrication and characterization of Ni-ZrO2 composite nano-coatings by pulse electrodeposition[J].Scripta Materialia,2005,53:613-618.
【4】薛玉君,朱荻,靳广虎,等.电沉积Ni-La2O3纳米复合镀层的摩擦磨损性能[J].摩擦学学报,2005,25(1):1-6.
【5】CHANG L M,GUO H F,AN M Z.Electrodeposition of Ni-Co/Al2O3 composite coating by pulse reverse method under ultra-sonic condition[J].Materials Letters,2008,62:3313-3315.
【6】XIA Fa-feng,WU Meng-hua,WANG Fan,et al.Nanocomposite Ni-TiN coatings prepared by ultrasonic electrodeposition[J].Current Applied Physics,2009,9:44-47.
【7】ZHENG Huan-yu,MAO Zhong-an,LU Jun-feng.Surface cha-racterization of the Zn-Ni-Al2O3 nanocomposite coating fabricated under ultrasound condition[J].Applied Surface Science,2008,254:1644-1650.
【8】HOU Feng-yan,WANG Wei,GUO He-tong.Effect of the dispersibility of ZrO2 nanoparticles in Ni-ZrO2 electroplated nanocomposite coatings on the mechanical properties of nanocom-posite coatings[J].Applied Surface Science,2006,252:3812-3817.
【9】GYFTOU P,PAVLATOU E A,SPYRELLIS N.Effect of pulse electrodeposition parameters on the properties of Ni/nano-SiC composites[J].Applied Surface Science,2008,254:5910-5916.
【10】VAEZI M R,SADRNEZHAAD S K,NIKZAD L.Electrodeposition of Ni-SiC nano-composite coatings and evaluation of wear and corrosion resistance and electroplating characte-ristics[J].Colloids and Surfaces,2008,315:176-182.
【11】YUE G H,PENG D L,YAN P X,et al.Structure and optical properties of SnS thin film prepared by pulse electrodeposition[J].Alloys and Compounds,2009,468:254-257.
【12】杨艳玲,申勇峰,陈进耿,等.超声波搅拌脉冲电镀法制备纳米镍[J].金属学报,2007,43(8):883-888.
【13】ZHENG Huan-yu,AN Mao-zhong.Electrodeposition of Zn-Ni-Al2O3 nanocomposite coatings under ultrasound conditions[J].Alloys and Compounds,2008,459:548-552.
【14】李济顺,薛玉君,兰明明,等.超声波对Ni-CeO2纳米复合电铸层微观结构和性能的影响[J].中国有色金属学报,2009,19(3):517-522.
【15】GORDON L M,BOUWHUIS B A,SURALVO M,et al.Micro-truss nanocrystalline Ni hybrids[J].Acta Materialia,2009,57:932-939.
【16】ZHENG Yan-zhen,DING Hai-yang,ZHANG Mi-lin.Preparation and electrochemical properties of nickel oxide as a super-capacitor electrode material[J].Materials Research Bulletin,2009,44:403-407.
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