Structure and Properties of Porous NiTi Alloy Fabricated by Using New Stearic Acid Pore-Forming Agent
摘 要
采用可低温分解的硬脂酸颗粒为造孔剂结合梯级粉末烧结法制备了多孔Ni50.8Ti49.2合金,分析了其孔隙形貌、相变温度及力学性能等,并与采用碳酸氢铵和尿素造孔剂的多孔合金进行了比较.结果表明:采用硬脂酸造孔剂制备的多孔NiTi合金的孔隙接近球形、边缘圆整,孔隙率可控,合金具有优良的力学性能和稳定的线性超弹性;随着孔隙率的增大,其相变温度降低,抗压强度下降明显,形状回复率也降低;与另两种造孔剂相比,相同孔隙率下,采用硬脂酸造孔剂制备的多孔合金的力学性能较优,但形状记忆效应较差.
Abstract
Porous Ni50.8Ti49.2 alloy was prepared using low-temperature decomposable stearic acid particles as pore-forming agent through cascaded powder sintering process.The pore morphology,phase transformation temperature and mechanical properties were studied and compared with those of the alloys fabricated using NH4HCO3 and CO(NH2)2 pore-forming agents.The results show that the porous NiTi alloy fabricated using the stearic acid had nearly spherical,edge round pores and controllable porosity,and its mechanical properties were good and linear superelasticity was stable.Its phase transformation temperatures decreased with the increasing porosity,both the compression strength and shape recovery rate decreased.Compared with the other two pore-forming agents,when the porosity was the same,the porous alloy fabricated by using stearic acid had better mechanical properties,but worse shape memory effect.
中图分类号 TB383
所属栏目 新材料 新工艺
基金项目 国家自然科学基金资助项目(50671037,50871039)
收稿日期 2009/10/11
修改稿日期 2010/6/13
网络出版日期
作者单位点击查看
备注关锐峰(1986-),男,广东梅州人,硕士研究生.
引用该论文: GUAN Rui-feng,LI Da-sheng,ZHANG Xin-ping. Structure and Properties of Porous NiTi Alloy Fabricated by Using New Stearic Acid Pore-Forming Agent[J]. Materials for mechancial engineering, 2010, 34(11): 37~41
关锐峰,李大圣,张新平. 采用新型硬脂酸造孔剂烧结制备多孔NiTi合金的结构及性能[J]. 机械工程材料, 2010, 34(11): 37~41
被引情况:
【1】李大圣, "熔渗法制备高强Mg(AZ91D)/NiTi阻尼复合材料及其压缩和阻尼性能",机械工程材料 37, 37-42(2013)
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】李丙运,戎利建,李依依.生物医用多孔Ti-Ni形状记忆合金的研究进展[J].材料研究学报,2000,14(6):561-567.
【2】张新平,张宇鹏.多孔NiTi形状记忆合金研究进展[J].材料研究学报,2007,21(6):561-569.
【3】张宇鹏,张新平,钟志源.梯度孔隙率与大孔隙尺寸NiTi形状记忆合金的制备及其相变和超弹性行为[J].金属学报,2007,43(11):1221-1227.
【4】张新平,张宇鹏,钟志源,等.一种具有梯度孔隙率镍钛形状记忆合金的制备方法:中国.CN10103868[P].2007-07-25.
【5】LI D S,ZHANG Y P,EGGELER G,et al.High porosity and high-strength porous NiTi shape memory alloys with contro-llable pore characteristics[J].Journal of Alloys and Compounds,2009,470:1-5.
【6】ZHANG Y P,YUAN B,ZENG M Q,et al.High porosity and large pore size shape memory alloys fabricated by using pore-forming agent (NH4HCO3) and capsule-free hot isostatic pressing[J].Journal of Materials Processing Technology,2007,192/193:439-442.
【7】ASTM E9-89a.Test methods of compression testing of meta-llic materials at room temperature[S].
【8】吴承建,陈国良,强文江.金属材料学[M].北京:冶金工业出版社,2006.
【9】郑玉峰,赵连城.生物医用镍钛合金[M].北京:科学出版社,2004.
【10】徐祖耀,江伯鸿.形状记忆材料[M].上海:上海交通大学出版社,2000.
【11】舟久保,熙康.形状记忆合金[M].北京:机械工业出版社,1992.
【2】张新平,张宇鹏.多孔NiTi形状记忆合金研究进展[J].材料研究学报,2007,21(6):561-569.
【3】张宇鹏,张新平,钟志源.梯度孔隙率与大孔隙尺寸NiTi形状记忆合金的制备及其相变和超弹性行为[J].金属学报,2007,43(11):1221-1227.
【4】张新平,张宇鹏,钟志源,等.一种具有梯度孔隙率镍钛形状记忆合金的制备方法:中国.CN10103868[P].2007-07-25.
【5】LI D S,ZHANG Y P,EGGELER G,et al.High porosity and high-strength porous NiTi shape memory alloys with contro-llable pore characteristics[J].Journal of Alloys and Compounds,2009,470:1-5.
【6】ZHANG Y P,YUAN B,ZENG M Q,et al.High porosity and large pore size shape memory alloys fabricated by using pore-forming agent (NH4HCO3) and capsule-free hot isostatic pressing[J].Journal of Materials Processing Technology,2007,192/193:439-442.
【7】ASTM E9-89a.Test methods of compression testing of meta-llic materials at room temperature[S].
【8】吴承建,陈国良,强文江.金属材料学[M].北京:冶金工业出版社,2006.
【9】郑玉峰,赵连城.生物医用镍钛合金[M].北京:科学出版社,2004.
【10】徐祖耀,江伯鸿.形状记忆材料[M].上海:上海交通大学出版社,2000.
【11】舟久保,熙康.形状记忆合金[M].北京:机械工业出版社,1992.
相关信息