阳极氧化法制备高度有序TiO2纳米管阵列材料的研究进展
Recent Progress of Highly Ordered TiO2 Nanotube Array Materials Prepared by Anodic Oxidation Method
摘 要
综述了阳极氧化法制备TiO2纳米管阵列(TNTs)的研究进展。主要介绍了TNTs由恒电压合成到变电压阳极氧化制备的发展历程, 还介绍了电压、电流、电解液组成等因素对TNTs形貌的影响, 并比较了不同电解液中TNTs的形成机理。
阳极氧化
变电压
合成机理
TiO2 nanotube
anodic oxidation method
alternating voltage
formation mechanism
Abstract
The recent progresses on TiO2 nanotubes arrays (TNTs) prepared by anodic oxidation progress are reviewed. The evolution of TNTs anodic oxidation preparation from constant voltage to alternating voltage is introduced. The effects of some factors such as voltage, current, electrolyte composition on morphology of TNTs are also introduced. The formation mechanisms of TNTs prepared in various electrolytes are compared.
中图分类号 O614.3 DOI 10.11973/jxgccl201509001
所属栏目 综述
基金项目 上海市自然科学基金资助项目(14ZR1429300)
收稿日期 2014/7/3
修改稿日期 2015/7/17
网络出版日期
作者单位点击查看
备注张丽娜(1988-), 女, 河北沧州人, 硕士研究生。
引用该论文: ZHANG Li-na,JI Ya-jun,WU Da-hui,JIA Yan-chen,ZHOU Shi-lin. Recent Progress of Highly Ordered TiO2 Nanotube Array Materials Prepared by Anodic Oxidation Method[J]. Materials for mechancial engineering, 2015, 39(9): 1～5
张丽娜,计亚军,吴大辉,贾延臣,周仕林. 阳极氧化法制备高度有序TiO2纳米管阵列材料的研究进展[J]. 机械工程材料, 2015, 39(9): 1～5
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参考文献
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【27】LEI Bing-xin, LUO Qiu-ping, SUN Zhen-fan, et al. Fabrication of partially crystalline TiO2 nanotube arrays using 1, 2-propanediol electrolytes and application in dye-sensitized solar cells[J]. Advanced Powder Technology, 2013, 24(1): 175-182.
【28】PAULOSE M, SHANKAR K, YORIYA S, et al. Anodic growth of highly ordered TiO2 nanotube arrays to 134 μm in length[J]. The Journal of Physical Chemistry: B, 2006, 110(33): 16179-16184.
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【30】WEI W, KIRCHGEORG R, LEE K, et al. Nitrates: a new class of electrolytes for the rapid anodic growth of self-ordered oxide nanopore layers on Ti and Ta[J]. Physica Status Solidi (RRL)-Rapid Research Letters, 2011, 5(10/11): 394-396.
【31】WENDER H, FEIL A F, DIAZ L B, et al. Self-organized TiO2 nanotube arrays: Synthesis by anodization in an ionic liquid and assessment of photocatalytic properties[J]. ACS Applied Materials & Interfaces, 2011, 3(4): 1359-1365.
【32】SO S, LEE K, SCHMUKI P. Ultrafast growth of highly ordered anodic TiO2 nanotubes in lactic acid electrolytes[J]. Journal of the American Chemical Society, 2012, 134(28): 11316-11318.
【33】SREEKANTAN S, WEI L C, LOCKMAN Z. Extremely fast growth rate of TiO2 nanotube arrays in electrochemical bath containing H2O2[J]. Journal of the Electrochemical Society, 2011, 158(12): C397-C402.
【34】WANG Yan, WU Yu-cheng, QIN Yong-qiang, et al. Rapid anodic oxidation of highly ordered TiO2 nanotube arrays[J]. Journal of Alloys and Compounds, 2011, 509(14): L157-L160.
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【36】SANCHEZ-TOVAR R, LEE K, GARCA-ANTN J, et al. Formation of anodic TiO2 nanotube or nanosponge morphology determined by the electrolyte hydrodynamic conditions[J]. Electrochemistry Communications, 2013, 26: 1-4.
【2】WEIR A, WESTERHOFF P, FABRICIUS L, et al. Titanium dioxide nanoparticles in food and personal care products[J]. Environmental Science & Technology, 2012, 46(4): 2242-2250.
【3】TEKIN D, SAYGI B. Photoelectrocatalytic decomposition of acid black 1 dye using TiO2 nanotubes[J]. Journal of Environmental Chemical Engineering, 2013, 1(4): 1057-1061.
【4】李晓红, 张校刚, 力虎林. TiO2纳米管的模板法制备及表征[J]. 高等学校化学学报, 2001, 22(1): 130-132.
【5】李纲, 刘中清, 张昭, 等. 水热法制备TiO2纳米管阵列[J]. 催化学报, 2009, 30(1): 37-42.
【6】朱伟庆, 王树林, 高乾. 阳极氧化法制备有序TiO2纳米管阵列[J]. 上海理工大学学报, 2010, 32(3): 256-258.
【7】田甜, 王凡, 袁永健, 等. TiO2 纳米管阵列阳极氧化制备的研究进展[J]. 材料导报, 2013(7): 11-15.
【8】LI Yin-chang, MA Qun, HAN Jun, et al.Controllable preparation, growth mechanism and the properties research of TiO2 nanotube arrays[J]. Applied Surface Science, 2014, 297: 103-108.
【9】KIM D, GHICOV A, ALBU S P, et al. Bamboo-type TiO2 nanotubes: improved conversion efficiency in dye-sensitized solar cells[J]. Journal of the American Chemical Society, 2008, 130(49): 16454-16455.
【10】LUAN Xin-ning, GUAN Dong-sheng, WANG Ying. Facile synthesis and morphology control of bamboo-type TiO2 nanotube arrays for high-efficiency dye-sensitized solar cells[J]. The Journal of Physical Chemistry: C, 2012, 116(27): 14257-14263.
【11】ALBU S P, GHICOV A, ALDABERGENOVA S, et al. Formation of double-walled TiO2 nanotubes and robust anatase membranes[J]. Advanced Materials, 2008, 20(21): 4135-4139.
【12】JI Ya-jun, LIN Keng-chu, ZHENG He-gen, et al. Fabrication of double-walled TiO2 nanotubes with bamboo morphology via one-step alternating voltage anodization[J]. Electrochemistry Communications, 2011, 13(9): 1013-1015.
【13】JI Ya-jun, ZHANG Ming-dao, CUI Jie-hu, et al. Highly-ordered TiO2 nanotube arrays with double-walled and bamboo-type structures in dye-sensitized solar cells[J]. Nano Energy, 2012, 1(6): 796-804.
【14】LIN J, LIU K, CHEN X. Synthesis of periodically structured titania nanotube films and their potential for photonic applications[J]. Small, 2011, 7(13): 1784-1789.
【15】XIE Yu-long, LI Zi-xia, XU Hua, et al. Fabrication of TiO2 nanotubes with extended periodical morphology by alternating-current anodization[J]. Electrochemistry Communications, 2012, 17: 34-37.
【16】GUI Qun-fang, YU Dong-liang, ZHANG Shao-yu, et al. Influence of anodizing voltage mode on the nanostructure of TiO2 nanotubes[J]. Journal of Solid State Electrochemistry, 2014, 18(1): 141-148.
【17】GONG D, GRIMES C A, VARGHESE O K, et al. Titanium oxide nanotube arrays prepared by anodic oxidation[J]. Journal of Materials Research, 2001, 16(12): 3331-3334.
【18】MOR G K, VARGHESE O K, PAULOSE M, et al. Fabrication of tapered, conical-shaped titania nanotubes[J]. Journal of Materials Research, 2003, 18(11): 2588-2593.
【19】MACAK J M, SIROTNA K, SCHMUKI P. Self-organized porous titanium oxide prepared in Na2SO4/NaF electrolytes[J]. Electrochimica Acta, 2005, 50(18): 3679-3684.
【20】JAROENWORALUCK A, REGONINI D, BOWEN C R, et al. Macro, micro and nanostructure of TiO2 anodised films prepared in a fluorine-containing electrolyte[J]. Journal of Materials Science, 2007, 42(16): 6729-6734.
【21】REGONINI D, BOWEN C R, JAROENWORALUCK A, et al. A review of growth mechanism, structure and crystallinity of anodized TiO2 nanotubes[J]. Materials Science and Engineering: R: Reports, 2013, 74(12): 377-406.
【22】SHANKAR K, MOR G K, PRAKASAM H E, et al. Highly-ordered TiO2 nanotube arrays up to 220 μm in length: use in water photoelectrolysis and dye-sensitized solar cells[J/OL]. Nanotechnology, 2007, 18(6): 065707[2014-07-03].http://iopscience.iop.org/0957-4484/18/6/065707.DOI:10.1088/0957-4484/18/6/065707.
【23】PAULOSE M, PRAKASAM H E, VARGHESE O K, et al. TiO2 nanotube arrays of 1000 μm length by anodization of titanium foil: phenol red diffusion[J]. The Journal of Physical Chemistry: C, 2007, 111(41): 14992-14997.
【24】BERGER S, KUNZE J, SCHMUKI P, et al. A lithographic approach to determine volume expansion factors during anodization: using the example of initiation and growth of TiO2 nanotubes[J]. Electrochimica Acta, 2009, 54(24): 5942-5948.
【25】MACA K J M, TSUCHIYA H, GHICOV A, et al. Dye-sensitized anodic TiO2 nanotubes[J]. Electrochemistry Communications, 2005, 7(11): 1133-1137.
【26】PAULOSE M, SHANKAR K, VARGHESE O K, et al. Backside illuminated dye-sensitized solar cells based on titania nanotube array electrodes[J]. Nanotechnology, 2006, 17(5): 1446-1448.
【27】LEI Bing-xin, LUO Qiu-ping, SUN Zhen-fan, et al. Fabrication of partially crystalline TiO2 nanotube arrays using 1, 2-propanediol electrolytes and application in dye-sensitized solar cells[J]. Advanced Powder Technology, 2013, 24(1): 175-182.
【28】PAULOSE M, SHANKAR K, YORIYA S, et al. Anodic growth of highly ordered TiO2 nanotube arrays to 134 μm in length[J]. The Journal of Physical Chemistry: B, 2006, 110(33): 16179-16184.
【29】FAHIM N F, SEKINO T. A novel method for synthesis of titania nanotube powders using rapid breakdown anodization[J]. Chemistry of Materials, 2009, 21(9): 1967-1979.
【30】WEI W, KIRCHGEORG R, LEE K, et al. Nitrates: a new class of electrolytes for the rapid anodic growth of self-ordered oxide nanopore layers on Ti and Ta[J]. Physica Status Solidi (RRL)-Rapid Research Letters, 2011, 5(10/11): 394-396.
【31】WENDER H, FEIL A F, DIAZ L B, et al. Self-organized TiO2 nanotube arrays: Synthesis by anodization in an ionic liquid and assessment of photocatalytic properties[J]. ACS Applied Materials & Interfaces, 2011, 3(4): 1359-1365.
【32】SO S, LEE K, SCHMUKI P. Ultrafast growth of highly ordered anodic TiO2 nanotubes in lactic acid electrolytes[J]. Journal of the American Chemical Society, 2012, 134(28): 11316-11318.
【33】SREEKANTAN S, WEI L C, LOCKMAN Z. Extremely fast growth rate of TiO2 nanotube arrays in electrochemical bath containing H2O2[J]. Journal of the Electrochemical Society, 2011, 158(12): C397-C402.
【34】WANG Yan, WU Yu-cheng, QIN Yong-qiang, et al. Rapid anodic oxidation of highly ordered TiO2 nanotube arrays[J]. Journal of Alloys and Compounds, 2011, 509(14): L157-L160.
【35】KOJIMA R, KIMURA Y, NIWANO M. Influence of the electrolyte composition on formation process and morphology of anodic titanium oxide nanotubes[C]//ECS Meeting Abstracts.[S.l]:The Electrochemical Society, 2013 (2): 109-109.
【36】SANCHEZ-TOVAR R, LEE K, GARCA-ANTN J, et al. Formation of anodic TiO2 nanotube or nanosponge morphology determined by the electrolyte hydrodynamic conditions[J]. Electrochemistry Communications, 2013, 26: 1-4.
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