Preparation of Ferrous/Polyacrylonitrile Composite Nanofibers by Electrostatic Spinning and Its Application for Cr(Ⅵ) Adsorption
摘 要
利用静电纺丝技术制备了铁(Ⅱ)/聚丙烯腈[Fe(Ⅱ)/PAN]复合纳米纤维,用于吸附检测溶液中的铬(Ⅵ)。SEM及BET分析可知,纤维形态结构均匀,直径大约为153 nm,比表面积为14.0 m2·g-1。Fe(Ⅱ)/PAN复合纳米纤维表面携带的PAN…Fe(Ⅱ)(OH)+官能团能快速吸附去除溶液中的铬(Ⅵ),并将其还原为铬(Ⅲ)。根据吸附等温线模型分析,Langmuir模型更适合本体系,最大吸附量为5.40 mg·g-1。在优化的试验条件下,97%的铬(Ⅵ)可被从溶液中去除。
Abstract
Ferrous chloride/polyacrylonitrile composite nanofibers were prepared by electrostatic spinning, and applied to the determination of Cr(Ⅵ) in a solution. As shown by the results of SEM and BET analysis, the composite nanofibers obtained had an uniform morphology and structure and a large specific surface area of 14.0 m2·g-1 with diameters around 153 nm. The functional groups of PAN…Fe(Ⅱ)(OH)+ on the surface of the composite nanofibers behaved to adsorb and remove Cr(Ⅵ) ions from a solution quidkly, in the course of which Cr(Ⅵ) ions were reduced to Cr(Ⅲ). The results of the adsorption isotherm experiment showed that the data fitted well to the Langmuir isotherm model. The maximum amount of adsorption of Cr(Ⅵ) was found to be 54 mg·g-1. Under the maximum condition, 97% of Cr(Ⅵ) in the solution could be removed.
中图分类号 O65 DOI 10.11973/lhjy-hx201509025
所属栏目 工作简报
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收稿日期 2014/12/12
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联系人作者张帅(316135328@qq.com)
备注刘芳(1987-),女,山东威海人,硕士研究生,主要 从事废水中重金属及染料的检测处理研究。
引用该论文: LIU Fang,ZHOU Shi-lin,WU Da-hui,ZHANG Li-na,DU Shuai,ZHANG Shuai,CHANG Chang-tang. Preparation of Ferrous/Polyacrylonitrile Composite Nanofibers by Electrostatic Spinning and Its Application for Cr(Ⅵ) Adsorption[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2015, 51(9): 1311~1315
刘芳,周仕林,吴大辉,张丽娜,杜帅,张帅,张章堂. 静电纺丝制备铁(Ⅱ)/聚丙烯腈复合纳米纤维及其应用于吸附铬(Ⅵ)[J]. 理化检验-化学分册, 2015, 51(9): 1311~1315
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【8】廖师琴,魏取福.PAN纳米纤维的改性及其应用于吸附金属离子[J].化工新型材料, 2014(12):89-94.
【9】MAHAPATRA A, MISHRA B G, HOTA G. Electrospun Fe2O3-Al2O3 nanocomposite fibers as efficient adsorbent for removal of heavy metal ions form aqueous solution[J]. Journal of Hazardous Materials, 2013,258:116-123.
【10】徐方亮,徐影,余灯广.聚合物稀溶液环流同轴电纺制备药物零级控释纳米纤维[J].上海理工大学学报, 2015,37(2):21-25.
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