Fracture Pattern of PPS Impact Sample under Different Temperature
摘 要
对聚苯硫醚(PPS)工程塑料的冲击断口形貌进行了宏观和微观观察,总结了PPS冲击断口的典型形貌特征,并研究了各典型形貌随试验温度的变化规律。宏观断口分析表明:当t<60℃时,断口由平坦区、放射区和最后断裂区组成;当 t≥60℃时,断口非常平坦,除少量人字形放射条纹外几乎观察不到其他形貌特征。微观断口分析和定量测试表明:平坦区微观典型形貌为岩石层状,随温度的升高,岩石层的片层尺寸和粗糙度都越来越大。在-196℃≤t≤-60℃时,放射区的放射状条纹数量较多且细密,当-60℃<t≤20℃时,放射状条纹数量逐渐减少,放射状片层粗糙不平,呈细密的岩石状形貌。最后断裂区可观察到弧形条纹(裂纹中止线)和河流花样。t<60℃时PPS发生脆性断裂,随温度升高,平坦区面积增大,缺口冲击强度线性增高。
Abstract
The fractographic features of notched impact PPS specimens at different impact temperature had been studied systematically both by the macroscopic and microscopic observation. The typical morphology and its changing regularity with the impact temperature had been concluded. The macroscopic study showed that,when the impact temperature is lower than 60℃,the fracture surface can be divided into the flat zone,the radiation zone and the last fracture zone. When the impact temperature is higher than 60℃,the fracture surface is rather flat,and nothing could be observed except for several radiation stripes. The microscopic study and the quantitative measurement showed that,the typical morphology of flat zone is rocky pattern. The size and roughness of rocky pattern grow with the increase of temperature. When the temperature is in the range of -196℃ to -60℃,there are lots of thin radiation stripes,and when the temperature is in the range of -60℃<t≤20℃,the radiation stripes decreased gradually. Arc pattern and river pattern could be found in the last fracture zone. When the temperature is lower than 60℃,the notched impact strength grows lineally with the increase of flat zone size.
中图分类号 TQ317.9
所属栏目 试验与研究
基金项目 贵州火炬计划项目(黔科合20008005);贵州省科学基金资助项目(黔科基合20003072)
收稿日期 2008/9/18
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备注薛 斌(1978-),男,工程师。
引用该论文: XUE Bin,DU Pei-hua,HU Zhi,LONG Xue-bin,XU Ding-hong,YU Jie. Fracture Pattern of PPS Impact Sample under Different Temperature[J]. Physical Testing and Chemical Analysis part A:Physical Testing, 2009, 45(3): 133~137
薛 斌,都佩华,胡 智,龙雪彬,徐定红,于 杰. 不同温度下聚苯硫醚冲击试样的断口形貌[J]. 理化检验-物理分册, 2009, 45(3): 133~137
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【4】罗 筑,徐 涛. 聚氯乙烯断面特征区及粗糙度与断裂能的关系[J].高分子学报,1999,8(4):494-497.
【5】于 杰,金志浩. 聚合物缺口冲击强度与断面粗糙度参数Rs的关系[J].高分子学报,1999,10(5):612-615.
【6】于 杰,金志浩,周惠久. ABS塑料断面形貌特征及分形分析[J].高分子材料科学与工程,1995,11(1):83-86.
【7】陈旭东,牛永平,沈家瑞. 二次电子衬度曲线法研究PVC/MBS共混物断面的分形特征[J].高分子学报,2005,10(5):669-673.
【8】Tanrattanakul V,Perkins W G,Massey F L,et al. Fracture mechanisms of poly(ethylene terephthalate) and blends with styrene-butadiene-styrene elastomers[J]. Joural of Materials Selence,1997,32:4749-4758.
【9】Dear DR J P. A study of polymer fracture surface features and their relationship to toughness [J]. Joural of Materials Selence,1999,34:4897-4907.
【10】Frantisek Lednicky. Morphology of coalescence processes secondary fracture cracks and spherulites[J]. Polymer Bulletin,1984,11:579-584.
【11】Luo Wenbo,Yang Tingqing.Computer simulation conic-shaped patterns on fracture surfaces of polymers[J]. Journal of Applied Polymer Science,2003,89:1722-1725.
【12】Moskowitz H D. Striations of the fracture of glassy polymers[J]. Journal of Materials Science,1975,10:159-160.
【13】Wu Jinrong,Pan Qiying,Huang Guangsu. Study on the morphology,rheology and surface of dynamically vulcanized chlorinated butyl rubber/polyethylacrylate extrudates: effect of extrusion temperature and times[J]. Joural of Materials Selence,2007,34:4494-4507.
【14】于 杰. 聚合物材料宏观断口分析[J]. 高分子材料科学与工程,1995,11(4):22-25.
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