稀土铅基板栅材料的性能研究
THE STUDY OF THE PROPERTIES OF THE LEAD-BASED GRID MATERIALS WITH REAR EARTH ADDITIVE
摘 要
研究了低钙高锡铅合金添加稀土对合金力学性能和电化学性能的综合影响。测试并分析了该合金的强度、塑性、硬度、恒流腐蚀及析气等特性。研究结果表明，新型铅合金具有良好的力学性能和耐腐蚀性能，稀土的加入不但提高了合金的强度还能增加合金的塑性，同时提高了合金的耐腐蚀性能。
耐腐蚀性能
稀土
力学性能
Grid
Properties of corrosion resistance
The rear earth
Mechanical properties
Abstract
The effect of Rear Earth additive was studied on the mechanical properties and the electrochemical properties of the lead-calcium alloys with low calcium and high tin content. The tensile strength, toughness, hardness, constant current corrosion performances and gas evolution behavior were detected and analyzed. The results showed that the new kind of the lead-calcium alloys has good mechanical and corrosion-resistance properties. The strength of the alloys was improved with the adding the Rear Earth into the alloy, the ductility was also improved rapidly and the corrosion-resistance property was improved more.
中图分类号 TG146.1+2
所属栏目
基金项目 科技部中小企业创新基金(03C26216111166)
收稿日期 2005/6/3
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备注仝明信(1978-)，男，工程师。
引用该论文: TONG Ming-xin,LIN Guan-fa. THE STUDY OF THE PROPERTIES OF THE LEAD-BASED GRID MATERIALS WITH REAR EARTH ADDITIVE[J]. Physical Testing and Chemical Analysis part A:Physical Testing, 2006, 42(2): 60～62
仝明信,林冠发. 稀土铅基板栅材料的性能研究[J]. 理化检验－物理分册, 2006, 42(2): 60～62
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参考文献
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【2】Zhong S, Liu H K, Dou S X, et al. Evaluation of Lead-calcium-tin-aluminium Grid Alloys for Valve-regulated Lead/acid Batteries[J]. J Power Sources, 1996,59:123-129.
【3】Lakshmi C S, Manders J E, Rice D M. Structure and Properties of Lead-calcium-tin Alloys for Battery Grids[J]. J Power Sources, 1998,73:23-29.
【4】Caillerie J L, Albert L. Lead-calcium Alloy Development:Quality Improvement[J]. J Power Sources, 1997,67:279.
【5】柳厚田,张新华,杨 炯,等.铈降低在硫酸溶液中生长的阳极Pb(Ⅱ)氧化物膜的电阻的研究[J].化学学报, 2002,60(4):643-646.
【6】柳厚田,杨 炯,梁海河,等.铈含量对铅铈合金在硫酸溶液中的阳极行为的影响[J]. 复旦学报(自然科学版), 2001,4(40):400-403.
【7】Fouache S, Chabrol A, Fossati G, et al. Effect of Calcium, Tin and Silver Contents in the Positive Grids of Automotive Batteries with Respect to the Grid Manufacturing Process[J]. J Power Sources, 1999,78:12-22.
【8】Prengaman R D. Chanllenges from Corrosion-resistant Grid Alloys in Lead Acid Battery Manufacturing[J]. J Power Sources, 2001,95:224-233.
【2】Zhong S, Liu H K, Dou S X, et al. Evaluation of Lead-calcium-tin-aluminium Grid Alloys for Valve-regulated Lead/acid Batteries[J]. J Power Sources, 1996,59:123-129.
【3】Lakshmi C S, Manders J E, Rice D M. Structure and Properties of Lead-calcium-tin Alloys for Battery Grids[J]. J Power Sources, 1998,73:23-29.
【4】Caillerie J L, Albert L. Lead-calcium Alloy Development:Quality Improvement[J]. J Power Sources, 1997,67:279.
【5】柳厚田,张新华,杨 炯,等.铈降低在硫酸溶液中生长的阳极Pb(Ⅱ)氧化物膜的电阻的研究[J].化学学报, 2002,60(4):643-646.
【6】柳厚田,杨 炯,梁海河,等.铈含量对铅铈合金在硫酸溶液中的阳极行为的影响[J]. 复旦学报(自然科学版), 2001,4(40):400-403.
【7】Fouache S, Chabrol A, Fossati G, et al. Effect of Calcium, Tin and Silver Contents in the Positive Grids of Automotive Batteries with Respect to the Grid Manufacturing Process[J]. J Power Sources, 1999,78:12-22.
【8】Prengaman R D. Chanllenges from Corrosion-resistant Grid Alloys in Lead Acid Battery Manufacturing[J]. J Power Sources, 2001,95:224-233.
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