染料敏化太阳能电池TiO2薄膜的制备方法
PREPARATION METHOD OF TiO2 FILMS IN DSSC
摘 要
阐述了对应用在染料敏化太阳能电池中作为电极的TiO2薄膜的要求,对如何能制备出具有较好电池性能的TiO2薄膜电极的方法进行了综述,分析了各种方法的优劣,对未来染料敏化太阳能电池中TiO2薄膜的制备方法提出了建议。
TiO2薄膜
制备方法
DSSC
TiO2 films
Preparation methods
Abstract
The requirements for TiO2 films used in dye-sensitized solar cells (DSSC) were described. The overview for the preparation methods to meet these requirements was given. The advantages and disadvantages were also listed,and some suggestions for the future TiO2 films in DSSC were put forward.
中图分类号 TK513
所属栏目 综述
基金项目
收稿日期 2008/3/19
修改稿日期
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备注高建华(1964-),女,高级实验师。
引用该论文: GAO Jian-hua,QIAN Wei-jun,WU Wei,ZENG Yi. PREPARATION METHOD OF TiO2 FILMS IN DSSC[J]. Physical Testing and Chemical Analysis part A:Physical Testing, 2008, 44(8): 431～436
高建华,钱伟君,吴 伟,曾 毅. 染料敏化太阳能电池TiO2薄膜的制备方法[J]. 理化检验－物理分册, 2008, 44(8): 431～436
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参考文献
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【9】Wang Zhongsheng,Hiroshi Kawauchi,Takeo Kashima,et al. Significant influence of TiO2 photoelectrode morphology on the energy conversion efficiency of N719 dye-sensitized solar cell[J]. Coordination Chemistry Reviews,2004,248: 1381-1389．
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【19】Huang Chung-Yi,Hsu Ying-Chan,Chen Jian-Ging,et al. The effects of hydrothermal temperature and thickness of TiO2 film on the performance of a dye-sensitized solar cell[J]. Solar Energy Materials & Solar Cells, 2006,90:2391-2397．
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【21】Wu J M,Hayakawa S,Tsuru K. Soft solution approach to prepare crystalline titania films[J]. Scripta Mater,2002,46: 705-709．
【22】Peng X,Chen A. Aligned TiO2 nanorod arrays synthesized by oxidizing titanium with acetone[J]. J Mater Chem,2004,14: 2542．
【23】Kalyanasundaram K,Gratzel M. Artificial photosynthesis: efficient dye-sensitized photoelectrochemical cells for the direct conversion of sunlight to electricity[J]. Curr Science,1994,66:706-715．
【24】Tsoukleris DS,Arabatzis I M,Chatzivasiloglou E,et al. 2-Ethyl-l-hexanol based screen-printed titania thin films for dye-sensitized solar cells[J]. Solar Energy,2005,79: 422-430．
【25】Karthikeyan C S,Thelakkat M,Willert-porada M. Different esoporous titania films for solid-state dye sensitized solar cells[J]. Thin Solid Films,2006 (511/512):187-194．
【26】戴松元,孔凡太,胡林华. 染料敏化纳米薄膜太阳电池实验研究[J]. 物理学报,2005,54(4)：1919．
【27】陈 增,林 原,王正平,等. 利用丝网印刷技术制备纳晶多孔TiO2薄膜电极[J]. 功能材料,2006,7(37):1073-1075．
【28】Ito Seigo,Murakami Takurou N,Gratzel M,et al. Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10%[J]. Thin solid films,2008,516(14): 4613-4619．
【29】Fotsa Ngaffo F,Caricato A P,Fernandez M,et al. Structural properties of single and multilayer ITO and TiO2 films deposited by reactive pulsed laser ablation deposition techniques[J]. Applied Surface Science ,2007,253: 6508-6511．
【30】Natarajan C,Nogami G. Cathodic electrodeposition of nanocrystalline titanium dioxide thin films[J]. J Electrochem Soc,1996,143 (5): 1547-1550．
【31】Karuppuchamy Subbian,Amalnerkar Dinesh P,Koichi Yamaguchi,et al. Cathodic electrodeposition of TiO2 thin films for dye-sensitized photoelectrochemical application[J]. Chemistry Letters,2001,1: 78-79．
【32】Fotsa Ngaffo F,Caricato A P,Fernandez M,et al. Deposition of ITO films on SiO2 substrates[J]. Applied Surface Science,2005,248: 428．
【33】YumJun-Ho,Kim Seok-soon,Kim Dong-yu,et al. Electrophoretically deposited TiO2 photo-electrodes for use in flexible dye-sensitized solar cells,Journal of photochemistry and photobiology[J]. A: Chemistry,2005,173: 1-6．
【34】Lindstrom Henrik,Holmberg Anna, Magnusson Eva,et al. A new method to make dye-sensitized nanocrystalline solar cells at room temperature,Journal of photochemistry and photobiology[J]. A: Chemistry,2001,145: 107-112．
【35】Pichot Francois, Pitts J Roland,Gregg Brian A. Low-temperature sintering of TiO2 colloids: application to flexible dye-sensitized solar cells[J]. Langmuir,2000,16: 5626-5630．
【36】Gutierrez-Tauste David,Zumeta Inti,Vigil Elena,et al.New low-temperature preparation method of the TiO2 porous photoelectrode for dye-sensitized solar cells using UV irradiation[J]. Journal of photochemistry and photobiology A: chemistry,2005,175: 165-171．
【37】Thelakkat M. Fully vapor-deposited thin-layer titanium dioxide solar cells[J]. Adv Mater,2002,14: 577-581．
【2】Nazeerudin M K,Kay A,Rodicio I,et al. Conversion of light to electricity by cis-X_2bis(2,2′-bipyridyl-4,4′-dicarboxylate) ruthenium (Ⅱ) charge-transfer sensitizers (X = Cl~- ,Br~- ,I~- ,CN~-,and SCN~- ) on nanocrystalline titanium dioxide electrodes[J]. J Am Chem Soc,1993,115 (14): 6382-6390．
【3】孔凡太,戴松元. 染料敏化电池研究进展,[J]. 化学进展,2006,11(18): 1409-1424．
【4】Van de Lagemaat J,Benkstein K D,Frank A J. Relation between particle coordination number and porosity in nanoparticle films: implications to dye-sensitized solar cells[J]. J Pyhs Chem B,2001,105:12433-12436．
【5】Deb Satyen K. Dye-sensitized TiO2 thin-film solar cell research at the national renewable energy laboratory (NREL)[J]. Solar Energy Materials & Cells,2005,88: 1-10．
【6】Park N G,van de Lagemaat J,Frank AJ. Comparison of dye-sensitized rutile- and anatase based TiO2 solar cells[J]. J Phys Chem B,2000,104: 8989-8994．
【7】Gratzel M. Concersion of sunlight to electric power by hanocrystalline dye-sensitized solar cell,photochemistry and photobiology[J]. Chemistry,2004,164: 3-14．
【8】Dai Songyuan,Weng Jian ,Sui Yifeng,et al. Dye-sensitized solar cells,from cell to module[J]. Solar Energy Materials & Solar Cells,2004,84: 125-133．
【9】Wang Zhongsheng,Hiroshi Kawauchi,Takeo Kashima,et al. Significant influence of TiO2 photoelectrode morphology on the energy conversion efficiency of N719 dye-sensitized solar cell[J]. Coordination Chemistry Reviews,2004,248: 1381-1389．
【10】Nakade S,Kubo W. Influence of TiO2 nanoparticle size on electron diffusion and recombination in dye-sensitized TiO2 solar cells[J]. J Phys Chem B,2003,107: 8607-8611．
【11】Wang Z S,Kawaycgu H,Kashima T,et al. Significant influence of TiO2 photoelectrode morphology on the energy conversion effiency of N719 dye-sensitized solar cells[J]. Coord Chem Rev,2004,248 : 1381-1389．
【12】Barbe C J,Arendse F,Comte P,et al. Nanocrystalline titanium oxide electrodes for photovoltaic applications[J]. J Am Ceram Soc,1997,80: 3157-3171．
【13】Sugimoto T,Zhou X J. Synthesis of uniform anatase TiO2 nanoparticles by the Gel-Sol method 2. Adsorption of OH-ions to Ti(OH)4 gel and TiO2 particles[J]. J Colloid Interface Sci,2002,252: 347-353．
【14】蓝 鼎,罗欣莲,万发荣,等. TiO2薄膜的制备方法及其对染料敏化太阳电池性能的影响[J]. 感光科学与光化学,2003,4(21): 262-272．
【15】Kim S J,Park S D,Jeong Y H. Homogeneous precipitation of TiO2 ultrafine powders from aqueous TiCl4 solution[J]. J Am Ceram Soc,1999,82(4): 927-932．
【16】Kay A,Gratzel M. Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon power[J]. Sol Energy Material & Sol Cells,1996,44: 99-117．
【17】Lao Chunfeng,Chuai Yutao. Mix-solvent-thermal method for the synthesis of anatase nanocrystalline titanium dioxide used in dye-sensitized solar cell[J]. Solar Energy Materials & Solar Cells,2005,85: 457-465．
【18】Chae Seung Yong,Park Myun Kyu. Preparation of size-controlled TiO2 nanoparticles and derivation of optically transparent photocatalytic films[J]. Chem Mater,2003,15: 3326-3331．
【19】Huang Chung-Yi,Hsu Ying-Chan,Chen Jian-Ging,et al. The effects of hydrothermal temperature and thickness of TiO2 film on the performance of a dye-sensitized solar cell[J]. Solar Energy Materials & Solar Cells, 2006,90:2391-2397．
【20】张东社,刘 尧,王维波,等. 纳晶多孔TiO2薄膜电极的化学处理[J]. 科学通报,2000,9(45):929-932．
【21】Wu J M,Hayakawa S,Tsuru K. Soft solution approach to prepare crystalline titania films[J]. Scripta Mater,2002,46: 705-709．
【22】Peng X,Chen A. Aligned TiO2 nanorod arrays synthesized by oxidizing titanium with acetone[J]. J Mater Chem,2004,14: 2542．
【23】Kalyanasundaram K,Gratzel M. Artificial photosynthesis: efficient dye-sensitized photoelectrochemical cells for the direct conversion of sunlight to electricity[J]. Curr Science,1994,66:706-715．
【24】Tsoukleris DS,Arabatzis I M,Chatzivasiloglou E,et al. 2-Ethyl-l-hexanol based screen-printed titania thin films for dye-sensitized solar cells[J]. Solar Energy,2005,79: 422-430．
【25】Karthikeyan C S,Thelakkat M,Willert-porada M. Different esoporous titania films for solid-state dye sensitized solar cells[J]. Thin Solid Films,2006 (511/512):187-194．
【26】戴松元,孔凡太,胡林华. 染料敏化纳米薄膜太阳电池实验研究[J]. 物理学报,2005,54(4)：1919．
【27】陈 增,林 原,王正平,等. 利用丝网印刷技术制备纳晶多孔TiO2薄膜电极[J]. 功能材料,2006,7(37):1073-1075．
【28】Ito Seigo,Murakami Takurou N,Gratzel M,et al. Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10%[J]. Thin solid films,2008,516(14): 4613-4619．
【29】Fotsa Ngaffo F,Caricato A P,Fernandez M,et al. Structural properties of single and multilayer ITO and TiO2 films deposited by reactive pulsed laser ablation deposition techniques[J]. Applied Surface Science ,2007,253: 6508-6511．
【30】Natarajan C,Nogami G. Cathodic electrodeposition of nanocrystalline titanium dioxide thin films[J]. J Electrochem Soc,1996,143 (5): 1547-1550．
【31】Karuppuchamy Subbian,Amalnerkar Dinesh P,Koichi Yamaguchi,et al. Cathodic electrodeposition of TiO2 thin films for dye-sensitized photoelectrochemical application[J]. Chemistry Letters,2001,1: 78-79．
【32】Fotsa Ngaffo F,Caricato A P,Fernandez M,et al. Deposition of ITO films on SiO2 substrates[J]. Applied Surface Science,2005,248: 428．
【33】YumJun-Ho,Kim Seok-soon,Kim Dong-yu,et al. Electrophoretically deposited TiO2 photo-electrodes for use in flexible dye-sensitized solar cells,Journal of photochemistry and photobiology[J]. A: Chemistry,2005,173: 1-6．
【34】Lindstrom Henrik,Holmberg Anna, Magnusson Eva,et al. A new method to make dye-sensitized nanocrystalline solar cells at room temperature,Journal of photochemistry and photobiology[J]. A: Chemistry,2001,145: 107-112．
【35】Pichot Francois, Pitts J Roland,Gregg Brian A. Low-temperature sintering of TiO2 colloids: application to flexible dye-sensitized solar cells[J]. Langmuir,2000,16: 5626-5630．
【36】Gutierrez-Tauste David,Zumeta Inti,Vigil Elena,et al.New low-temperature preparation method of the TiO2 porous photoelectrode for dye-sensitized solar cells using UV irradiation[J]. Journal of photochemistry and photobiology A: chemistry,2005,175: 165-171．
【37】Thelakkat M. Fully vapor-deposited thin-layer titanium dioxide solar cells[J]. Adv Mater,2002,14: 577-581．
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