四种硝基苯的电化学行为及其反应活性的理论计算
ELECTROCHEMICAL BEHAVIOR OF 4 NITROBENZENE DERIVATIVES AND THEORATICAL CALCULATION OF THEIR REACTIVE ACTIVITY
摘 要
在滴汞电极上研究了硝基苯、对硝基甲苯、间二硝基苯及2,4-二硝基氯苯的电化学行为,并用量子理论对四种硝基苯化合物的反应活性进行了预测,理论与试验结果基本一致,据此提出了预测分子的电化学活性的方法.
反应活性
硝基苯衍生物
理论计算
Electrochemical behavior
Reactive activity
Derivatives of nitrobenzene
Theoratical calculation
Abstract
Electrochemical behavior of nitrobenzene,1,3-dinitrobenzene,1-methyl-4-nitro-benzene and 1-chloro-2,4-dinitrobenzene were studied at the dropping mercury electrode.And at the same time,the reactive activity (including charge distribution and molecular energy) of these 4 derivatives were calculated theoratically by the quantum theory.It was found that the results obtained by the electrochemical experiments were in consistency with those obtained by theoratical calculation.Based on these facts,a method of predication of electrochemical activity of molecules of some compounds by theoratical calculation was proposed.
中图分类号 O657.1
所属栏目 工作简报
基金项目
收稿日期 2005/5/8
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备注宋远志(1966-),男,湖北天门市人,副教授,主要研究方向为环境监测与环境毒理.
引用该论文: SONG Yuan-zhi,ZHI San-jun,SUN Xiao-jun. ELECTROCHEMICAL BEHAVIOR OF 4 NITROBENZENE DERIVATIVES AND THEORATICAL CALCULATION OF THEIR REACTIVE ACTIVITY[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2006, 42(9): 740～742
宋远志,支三军,孙小军. 四种硝基苯的电化学行为及其反应活性的理论计算[J]. 理化检验－化学分册, 2006, 42(9): 740～742
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参考文献
【1】谢光炎,邓旭忠,肖锦.难降解有机物对硝基酚的电氧化工艺研究[J].广东工业大学学报,2001,18(4):81-85．
【2】Comninellis C H,Pulgarin C.Anodic oxidation of phenol for waste water treatment[J].J Appl Electrochem,1991,21(8):703-708．
【3】Takahashi N,Nakai T,Satoh Y,et al.Variation of biodegradability of nitrogenous organic compounds by ozonation[J].Wat Res,1994,28(7):1563-1570．
【4】Beltran J,Gomez-Serrano Y,Duran A.Degradation kinetics of p-nitrophenol ozonation in water[J].Wat Res,1992,26(1):9-17．
【5】高全昌,陈栓虎.对硝基苯酚的电解还原[J].化学世界,1994,35(8):432-434．
【6】赵藻藩,周性尧,张悟铭,等.仪器分析[M].北京:高等教育出版社,1990:344-346．
【2】Comninellis C H,Pulgarin C.Anodic oxidation of phenol for waste water treatment[J].J Appl Electrochem,1991,21(8):703-708．
【3】Takahashi N,Nakai T,Satoh Y,et al.Variation of biodegradability of nitrogenous organic compounds by ozonation[J].Wat Res,1994,28(7):1563-1570．
【4】Beltran J,Gomez-Serrano Y,Duran A.Degradation kinetics of p-nitrophenol ozonation in water[J].Wat Res,1992,26(1):9-17．
【5】高全昌,陈栓虎.对硝基苯酚的电解还原[J].化学世界,1994,35(8):432-434．
【6】赵藻藩,周性尧,张悟铭,等.仪器分析[M].北京:高等教育出版社,1990:344-346．
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