HG-AFS Determination of Inorganic Arsenic in Readymade Chinese Traditional Medicines by Extraction with Hydrochloric Acid
摘 要
中成药在6 moL·L-1的盐酸溶液中,经加热后,无机砷以氯化物的形式被提取,用氢化物发生-原子荧光光谱法测定痕量无机砷.砷浓度在50 μg·L-1以内与其峰面积之间保持线性关系(r=0.999 6),方法的检出限为0.34 μg·L-1,分析了中成药样品,结果的RSD值小于4%,回收率试验结果在92.6%~104.0%之间.
Abstract
Trace amounts of inorganic arsenic in the medicine sample was extracted with 6 moL·L-1 HCl by heating at 60 ℃ in a water bath,and transferred into solution in the form of chloride. The sample solution was used for hydride generation and AFS determination. Linearity was held within arsenic concentrations of 50 μg·L-1 with its peak area (r=0.999 6). Detection limit (n=11) was found to be 0.34 μg·L-1. Values of RSD′s (n=7) and recoveries obtained,in the analysis of 2 medicine samples,were less than 4.0% and in the range of 92.6%-104.0% respectively.
中图分类号 O657.31
所属栏目 工作简报
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收稿日期 2006/1/10
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备注蒋瑾华(1952-),女,北京人,高级工程师,从事光谱分析及方法研究工作.
引用该论文: JIANG Jin-hua,WEN Qiao-ling,HU Si. HG-AFS Determination of Inorganic Arsenic in Readymade Chinese Traditional Medicines by Extraction with Hydrochloric Acid[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2007, 43(7): 578~579
蒋瑾华,温巧玲,胡思. 盐酸浸提-氢化物发生-原子荧光光谱法测定中成药中痕量无机砷[J]. 理化检验-化学分册, 2007, 43(7): 578~579
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参考文献
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【2】金阳,李薇雅.食品中无机砷和有机砷的分离和测定[J].食品工业科技,2003,12(24):92-93.
【3】王滨,王耀成,江永圣.氢化物发生原子荧光法测定食品中无机砷[J].理化检验-化学分册,2004,40(11):687-688.
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