EDTA Titrimetric Determination of Sulfate and Total Hardness of Water Using Drop-Counting Micro Capillary Burette
摘 要
用EDTA微量滴定法测定了水中硫酸根及总硬度,测定过程在氨性缓冲介质中进行,采用络黑T作指示剂,用一种自制的聚乙烯微型毛细管滴定管进行滴定,滴定反应所耗的滴定剂用计滴法计数.从微滴管流出的每一小滴滴定剂的体积(通常在0.01~0.02 mL之间)用重量法校正,每次滴定所耗滴定剂一般在50~200小滴之间.此方法的扩展不确定度,对硫酸根测定为0.94%与重量法相当,而精密度则优于重量法,对总硬度测定为0.82%优于常量滴定法.此方法的特点为分析快速、准确,消耗试剂少且便于携带,适合于现场或野外分析应用.
Abstract
Sulfate and total hardness of natural water were determined by EDTA micro titration in ammoniacal buffer solution with eriochrome black T as indicator.A self-made polythene microburette was used in the titration by counting the droplets used in the reaction.Volume of the droplet (ordinarity 0.01 to 0.02 mL per drop) from the microburette was calibrated by gravimetry.Amounts of titrant used in the titration were usually in the range of 50-200 droplets.Expanded uncertainty of this method was found to be 0.94% for SO2-4 determination which is equivalent to the uncertainty of the gravimetric method,while the precision is better than gravimetry.Expanded uncertainty for hardness determination was found to be 0.82%,which is also better than the macro titration method.The special features of this method were its rapidity and accuracy in analysis,less in consumption of reagent and portability.It is proved to be feasible in the worksite or field analys.s
中图分类号 X832 O655.21
所属栏目 工作简报
基金项目
收稿日期 2007/3/5
修改稿日期
网络出版日期
作者单位点击查看
备注沈文闻(1970-),男,广西德保县人,讲师,主要从事精细化工的研究与分析工作.
引用该论文: SHEN Wen-wen,CAI Cheng-xiang. EDTA Titrimetric Determination of Sulfate and Total Hardness of Water Using Drop-Counting Micro Capillary Burette[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2007, 43(8): 663~665
沈文闻,蔡成翔. 水中硫酸根及其总硬度的EDTA滴定法——采用计滴微型毛细管滴定管[J]. 理化检验-化学分册, 2007, 43(8): 663~665
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】宋金如,刘淑娟,朱霞萍.测定水中硫酸根方法的概述[J].华东地质学院学报,2002,25(12):154-158.
【2】刘文明,马卫兴,钱保华.络黑T光度法测定水的硬度[J].理化检验-化学分册,2000,36(9):426-427.
【3】姜晖霞,曾光明.硫酸根离子分析方法评述[J].湖南化工,1998,28(6):14-15.
【4】罗明辉,杨勤,韦永勒,等.定量化学分析实验微型化的研究[J].化工高等教育,2002,73(3):71-72.
【5】张大洋,范文玉,赵鸣玉.滴定体积法测定表面张力的快速计算[J].日用化学工业,2001,31(1):49-50.
【6】黄佩伦,韩仲果.测定原盐氯化钠的新方案[J].海湖盐与化工,2001,30(6):21-24.
【7】蔡成翔.毛细滴管-吸量管数滴微型滴定法现场快速测定水的总硬度[J].工业水处理,2006,26(12):70-73.
【2】刘文明,马卫兴,钱保华.络黑T光度法测定水的硬度[J].理化检验-化学分册,2000,36(9):426-427.
【3】姜晖霞,曾光明.硫酸根离子分析方法评述[J].湖南化工,1998,28(6):14-15.
【4】罗明辉,杨勤,韦永勒,等.定量化学分析实验微型化的研究[J].化工高等教育,2002,73(3):71-72.
【5】张大洋,范文玉,赵鸣玉.滴定体积法测定表面张力的快速计算[J].日用化学工业,2001,31(1):49-50.
【6】黄佩伦,韩仲果.测定原盐氯化钠的新方案[J].海湖盐与化工,2001,30(6):21-24.
【7】蔡成翔.毛细滴管-吸量管数滴微型滴定法现场快速测定水的总硬度[J].工业水处理,2006,26(12):70-73.
相关信息