FAAS Determination of Barium and Zinc in Lube Additives with Emulsion Sample Introduction
摘 要
在润滑油添加剂样品溶液的制备中应用了乳化技术.在样品的乙酸乙酯溶液中加入Triton X-100进行乳化,所得乳化样品溶液直接用于钡及锌的火焰原子吸收光谱法(FAAS)测定,对试样制备及FAAS测定的各种条件,包括乳化剂的加入量,背景干扰以及共存物质的干扰等进行试验并予以优化.为使试剂空白溶液及标准工作曲线的各浓度点试液的粘度与试样溶液的粘度相匹配,在其中加入了琼脂溶液.在应用所提出的方法分析实样中,分析结果的RSD(n=6)值在2.0%~3.5%之间.用标准加入法进行了回收率试验,所得结果在95.4%~103.0%之间.
Abstract
Emulsification technique was applied to the pretreatment of lube additives.The lube additive sample was dissolved in ethyl acetate and emulsified by addition of Triton X-100.The emulsified sample solution was used directly for the FAAS determination of barium and zinc.Conditions for sample preparation and FAAS determination,including the amount of emulsifying agent used,interferences due to background absorption and co-existing substances,were studied and optimized.For matching the viscosity of the blank solution and testing solutions of working standards with the sample solution,appropriate amounts of agar solution were added.Values of RSD′s (n=6) and recovery found in the analysis of substantial samples were in the ranges of 2.0%-3.5% and 95.4%-103.0% respectively.
中图分类号 O657.32
所属栏目 工作简报
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收稿日期 2006/8/16
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备注刘立行(1938-),男,陕西省山阳县人,教授,主要从事仪器分析教学及分析方法研究.
引用该论文: LIU Li-xing,LIU Li-jun. FAAS Determination of Barium and Zinc in Lube Additives with Emulsion Sample Introduction[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2007, 43(10): 873~874
刘立行,刘丽君. 乳化进样-火焰原子吸收光谱法测定润滑油添加剂中钡及锌[J]. 理化检验-化学分册, 2007, 43(10): 873~874
被引情况:
【1】马忠革,沈春玉, "灰化法样品预处理-分光光度法测定润滑油及其添加剂中钙",理化检验-化学分册 46, 1146-1147(2010)
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参考文献
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【2】陈焕斌,陈焕曦.微波溶样原子吸收光谱法测定石油添加剂中的钙、镁[J].石油化工,1999,28(2):116.
【3】梁鸿文,段玲兰,于爱英.用原子吸收法测定添加剂和含添加剂润滑油中的钡[J].理化检验-化学分册,1984,20(3):16-17.
【4】孙宝湖.应用MIBK-冰醋酸体系AAS法直接测添加剂和润滑油中钙、钡、锌含量[J].分析测试通报,1987,6(2):41-45.
【5】金姗,姚丽珠.火焰发射光谱法测定钡和钙[J].分析试验室,1995,14(4):57-58.
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