ICP-AES Determination of Lead,Cadmium,Chromium and Arsenic in Industrial Waste Water
摘 要
采用电感耦合等离子体原子发射光谱(ICP-AES)法同时测定工业废水中铅、镉、铬和砷.对仪器的工作参数和被测元素的分析谱线进行了优化和选择.方法的检出限依次为0.008,0.002,0.007,0.015 mg·L-1.在质量浓度为0.489 mg·L-1(Pb),0.086 6 mg·L-1(Cd),0.231 mg·L-1(Cr)及0.395 mg·L-1(As)的水平上按试验方法测定8次,作了精密度试验,测得相对标准偏差值依次为1.71%,1.22%,0.95%及1.40%.在两个废水样品的基础上作了加标回收试验,所得结果在95.4%~104.6%之间.
Abstract
ICP-AES was applied to simultaneous determination of Pb,Cd,Cr and As in industrial waste water.Working conditions of the instrument and choice of analytical spectral lines for the elements were tested and optimized.Values of detection limit were found to be 0.008,0.002,0.007,0.015 mg·L-1 for Pb,Cd,Cr and As respectively.Precision of the method were tested at the concentration levels of 0.489 mg·L-1 (for Pb),0.086 6 mg·L-1 (for Cd),0.231 mg·L-1 (for Cr) and 0.395 mg·L-1 (for As) for 8 determinations,and values of RSD′s obtained were 1.71%,1.22%,0.95% and 1.40% respectively.Tests for recovery were made by the standard addition method on the base of 2 waste water samples,values of recovery found were in the range from 95.4% to 104.6%.
中图分类号 O657.31
所属栏目 工作简报
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收稿日期 2006/8/18
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备注鲁丹(1964-),女,宁波人,副主任技师,理学学士,主要从事原子光谱分析研究工作.
引用该论文: LU Dan,RUAN Yi. ICP-AES Determination of Lead,Cadmium,Chromium and Arsenic in Industrial Waste Water[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2007, 43(12): 1022~1023
鲁丹,阮毅. 电感耦合等离子体原子发射光谱法测定工业废水中铅、镉、铬和砷[J]. 理化检验-化学分册, 2007, 43(12): 1022~1023
被引情况:
【1】张世龙,吴周丁,刘小玲,张合良,陈和平,胡小明, "电感耦合等离子体原子发射光谱法测定多金属矿石中铁、铜、铅、锌、砷、锑、钼和镉的含量",理化检验-化学分册 51, 930-933(2015)
【2】付海曦,刘威,张春辉,李艳, "水体中重金属离子的检测方法研究进展",理化检验-化学分册 48, 496-503(2012)
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参考文献
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【2】Akbar Montaser,Golightly D W.感耦等离子体在原子光谱分析法中的应用[M].陈隆懋,等译.北京:人民卫生出版社,1992:477-479.
【3】辛仁轩.等离子体发射光谱分析[M].北京:化学工业出版社,2005:225-229.
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