Analysis and Quality Control of Essence Used in Cigarette Manufacturing by GC-MS with Multivariate Analysis
摘 要
采用同时蒸馏萃取法及气相色谱-质谱法对AB6香精中挥发性成分进行了提取分离与测定.定性了15种成分,占总成分的80.5%(截除溶剂峰),其中4种主要组分在10个不同批次样品中含量的相对标准偏差分别为3.9%,6.1%,5.7%和2.2%,由此构成合格样品库,并采用主成分投影分析法有效地区分了掺有溶剂的AB6香精与AB6香精的合格样品,随着溶剂量的增加它们之间的距离越远,同时,不同品种的香精样品之间也具有显著的差异.气相色谱-质谱法分析和主成分投影分析法可用于香精的质量控制.
Abstract
Volatile components in essence AB6 were separated by the method of simultaneous distillation and extraction,and determined by GC-MS. Fifteen components,amounting to 80.5% of the total (solvent peaks eliminated) were identified,among which 4 main components were determined in samples taken from 10 different batches of products,giving values of RSD′s in the range of 2.2% to 6.1%. A database of qualified sample was established based on the experimental data obtained. Qualified samples of AB6 essence were effectively differentiated from samples of AB6 essence admixed with solvents by applying the principle component projection analysis. More the solvents admixed,the more will be the distance to keep them apart. In the mean time,remarkable differences were also observed among different kinds of essence. It was proved that quality control of essence used in cigarette manufacturing could be achieved by the application of GC-MS analysis as well as the principle component projection analysis.
中图分类号 O657.37
所属栏目 工作简报
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收稿日期 2006/9/5
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备注郭紫明(1969-),男,湖南常德人,研究生,工程师,主要从事烟草化学研究.
引用该论文: GUO Zi-ming,DONG Dao-zhu,LI Yan-Chun,HUANG Lan-fang,GUO Fang-qiu. Analysis and Quality Control of Essence Used in Cigarette Manufacturing by GC-MS with Multivariate Analysis[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2008, 44(1): 22~24
郭紫明,董道竹,李燕春,黄兰芳,郭方遒. 气相色谱-质谱法和主成分投影分析法用于烟用香精的分析和质量控制[J]. 理化检验-化学分册, 2008, 44(1): 22~24
被引情况:
【1】杨君,蒋健,许式强,舒明,郑晓,王晓晴,潘再法,王丽丽, "烟用香精香料的固相微萃取-气相色谱指纹图谱及系统聚类分析",理化检验-化学分册 48, 712-715(2012)
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【6】Edris A E,Girgis B S,Fadel H M. Recovery of volatile aroma components from aqueous waste streams using an activated carbon column[J]. Food Chemistry,2003,82(2):195-202.
【7】高芸,刘百战,朱晓兰,等.秘鲁浸膏精油化学成分的GC/MS分析[J].分析仪器,1999(3):37-38.
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