Atomic Absorption Spectrometric Determination of Lead,Copper,Cadmium,Magnesium,Manganese and Iron in Grains with Microwave Heated Sample Digestion
摘 要
用微波消解法进行样品消解,原子吸收光谱法测定了小麦粉国家标准物质中铅、铜、镉、镁、锰、铁6种元素的含量.其中镁、锰、铁用火焰原子化法,铅、铜、镉用石墨炉原子化法,方法的相对标准偏差分别为1.43%(镁),4.72%(镉),5.20%(锰),6.04%(铜),13.8%(铁)及18.7%(铅),检出限分别为0.001(铅及铜),0.000 1(镉),0.01(锰)及0.02(镁和铁) mg·kg-1.
Abstract
Contents of lead,copper,cadmium,magnesium,manganese and iron in wheat powder were determined by atomic absorption spectrometry.Sample of wheat powder was digested with HNO3 in a tightly closed vessel heated with micro-wave.The sample solution obtained were submitted for AAS determination of the 6 elements,among which flame-atomization was used for Mg,Mn and Fe,while graphite furnace-atomization was used for Pb,Cu and Cd.Working conditions of instrument and other AAS analytical conditions were tested and described in detail.Detection limits were found as (mg·kg-1) 0.001 (for Pb and Cu),0.000 1 (for Cd),0.01 (for Mn) and 0.02 (for Mg and Fe).Values of RSD′s (n=8) obtained were 1.43% (Mg),4.72% (Cd),5.20% (Mn),6.04% (Cu),13.8% (Fe) and 18.7% (Pb).
中图分类号 O657.31
所属栏目 工作简报
基金项目
收稿日期 2006/12/19
修改稿日期
网络出版日期
作者单位点击查看
备注袁晶(1970-),女,杭州人,工程师,主要研究方向为化学检验.
引用该论文: ZHANG Chun-yan,YUAN Jing,PAN Guo-qing. Atomic Absorption Spectrometric Determination of Lead,Copper,Cadmium,Magnesium,Manganese and Iron in Grains with Microwave Heated Sample Digestion[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2008, 44(4): 355~356
张春艳,袁晶,潘国卿. 微波消解-原子吸收光谱法测定粮谷中铅、铜、镉、镁、锰、铁[J]. 理化检验-化学分册, 2008, 44(4): 355~356
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】周同惠,汪尔康,陆婉珍,等.分析化学手册:光谱分析分册[M].北京:化学工业出版社,1998.
【2】GB/T 5009.12-2003食品中铜的测定[S].
【3】GB/T 5009.1-2003食品卫生检验方法理化部分 总则[S].
【4】GB/T 5009.15-2003食品中镉的测定[S].
【5】GB/T 5009.94-2003食品中铁、镁、锰的测定[S].
【6】宋清.定量分析中的误差和数据评价[M].北京:人民教育出版社出版,1982.
【2】GB/T 5009.12-2003食品中铜的测定[S].
【3】GB/T 5009.1-2003食品卫生检验方法理化部分 总则[S].
【4】GB/T 5009.15-2003食品中镉的测定[S].
【5】GB/T 5009.94-2003食品中铁、镁、锰的测定[S].
【6】宋清.定量分析中的误差和数据评价[M].北京:人民教育出版社出版,1982.
相关信息