Single-scanning Oscillo-polarographic Determination of the Banned Pigment-Sudan Red Ⅰ in Foodstuffs
摘 要
在pH 10硼砂缓冲介质中,苏丹红Ⅰ产生一个峰电位在-0.95 V(vs.SCE)的灵敏的吸附还原极谱波.其峰电流的一阶导数值(I′p)与苏丹红Ⅰ的质量浓度在0.1~2.0 mg·L-1范围内呈线性关系,检出限为0.01 mg·L-1.应用此方法分析了辣椒酱及腐乳等试样,均未测出苏丹红Ⅰ,以此试样为基体加入苏丹红Ⅰ标准溶液做回收试验,测得回收率在95.3%~103.0%之间.
Abstract
In a borate buffer medium of pH 10,a sensitive adsorptio-reductive polarographic wave was produced by sudan red Ⅰ with its peak potential at -0.95 V (vs.SCE).Linear relationship between values of 1st derivative of peak current (I′p) and concentration of sudan red Ⅰ was obtained in the range from 0.1-2.0 mg·L-1,with its detection limit of 0.01 mg·L-1.Samples of chilli pickle and fermented bean curd were analyzed by the proposed method and no sudan red Ⅰ was found in the samples.Recovery test was made by adding standard sudan red Ⅰ solution to the samples mentioned above,and values of recovery obtained were in the range of 95.3%-103.0%.
中图分类号 O657.14
所属栏目 工作简报
基金项目 广西教育厅科研基金(桂教科200508135)资助
收稿日期 2006/12/28
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备注魏小平(1967-),女,陕西大荔人,高级工程师,研究方向为化学传感器与应用电化学.
引用该论文: WEI Xiao-ping,WANG Qiang,LIU Rong-fen,LI Jian-ping. Single-scanning Oscillo-polarographic Determination of the Banned Pigment-Sudan Red Ⅰ in Foodstuffs[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2008, 44(8): 719~721
魏小平,王强,刘荣芬,李建平. 单扫描示波极谱法测定食品中禁用色素苏丹红Ⅰ[J]. 理化检验-化学分册, 2008, 44(8): 719~721
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参考文献
【1】中华人民共和国卫生部.苏丹红危险性评估报告[EB].北京:中华人民共和国卫生部,2005:4.
【2】GB/T 19681-2005食品中苏丹红染料的检测方法高效液相色谱法[S].
【3】喻凌寒.HPLC-DAD法测定辣椒及其制品中苏丹红Ⅰ的含量[J].光谱实验室,2004,11(6):31-33.
【4】李平,陈澍,付松.二极管阵列检测器在液相色谱测定苏丹红Ⅰ中的应用[J].预防医学情报杂志,2005,21(2):132-134.
【5】Yamaki S B,Andrade A A,Mendonca C R,et al.Morphological and structural characteristics of diazo dyes at the air-water interface: in situ Brewster angle microscopy and polarized UV/vis analysis[J].J Colloid Interface Sci,2005,283(2):464-471.
【2】GB/T 19681-2005食品中苏丹红染料的检测方法高效液相色谱法[S].
【3】喻凌寒.HPLC-DAD法测定辣椒及其制品中苏丹红Ⅰ的含量[J].光谱实验室,2004,11(6):31-33.
【4】李平,陈澍,付松.二极管阵列检测器在液相色谱测定苏丹红Ⅰ中的应用[J].预防医学情报杂志,2005,21(2):132-134.
【5】Yamaki S B,Andrade A A,Mendonca C R,et al.Morphological and structural characteristics of diazo dyes at the air-water interface: in situ Brewster angle microscopy and polarized UV/vis analysis[J].J Colloid Interface Sci,2005,283(2):464-471.
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