孔雀石绿及无色孔雀石绿的固相萃取性能比较
Study of Extraction Behavior of Solid Phase Extraction Materials for Malachite Green and Leucomalachite Green
摘 要
研究了固相萃取剂氧化铝(碱性、中性、酸性)及丙基磺酸阳离子交换树脂对孔雀石绿及无色孔雀石绿的固相萃取性质,试验发现不同的丙基磺酸阳离子树脂的固相萃取性能有差异,应该用洗脱曲线来进行测试.去除杂质过程中使用中性氧化铝和酸性氧化铝对检测结果的准确性没有影响.
孔雀石绿
无色孔雀石绿
氧化铝
丙基磺酸阳离子树脂
Solid phase extraction
Malachite green
Leucomalachite green
Al2O3
Propylsulfonation cation exchange resin
Abstract
Solid phase extraction (SPE) is a key operation applied to the detection of residual malachite green (MG) and its metabolite leucomalachite green (LMG) in aquatic products.In this paper,SPE behavior of some materials,including Al2O3 (acidic,neutral,alkaline) and propylsulfonation cation exchange resins,for MG and LMG was studied.Experimental findings showed that SPE performance of resin should be confirmed via eluation test.In addition,it has been demonstrated that the neutral Al2O3 and acidic Al2O3 have no significant difference in SPE of MG and LMG.
中图分类号 O657
所属栏目 工作简报
基金项目 科技部标准重大专项,主要养殖水产品安全限量及控制标准研究(2002BA906A39)资助
收稿日期 2007/5/11
修改稿日期
网络出版日期
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备注江洁(1976-),女,山东沂源人,讲师,博士生研究生,主要从事水产品标准化与渔药残留分析的研究.
引用该论文: JIANG Jie,LIN Hong,XU Jie. Study of Extraction Behavior of Solid Phase Extraction Materials for Malachite Green and Leucomalachite Green[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2008, 44(10): 965～968
江洁,林洪,徐杰. 孔雀石绿及无色孔雀石绿的固相萃取性能比较[J]. 理化检验－化学分册, 2008, 44(10): 965～968
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参考文献
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【2】Bergwerff A A,Kuiper1 R V,Scherpenisse P.Persistence of residues of malachite green in juvenile eels (Anguilla anguilla)[J].Aquaculture,2004,233:55-63．
【3】Rao K V K.Inhibition of DNA synthesis in primary rat hepatocyte cultures by malachite green: a new liver tumor promoter[J].Toxicol Lett,1995,81(2):107-113．
【4】Culp S J,Beland F A.Mutagenicity and carcinogenicity in relation to DNA adduct formation in rats fed leucomalachite green[J].Muta Res,2002,506:55-63．
【5】Mitrowska K,Posyniak A.Determination of malachite green and its metabolite,leucomalachite green,in fish muscle by liquid chromatography[J].Bull Vet Inst Pulawy,2004,48:173-176．
【6】葛宝坤,王云凤,常春艳,等.固相萃取-液相色谱法快速测定水产品中的孔雀石绿、结晶紫及其代谢物[J].中国卫生检验杂志,2006,16(1):45-47．
【7】Roybal J E,Denver C O,Pfenning A P,et al.Determination of malachite green and its metabolite,leucomalachite green,in catfish (Ictalurus punctatus) tissue by liquid chromatography with visible detection[J].J of AOAC,1995,78:453-457．
【8】Turnipseed S B,Roybal J E,Hurlbut J A,et al.Gas chromatographic/mass spectrometric confirmation of leucomalachite green in catfish (Ictalurus punctatus) tissue[J].J of AOAC,1995,78(4):971-977．
【9】Bergwerff A A,Scherpenisse P.Determination of residues of malachite green in aquatic animals[J].J of Chromatography B,2003,788:351-359．
【10】Scherpenisse P,Bergwerff A A.Determination of residues of malachite green in finfish by liquid chromatography tandem mass spectrometry[J].Anal Chim Acta,2005,529:173-177．
【11】SC/T 3021-2004水产品中孔雀石绿残留量的测定 液相色谱法[S]．
【12】Plakas S M,El Said K R,Stehly G R,et al.Optimization of a liquid chromatographic method for determination of malachite green and its metabolites in fish tissues[J].J of AOAC,1995,78:1388-1394．
【13】何炳林,黄文强.离子交换与吸附树脂[M].上海:上海科技教育出版社,1995:127．
【14】Rushing L G,Thompson H C Jr.Simultaneous determination of malachite green,gentian violet and their leuco metabolites in catfish or trout tissue by high-performance liquid chromatography with visible detection[J].J of Chromatography B,1997,688:325-330．
【15】郭德华,叶长淋,朱莹洁.液相色谱法测定鳗鱼中的孔雀石绿[J].化学计量分析,2002,11(2):20-21．
【16】GB/T 19857-2005水产品中孔雀石绿、隐色孔雀石绿、结晶紫、隐色结晶紫残留量的测定[S]．
【2】Bergwerff A A,Kuiper1 R V,Scherpenisse P.Persistence of residues of malachite green in juvenile eels (Anguilla anguilla)[J].Aquaculture,2004,233:55-63．
【3】Rao K V K.Inhibition of DNA synthesis in primary rat hepatocyte cultures by malachite green: a new liver tumor promoter[J].Toxicol Lett,1995,81(2):107-113．
【4】Culp S J,Beland F A.Mutagenicity and carcinogenicity in relation to DNA adduct formation in rats fed leucomalachite green[J].Muta Res,2002,506:55-63．
【5】Mitrowska K,Posyniak A.Determination of malachite green and its metabolite,leucomalachite green,in fish muscle by liquid chromatography[J].Bull Vet Inst Pulawy,2004,48:173-176．
【6】葛宝坤,王云凤,常春艳,等.固相萃取-液相色谱法快速测定水产品中的孔雀石绿、结晶紫及其代谢物[J].中国卫生检验杂志,2006,16(1):45-47．
【7】Roybal J E,Denver C O,Pfenning A P,et al.Determination of malachite green and its metabolite,leucomalachite green,in catfish (Ictalurus punctatus) tissue by liquid chromatography with visible detection[J].J of AOAC,1995,78:453-457．
【8】Turnipseed S B,Roybal J E,Hurlbut J A,et al.Gas chromatographic/mass spectrometric confirmation of leucomalachite green in catfish (Ictalurus punctatus) tissue[J].J of AOAC,1995,78(4):971-977．
【9】Bergwerff A A,Scherpenisse P.Determination of residues of malachite green in aquatic animals[J].J of Chromatography B,2003,788:351-359．
【10】Scherpenisse P,Bergwerff A A.Determination of residues of malachite green in finfish by liquid chromatography tandem mass spectrometry[J].Anal Chim Acta,2005,529:173-177．
【11】SC/T 3021-2004水产品中孔雀石绿残留量的测定 液相色谱法[S]．
【12】Plakas S M,El Said K R,Stehly G R,et al.Optimization of a liquid chromatographic method for determination of malachite green and its metabolites in fish tissues[J].J of AOAC,1995,78:1388-1394．
【13】何炳林,黄文强.离子交换与吸附树脂[M].上海:上海科技教育出版社,1995:127．
【14】Rushing L G,Thompson H C Jr.Simultaneous determination of malachite green,gentian violet and their leuco metabolites in catfish or trout tissue by high-performance liquid chromatography with visible detection[J].J of Chromatography B,1997,688:325-330．
【15】郭德华,叶长淋,朱莹洁.液相色谱法测定鳗鱼中的孔雀石绿[J].化学计量分析,2002,11(2):20-21．
【16】GB/T 19857-2005水产品中孔雀石绿、隐色孔雀石绿、结晶紫、隐色结晶紫残留量的测定[S]．
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