有机化学试验的绿色化
Green Organic Chemical Experimentation
摘 要
论述了在有机化学中增强绿色化学教育的必要性,主要围绕化学反应、原料、溶剂的绿色化三方面展开讨论.提出应将绿色化学思想贯穿于有机化学教育全过程中,培养学生绿色化思维习惯,以适应21世纪社会发展对人才的要求.
绿色化学
化学试验
环境污染
Organic chemistry
Green chemistry
Chemical experimentation
Environmental pollution1
Abstract
The necessity of green chemical education in the course of organic chemistry was emphasized,centering especially on the topics of greening of chemical reactions,raw materials and solvents.It was stressed that the thought of green chemistry should be run through the whole process of the education of organic chemistry,aiming to train the students be accustomed to have a “greening” thought and to meet with the requirements of talents for the social progress in the 21st century.
中图分类号 O65
所属栏目 专题讲座
基金项目 齐齐哈尔大学青年教师科研启动支持项目
收稿日期 2009/4/20
修改稿日期
网络出版日期
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备注姜海燕(1980-),女,满族,黑龙江齐齐哈尔人,硕士,讲师,主要从事有机化学教学和科研.
引用该论文: JIANG Hai-yan,JIANG Yong-feng. Green Organic Chemical Experimentation[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2010, 46(11): 1337～1339
姜海燕,姜永峰. 有机化学试验的绿色化[J]. 理化检验－化学分册, 2010, 46(11): 1337～1339
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参考文献
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【2】王清廉,沈凤嘉.有机化学实验[M].2版.北京:高等教育出版社,2000:155-157．
【3】蔡春,吕春绪.五氧化二氮对一元取代苯的硝化研究[J].火炸药学报,2000(1):25-27．
【4】李增瑞,程金生,韦淑飞,等.绿色化学与超临界二氧化碳介质[J].右江民族医学院学报,2006,6:1077-1080．
【5】SIHVONEN M,JRVENP E,HIETANIEMI V,et al.Advances in supercritical carbon dioxide thechologies[J].Trendsin Food Science & Technology,1999,10(6):217-222．
【6】杨光,刘宗章,张敏华.超临界二氧化碳抗溶剂法在药物微胶囊化方面的应用[J].化工进展,2005,24(9):1037-1041．
【7】李颖华.超临界二氧化碳在有机合成中的应用[J].化学世界,2002(9):490-493,468．
【8】XIAO J,NEFKENS S C A,JESSOP P G,et al.Asymmetric hydrogenation of α,β-unsaturated carboxylic acids in supercritical carbon dioxide[J].Tetrahydron Lett,1996,37(16):2813-2816．
【9】YOSHIDA M,HARA N,OKUYAMA S.Catalytic production of urethanes from amines and alkyl halides in supercritical carbon dioxide[J].Chem Commun,2000(2):151-152．
【10】DESIMONE J M,GUAN Z,ELSBERND C S.Synthesis of fluoropolymers in supercritical carbon dioxide[J].Science,1992,257:945．
【11】BURK M J,FENG S,GROSS M F,et al.Asymmetric catalytic hydrogenation reactions in supercritical carbon dioxide[J].J Am Chem Soc,1995,117:8277．
【12】刘竹青,胡爱林,王公应.对氨基苯酚的合成研究进展[J].工业催化,1999,2:11-16．
【13】POLAT K,AKSU M L,PEKEL A T.Electroreduction of nitrobenzene to p-aminophenol using voltammetric and semiplot scale preparative electrolysis techniques[J].Journal of Applied Electrochemistry,2002,32:217-223．
【14】WILSON C L,UDUPA H V.Electrolytic reduction of organic compounds.Ⅵ.aminophenols from nitrocompounds[J].Journal of the Electrochemical Society,1952,99(7):289-294．
【15】WEINBERY N L.Technique of electroorganic synthesis.part Ⅲ[M].New York: Wiley,1982:162,406．
【16】MOTILLET A,COMITI J,LEGRAND J.Application of metallic foams in electrochemical reactors of filter press type[J].Journal of Applied Electrochemistry,1993,23:1045-1050．
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