Laves相Ta-Cr系合金的高温抗氧化性研究进展
Research Progress in High Temperature Oxidation Resistance of Laves Phase Ta-Cr Base Compounds
摘 要
Laves相Ta-Cr系合金以其熔点高、适当的密度和良好的高温力学性能成为新型候选高温结构材料之一。综述了Laves相TaCr2的氧化机制以及提高抗氧化性的方法, 着重评述了掺杂、活性元素效应以及涂层保护方面的研究进展, 指出了存在的问题及今后的研究方向。
TaCr2
高温抗氧化
研究进展
laves phase
TaCr2
high temperature oxidation resistance
research progress
Abstract
Laves phase Ta-Cr based compounds are important potential high temperature structural materials due to their high melting temperature, moderate density and good high temperature mechanical propertis. The research on oxidation mechanism and the method of enhancing the oxidation resistance of Laves phase Ta-Cr based compounds are reviewed, including the progress in the aspects of doping, active element effects and protective coatings. The problems existing in the field and the development trend of the future research are also pointed out.
中图分类号 TG172.8 DOI 10.11973/fsyfh-201511011
所属栏目 专论
基金项目 国家自然科学基金(51161020); 江西省自然科学基金(20114BAB216012); 南昌航空大学学位与研究生教育教学改革研究项目(YJG201401)
收稿日期 2015/3/27
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联系人作者肖璇(57514892@qq.com)
备注肖璇(1979-), 副教授, 博士, 从事先进高温结构材料的强韧化研究,
引用该论文: WAN Bin,XIAO Xuan,ZHOU Tian-ning,HU Kong-sheng,HE Li,ZENG Yuan. Research Progress in High Temperature Oxidation Resistance of Laves Phase Ta-Cr Base Compounds[J]. Corrosion & Protection, 2015, 36(11): 1063
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参考文献
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【33】陈云峰,熊华平,毛唯. 液相Al-Si共渗提高Ti3Al基合金高温抗氧化性[J]. 腐蚀科学与防护技术,2005,17(1):39-42.
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【2】BEI H,PHARR G M,GEORGE E P. A review of directionally solidified intermetallic composites for high-temperature structural applications[J]. Journal of material science,2004,39:3975-3984.
【3】李专,肖鹏,熊翔. 连续纤维增强陶瓷基复合材料的研究进展[J]. 粉末冶金材料科学与工程,2007,12(1):13-19.
【4】曲选辉,何定玉,黄伯云. Laves相铬化物的研究[J]. 高技术通讯,1996,6(12):27-30.
【5】聂小武,鲁世强,王克鲁. Laves相TaCr2金属间化合物的研究进展[J]. 材料研究与应用,2007,1(4):270-273.
【6】SAUTHOFF G. Laves phase alloys for high temperature applications[J]. Trans Noferrous Met Soc China,1999,9(1):326-334.
【7】BRADY M P,LIU C T,ZHU J H,et al. Effects of Fe additions on the mechanical properties and oxidation behavior of Cr2Ta Laves phase reinforced Cr[J]. Scripta Materialia,2005,52(9):815-819.
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【10】BRADY M P,TORTORELLI P F. The effect of microstructure and temperature on the oxidation behavior of two phase Cr-Cr2X(X=Nb,Ta) alloys[C]//Symposium on High Temperature Corrosion and Materials Chemistry.San Diego:The Electrhemical society,1998.
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【12】BRADY M P,TORTORELLI P F,WALKER L R. Oxidation behavior of Cr2N,CrNbN,and CrTaN phase mixtures formed on nitrided Cr and Laves-reinforced Cr alloys[J]. Oxidation of Metals,2004,61(5/6):379-401.
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【15】卢旭东,田素贵,于兴福,等. Ni-Cr-Ta-Al-Co-Mo合金在900 ℃和1 000 ℃的恒温氧化行为[J]. 材料研究学报,2011,23(4):427-432.
【16】BRADY M P,SACHENKO P. Effects of Fe on the oxidation/internal nitridation behavior and tensile properties of Cr and oxide dispersion ductilized Cr[J]. Scripta Materialia,2005,52:809-814.
【17】LIU C T,ZHU J H,BRADY M P,et al. Physical metallurgy and mechanical properties of transition-metal Laves phase alloys[J]. Intermetallics,2000,8:1119-1129.
【18】刘含莲,腾新营,王执福,等. Fe-Cr-Ni-N高温耐热钢的抗氧化性研究[J]. 铸造技术,2001(6):55-57.
【19】BRADY M P,ZHU J H,LIU C T,et al. Intermetallic reinforced Cr alloys for high-temperature use[J]. Materials at High Temperatures,1999,16(4):189-193.
【20】BhOWMIK A,PANG H T,EDMONDS I M,et al. Effect of silicon additions on the high temperature oxidation behaviour of Cr-Cr2Ta alloys[J]. Intermetallics,2013,32:373-383.
【21】BHOWMIK A,BENNETT R J,MONSERRAT B,et al. Alloys based on Cr-Cr2Ta containing Si[J]. Intermetallics,2014,48:62-70.
【22】黄旭,孙福生,王宝,等. Ti-Cr合金高温氧化行为的研究[J]. 航空材料学报,2000,20(3):16-20.
【23】BRADY M P,SMIALEK J L,HUMPHREY D L,et al. The role of Cr in promoting protective alumina scale formation by γ-based Ti-Al-Cr alloys-I.compatibility with alumina and oxidation behavior in oxygen[J]. Acta Materialia,1997,45(6):2357-2369.
【24】VAZQUEZ A,VARMA S K. High-temperature oxidation behavior of Nb-Si-Cr alloys with Hf additions[J]. Journal of Alloys and Compounds,2011,509:7027-7033.
【25】OHTA T,NAKAGAWA Y,KANENO Y,et al. Microstructures and mechanical properties of NbCr2 and ZrCr2 Laves phase alloys prepared by powder metallurgy[J]. Journal of Materials Science,2003,38(4):657-665.
【26】LIU C T,TORTORELLI P F,HORTON J A,et al. Efferts of alloy additions on the microstructure and properties of Cr-Cr2Nb alloy[J]. Materials Science and Engineering,1996,A214:23-32.
【27】肖平安. Laves相TiCr2微粒增强Ti基合金的制备及其组织、性能和力学行为的研究[D]. 长沙:中南大学,2002.
【28】郑海忠,鲁世强,闵嗣林,等. 稀土元素钇对Laves相NbCr2合金在1 100 ℃氧化行为的影响[J]. 机械工程材料,2009,33(3):94-97.
【29】苏倩,鲁世强,刘志和,等. Y2O3对Cr-Nb合金高温抗氧化性能作用机制的研究[J]. 航空材料学报,2008,28(6):67-71.
【30】HE Y R,RAPP R A,TORTORELLI P F. Oxidation-resistant Ge-doped silicide coating on Cr-Cr2Nb alloys by pack cementation[J]. Materials Science and Engineering A,1997,222:109-117.
【31】FOX-RABINOVICH G S,WEATHERLY G C,WILKINSON D S,et al. The role of chromium in protective alumina scale formation during the oxidation of ternary TiAlCr alloys in air[J]. Intermetallics,2004,12(2):165-180.
【32】FOX-RABINOVICH G S,WILKINSON D S,VELDHUIS S C,et al. Oxidation resistant Ti-Al-Cr alloy for protective coating applications[J]. Intermetallics,2006,14(2):189-197.
【33】陈云峰,熊华平,毛唯. 液相Al-Si共渗提高Ti3Al基合金高温抗氧化性[J]. 腐蚀科学与防护技术,2005,17(1):39-42.
【34】CARDONNE S M,KUMAR P,MICHALUK C A. Tantalum and its alloys[J]. Refractory Metal & Hard Material,1995,13:187-194.
【35】TIEN H,ZHU J H,LIU C T,et al. Effect of Ru additions on microstructure and mechanical properties of Cr-TaCr2 alloys[J]. Intermetallics,2005,13:361-366.
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