Galvanic Corrosion Behavior of Copper Alloys in Simulated Deep-sea Low Temperature Environment
摘 要
采用开路电位监测、线性极化等电化学手段, 探讨了舰船常用的管路材料B10以及硅黄铜在模拟深海环境中的电化学腐蚀行为, 同时采用自制的多通道电偶腐蚀测量仪和腐蚀失重法讨论了不同温度下B10和硅黄铜之间的电偶腐蚀行为。结果表明,在静态海水中, 腐蚀电偶序顺序为B10> 硅黄铜, B10作为偶合阴极受到保护, 硅黄铜为偶合阳极被加速腐蚀, 电偶腐蚀效应及电偶腐蚀敏感度随着温度的降低而降低, 因为温度降低一方面减小了阴阳两极之间的驱动力, 另一方面减弱了极化过程。
Abstract
Open circuit potential monitoring, linear polarization measurements and other electrochemical means in simulated deep-sea environment were applied to explore the electrochemical corrosion behavior of commonly used ship piping materials B10 and silicon brass. By selfmade multi-channel measuring instrument for galvanic corrosion and corrosion weight loss, the galvanic corrosion behavior of B10 and silicon brass under low temperature and hypoxia conditions was investigated. The results show that the corrosion potential sequence of the materials was B10>silicon brass. B10 alloy acting as the couple cathode was protected from corrosion, while silicon brass was the sacrificial anode. The galvanic effect and the susceptibility of the coupling reduced with decreasing temperature. Because the temperature decreasing on the one hand reduced the driving force between cathode and anode, on the other hand weakened the polarization process.
中图分类号 TG172.2 DOI 10.11973/fsyfh-201512011
所属栏目 试验研究
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收稿日期 2014/12/16
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备注郭为民(1968-),高工,硕士,从事环境试验研究,
引用该论文: ZHANG Xiao-mei,GUO Wei-min,ZHANG Hui-xia,FU Yu-bin,YANG Chao. Galvanic Corrosion Behavior of Copper Alloys in Simulated Deep-sea Low Temperature Environment[J]. Corrosion & Protection, 2015, 36(12): 1161
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参考文献
【1】曹楚南. 腐蚀电化学原理[M]. 北京:化学工业出版社,2004:40-41.
【2】王春丽, 吴建华, 李庆芬. 海洋环境电偶腐蚀研究现状与展望[J]. 中国腐蚀与防护学报, 2010, 30(5): 416-419.
【3】NORTH R F, PRYOR M J. The nature of protective film formed on a copper iron alloy[J]. Corrosion Science, 1969, 9(7): 509-516.
【4】NORTH R F, PRYOR M J. The Influence of corrosion product structure on the corrosion rate of Cu-Ni alloys[J]. Corrosion Science, 1970, 10(70): 297-311.
【5】SHALABY L A. Galvanic coupling of Ti with Cu and Al alloys in chloride media[J]. Corrosion Science,1971,11(10):767-787.
【6】VARELA F E, KURATA Y, SANADA N. The influence of temperature on the galvanic corrosion of a cast iron-stainless steel couple (prediction by boundary element method)[J]. Corrosion Science, 1997, 39(4): 775-788.
【7】李淑英, 李玮. 碳钢/紫铜在NaCl介质中的电偶行为[J]. 腐蚀科学与防护技术, 2000, 12(5): 300-302.
【8】BLASCO TAMARIT E, IGUAL MUNOZ A, ANTON J G, et al. Comparison between open circuit and imposed potential measurements to evaluate the effect of temperature on galvanic corrosion of the pair alloy 31-welded alloy 31 in LiBr solutions[J]. Corrosion Science, 2008, 50(12): 3590-3598.
【9】BALSCO TAMARIT E, IGUAL MUNOZ A, GARCIA ANTON J. Effect of temperature on the galvanic corrosion of a high alloyed austenitic stainless steel in its welded and nonwelded condition in LiBr solutions[J]. Corrosion Science,2007, 49: 4472-4490.
【10】朱相荣, 戴明安, 陈振进,等. 高流速海水中金属材料的腐蚀行为[J]. 中国腐蚀与防护学报, 1992, 12(2): 173-179.
【11】戴明安, 张英. 流动海水中电偶腐蚀动力学规律[J]. 腐蚀科学与防护技术, 1992, 3(4): 209-211.
【12】张英, 戴明安. 海水中舰船钢低电位差电偶的腐蚀[J]. 中国腐蚀与防护学报, 1993, 13(1):86-90.
【13】WAGNER C,TRAUD W. Concerning the evaluation of corrosion reactions by superposition of electrochemical partial reactions and concerning the potential formation on mixed electrodes[J]. Z Electrochem, 1938, 44: 391-396.
【14】HACK H P. Evaluation of galvanic corrosion[M]//Metals Hand-Book:Corrosion. Metals Park, Ohio:ASM International, 1987: 234-238.
【15】MELCHERS R E. Temperature effect on seawater immersion corrosion of 90:10 copper-nickel alloy[J]. Corrosion,2001,57(5):440-451.
【16】KEAR G,BARKER B D,STOKES K,et al. Electrochemical corrosion behavior of 90-10 Cu-Ni alloy in chloride-based electrolytes[J]. Journal of Applied Electrochemistry,2004,34(1):658-659.
【17】HB 5374-1987 不同金属电偶电流测定方法[S].
【2】王春丽, 吴建华, 李庆芬. 海洋环境电偶腐蚀研究现状与展望[J]. 中国腐蚀与防护学报, 2010, 30(5): 416-419.
【3】NORTH R F, PRYOR M J. The nature of protective film formed on a copper iron alloy[J]. Corrosion Science, 1969, 9(7): 509-516.
【4】NORTH R F, PRYOR M J. The Influence of corrosion product structure on the corrosion rate of Cu-Ni alloys[J]. Corrosion Science, 1970, 10(70): 297-311.
【5】SHALABY L A. Galvanic coupling of Ti with Cu and Al alloys in chloride media[J]. Corrosion Science,1971,11(10):767-787.
【6】VARELA F E, KURATA Y, SANADA N. The influence of temperature on the galvanic corrosion of a cast iron-stainless steel couple (prediction by boundary element method)[J]. Corrosion Science, 1997, 39(4): 775-788.
【7】李淑英, 李玮. 碳钢/紫铜在NaCl介质中的电偶行为[J]. 腐蚀科学与防护技术, 2000, 12(5): 300-302.
【8】BLASCO TAMARIT E, IGUAL MUNOZ A, ANTON J G, et al. Comparison between open circuit and imposed potential measurements to evaluate the effect of temperature on galvanic corrosion of the pair alloy 31-welded alloy 31 in LiBr solutions[J]. Corrosion Science, 2008, 50(12): 3590-3598.
【9】BALSCO TAMARIT E, IGUAL MUNOZ A, GARCIA ANTON J. Effect of temperature on the galvanic corrosion of a high alloyed austenitic stainless steel in its welded and nonwelded condition in LiBr solutions[J]. Corrosion Science,2007, 49: 4472-4490.
【10】朱相荣, 戴明安, 陈振进,等. 高流速海水中金属材料的腐蚀行为[J]. 中国腐蚀与防护学报, 1992, 12(2): 173-179.
【11】戴明安, 张英. 流动海水中电偶腐蚀动力学规律[J]. 腐蚀科学与防护技术, 1992, 3(4): 209-211.
【12】张英, 戴明安. 海水中舰船钢低电位差电偶的腐蚀[J]. 中国腐蚀与防护学报, 1993, 13(1):86-90.
【13】WAGNER C,TRAUD W. Concerning the evaluation of corrosion reactions by superposition of electrochemical partial reactions and concerning the potential formation on mixed electrodes[J]. Z Electrochem, 1938, 44: 391-396.
【14】HACK H P. Evaluation of galvanic corrosion[M]//Metals Hand-Book:Corrosion. Metals Park, Ohio:ASM International, 1987: 234-238.
【15】MELCHERS R E. Temperature effect on seawater immersion corrosion of 90:10 copper-nickel alloy[J]. Corrosion,2001,57(5):440-451.
【16】KEAR G,BARKER B D,STOKES K,et al. Electrochemical corrosion behavior of 90-10 Cu-Ni alloy in chloride-based electrolytes[J]. Journal of Applied Electrochemistry,2004,34(1):658-659.
【17】HB 5374-1987 不同金属电偶电流测定方法[S].
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