Y2O3含量对Ni-20Cr-5Al合金高温抗氧化性能的影响
Effect of Y2O3 Content on High Temperature Oxidation Resistance of Ni-20Cr-5Al Alloy
摘 要
将镍、铬、铝粉按比例混合后,再添加不同质量分数(0～5%)Y2O3粉作为弥散相, 采用粉末冶金技术制备了Ni-20Cr-5Al-xY2O3(质量分数/%)氧化物弥散强化镍基高温合金, 并在1 150 ℃下进行了100 h恒温氧化试验, 研究了Y2O3含量对其高温抗氧化性能的影响。结果表明: Y2O3质量分数为0~5%时, 试验合金在长时间氧化后均具有较好的高温抗氧化性能; Y2O3的添加有利于试验合金表面氧化膜中Cr2O3的形成, 但其质量分数为1%~5%时会同时降低氧化膜的致密性和附着性, 从而降低合金的高温抗氧化性能。
氧化物弥散强化
Y2O3
高温氧化
Ni-based superalloy
oxide dispersion strengthened
Y2O3
high temperature oxidation
Abstract
The 0-5wt% Y2O3 powders were added to the mixed powders of nickel, chromium and aluminum at a certain ratio as a dispersion phase, and then the Ni-20Cr-5Al-xY2O3 (mass/%) oxide dispersion strengthened Ni-based superalloys were prepared by the powder metallurgy technology. The isothermal oxidation tests of the alloys were carried out at 1 150 ℃ for 100 h and the effects of Y2O3 content on the high temperature oxidation resistance of the alloys were studied. The results show that the experimental alloys all had an excellent oxidation resistance after oxidation for a long time with the Y2O3 content of 0-5wt%.The addition of Y2O3 can promote the formation of Cr2O3 in the surface oxidation films of the experimental alloys, but also reduced the density and adhesion of the oxide films with the addition of 1wt%-5wt%, resulting in the decrease of the high temperature oxidation resistance of the alloys.
中图分类号 TG172.82 DOI 10.11973/jxgccl201604009
所属栏目 材料性能及其应用
基金项目 广西大学有色金属及材料加工新技术教育部重点实验室开放基金资助项目(GXKFJ09-21, GXKFJ09-04); 国家自然科学基金资助项目(51371059, 51001032)
收稿日期 2015/6/7
修改稿日期 2016/3/7
网络出版日期
作者单位点击查看
备注孙端君(1995-), 男, 湖北宜昌人, 本科生。
引用该论文: SUN Duan-jun,LIANG Chun-yuan,SHANG Jin-long,LAI Can-wei,YIN Ji-hui,SONG Ya-ru,ZHANG Xiu-hai. Effect of Y2O3 Content on High Temperature Oxidation Resistance of Ni-20Cr-5Al Alloy[J]. Materials for mechancial engineering, 2016, 40(4): 34～37
孙端君,梁春园,尚金龙,赖灿伟,尹继辉,宋亚茹,张修海. Y2O3含量对Ni-20Cr-5Al合金高温抗氧化性能的影响[J]. 机械工程材料, 2016, 40(4): 34～37
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】朱日彰,何业东,齐慧滨.高温腐蚀及耐高温腐蚀材料［M］.上海: 上海科学技术出版社,1995: 296-305.
【2】XIANG J H,GESMUNDO F,NIU Y.The oxidation of two ternary Ni-Cu-10at%Al alloys in 1 atm of pure O2 at 800-900 ℃［J］.Corrosion Science,2004,46: 2025-2039.
【3】HU Z Q,LIU L R,JIN T, et al.Development of the Ni-base single crystal superalloys［J］.Aero-engines,2005,31(3): 1-7.
【4】杜金辉, 邓群, 曲敬龙, 等.GH4169合金盘锻件制备技术发展趋势［J］.钢铁研究学报,2011,23(2): 130-133.
【5】吴卫东,柳光祖,李华林,等.氧化物弥散相的分布对ODS镍基合金高温持久性能的影响［J］.材料工程,1996(8): 6-9.
【6】柳光祖,田耘,单秉权.氧化物弥散强化高温合金［J］.粉末冶金技术,2001,19(1): 20-23.
【7】吴凯, 刘国权,胡本芙,等.新型镍基粉末高温合金微量元素的相研究［J］.稀有金属材料与工程,2011,40(2): 279-284.
【8】陈文婷,熊惟皓,张修海.Y2O3含量和烧结温度对ODS镍基合金性能的影响［J］.稀有金属材料与工程,2010,39(1): 112-116.
【9】IINO Y.Effects of high-temperature air and vacuum exposure on tensile properties and fracture of ODS alloy MA600［J］.Materials Science and Engineering: A,1997,234/236: 802-805.
【10】NGANBE M,HEILMAIER M.Modelling of particle strengthening in the γ′ and oxide dispersion strengthened nickel-base superalloy PM3030［J］.Materials Science and Engineering: A,2004,387/389: 609-612.
【11】赖灿伟,张修海,李伟洲,等.Y含量对Ni-20Cr合金高温抗氧化性能的影响［J］.广西大学学报,2014,39(6): 1426-1430.
【12】GUO H B,ZHANG T,WANG S X,et al.Effect of Dy on oxide scale adhesion of NiAl coatings at 1 200 ℃［J］.Corros Sci ,2011,53(6): 2228-2232.
【13】陈阳,吴树森,刘龙飞,等.一种铸造镍基高温合金的氧化行为［J］.铸造,2014(1): 62-66.
【14】李美栓.金属的高温腐蚀［M］.北京: 冶金工业出版社,2001.
【15】ZHANG X H,ZHANG C,ZHANG Y D,et al.Effect of yttrium and aluminum additions on isothermal oxidation behavior of Tribaloy T-700 alloys［J］.Corrosion Science,2014,88(6): 405-415.
【16】杨世伟, 刘海涛, 朱玲斌, 等.K4104合金渗Al-Si涂层的抗高温氧化性能研究［J］.中国腐蚀与防护学报, 2006,26(6): 370-375.
【17】STRINGER J, WILCOX B A, JAFFEE R I.The high-temperature oxidation of nickel-20wt% chromium alloys containing dispersed oxide phases［J］.Oxid Met, 1972, 5(1): 11-47.
【18】PINT B A, LEIBOWITZ J, DEVAN J H.The effect of anoxide dispersion on the critical Al content in Fe-Al alloys［J］.Oxid Met, 1999, 51(1/2): 181-197.
【19】马静,何业东,王俊, 等.1Cr13合金沉积Y2O3薄膜后的高温氧化行为［J］.材料保护,2008,41(7): 21-22.
【20】周涛,袁铁锤,李志友,等.两类Ni-Fe基合金抗氧化性能的对比研究［J］.矿冶工程,2006,26(4): 68-71.
【21】孔涛,熊惟皓,张志力,等.镍包覆Y2O3颗粒弥散强化镍基高温合金的抗热腐蚀性能［J］.机械工程材料,2013, 37(11): 43-48.
【22】刘贵立.Fe-Cr-Al合金高温氧化行为电子理论研究［J］.物理学报,2010,59(1): 494-498.
【2】XIANG J H,GESMUNDO F,NIU Y.The oxidation of two ternary Ni-Cu-10at%Al alloys in 1 atm of pure O2 at 800-900 ℃［J］.Corrosion Science,2004,46: 2025-2039.
【3】HU Z Q,LIU L R,JIN T, et al.Development of the Ni-base single crystal superalloys［J］.Aero-engines,2005,31(3): 1-7.
【4】杜金辉, 邓群, 曲敬龙, 等.GH4169合金盘锻件制备技术发展趋势［J］.钢铁研究学报,2011,23(2): 130-133.
【5】吴卫东,柳光祖,李华林,等.氧化物弥散相的分布对ODS镍基合金高温持久性能的影响［J］.材料工程,1996(8): 6-9.
【6】柳光祖,田耘,单秉权.氧化物弥散强化高温合金［J］.粉末冶金技术,2001,19(1): 20-23.
【7】吴凯, 刘国权,胡本芙,等.新型镍基粉末高温合金微量元素的相研究［J］.稀有金属材料与工程,2011,40(2): 279-284.
【8】陈文婷,熊惟皓,张修海.Y2O3含量和烧结温度对ODS镍基合金性能的影响［J］.稀有金属材料与工程,2010,39(1): 112-116.
【9】IINO Y.Effects of high-temperature air and vacuum exposure on tensile properties and fracture of ODS alloy MA600［J］.Materials Science and Engineering: A,1997,234/236: 802-805.
【10】NGANBE M,HEILMAIER M.Modelling of particle strengthening in the γ′ and oxide dispersion strengthened nickel-base superalloy PM3030［J］.Materials Science and Engineering: A,2004,387/389: 609-612.
【11】赖灿伟,张修海,李伟洲,等.Y含量对Ni-20Cr合金高温抗氧化性能的影响［J］.广西大学学报,2014,39(6): 1426-1430.
【12】GUO H B,ZHANG T,WANG S X,et al.Effect of Dy on oxide scale adhesion of NiAl coatings at 1 200 ℃［J］.Corros Sci ,2011,53(6): 2228-2232.
【13】陈阳,吴树森,刘龙飞,等.一种铸造镍基高温合金的氧化行为［J］.铸造,2014(1): 62-66.
【14】李美栓.金属的高温腐蚀［M］.北京: 冶金工业出版社,2001.
【15】ZHANG X H,ZHANG C,ZHANG Y D,et al.Effect of yttrium and aluminum additions on isothermal oxidation behavior of Tribaloy T-700 alloys［J］.Corrosion Science,2014,88(6): 405-415.
【16】杨世伟, 刘海涛, 朱玲斌, 等.K4104合金渗Al-Si涂层的抗高温氧化性能研究［J］.中国腐蚀与防护学报, 2006,26(6): 370-375.
【17】STRINGER J, WILCOX B A, JAFFEE R I.The high-temperature oxidation of nickel-20wt% chromium alloys containing dispersed oxide phases［J］.Oxid Met, 1972, 5(1): 11-47.
【18】PINT B A, LEIBOWITZ J, DEVAN J H.The effect of anoxide dispersion on the critical Al content in Fe-Al alloys［J］.Oxid Met, 1999, 51(1/2): 181-197.
【19】马静,何业东,王俊, 等.1Cr13合金沉积Y2O3薄膜后的高温氧化行为［J］.材料保护,2008,41(7): 21-22.
【20】周涛,袁铁锤,李志友,等.两类Ni-Fe基合金抗氧化性能的对比研究［J］.矿冶工程,2006,26(4): 68-71.
【21】孔涛,熊惟皓,张志力,等.镍包覆Y2O3颗粒弥散强化镍基高温合金的抗热腐蚀性能［J］.机械工程材料,2013, 37(11): 43-48.
【22】刘贵立.Fe-Cr-Al合金高温氧化行为电子理论研究［J］.物理学报,2010,59(1): 494-498.
相关信息
