咪唑基离子液体增塑聚合物的研究进展
Research Progress on Imidazole Ionic Liquid Plasticized Polymer
摘 要
综述了近十多年来咪唑基离子液体作为一种新型聚合物加工增塑剂的研究进展, 主要包括离子液体对聚合物力学性能、热学性能、聚集态结构、流变学行为等影响的研究, 并分析了离子液体增塑聚合物的机理, 最后展望了离子液体在聚合物加工中的应用前景。
聚合物加工
增塑
玻璃化转变温度
ionic liquid
polymer processing
plasticization
glass transition temperature
Abstract
The advanced progress on imidazole ionic liquid as novel polymer processing plasticizer is reviewed, the effects of ionic liquids on the mechanics proporties, thermology proporties, aggregation structure and rheological behavior of the polymer are studied, and the mechanism of ionic liquid plasticized polymer is analyzed. The research direction of ionic liquid in polymer processing is also prospected.
中图分类号 O631 DOI 10.11973/jxgccl201607001
所属栏目 综述
基金项目 国家自然科学基金资助项目(51373045)
收稿日期 2015/5/5
修改稿日期 2016/4/21
网络出版日期
作者单位点击查看
备注王周锋(1980-), 男, 山东菏泽人, 讲师, 博士。
引用该论文: WANG Zhou-feng,WANG Ping,DING Guo-xin,YANG Ji-nian,CHENG Guo-jun,GUI Hao-guan. Research Progress on Imidazole Ionic Liquid Plasticized Polymer[J]. Materials for mechancial engineering, 2016, 40(7): 1～6
王周锋,王平,丁国新,杨继年,程国君,桂豪冠. 咪唑基离子液体增塑聚合物的研究进展[J]. 机械工程材料, 2016, 40(7): 1～6
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参考文献
【1】张星辰. 离子液体-从理论基础到研究进展［M］. 北京: 化学工业出版社, 2009.
【2】张锁江, 徐春明, 吕兴梅, 等. 离子液体与绿色化学［M］. 北京: 科学出版社, 2009.
【3】张锁江, 刘晓敏, 姚晓倩, 等. 离子液体的前沿、进展及应用［J］. 中国科学: B辑, 2009, 39(10): 1134-1144.
【4】SHEA K M. Pediatric exposure and potential toxicity of phthalate plasticizers［J］. Pediatrics, 2003, 111(6): 1467-1474.
【5】SINGH S, LI S S L. Phthalates: toxicogenomics and inferred human diseases［J］. Genomics, 2011, 97(3): 148-157.
【6】丁运生, 王僧山, 余章普, 等. 咪唑基离子液体对聚丙烯抗静电性能的影响［J］. 高分子材料科学与工程, 2006(6): 99-101.
【7】唐海欧, 丁运生, 吴淑莹, 等. 咪唑基离子液体［C14mim］Br对LLDPE结构与性能的影响［J］. 高分子材料科学与工程, 2009(11): 83-85.
【8】DING Y, WANG P, WANG Z, et al. Magnesium hydroxide modified by 1-n-tetradecyl-3-carboxymethyl imidazolium chloride and its effects on the properties of LLDPE［J］. Polymer Engineering & Science, 2011, 51(8): 1519-1524.
【9】唐海欧, 丁运生, 李博轩. 咪唑基离子液体Br［C14im］(CH2)4［C14im］Br对PP结构与性能的影响［J］. 高分子学报, 2009(2): 191-194.
【10】张效敏, 丁运生, 吴淑莹, 等. 咪唑基离子液体修饰蒙脱土/聚丙烯复合材料的耐热老化性能［J］. 高分子材料科学与工程, 2009(6): 82-84.
【11】丁运生, 王僧山, 查敏, 等. 有机阳离子［C18mim］+在蒙脱土层间的物理化学吸附与聚集状态［J］. 物理化学学报, 2006(5): 548-551.
【12】SCOTT M P, BRAZEL C S, BENTON M G, et al. Application of ionic liquids as plasticizers for poly (methyl methacrylate)［J］. Chemical Communications, 2002, 13(13): 1370-1371.
【13】SCOTT M P, RAHMAN M, BRAZEL C S. Application of ionic liquids as low-volatility plasticizers for PMMA［J］. European Polymer Journal, 2003, 39(10): 1947-1953.
【14】SCOTT MARK P, BENTON MICHAEL G, RAHMAN M, et al. Plasticizing effects of imidazolium salts in PMMA: high-temperature stable flexible engineering materials［C］//Acs Symposium Series.［S.l.］: ［s.n.］, 2009: 468-477.
【15】娄帅, 刘晓霞, 李文斌, 等. 离子液体对PMMA绿色增塑性能［J］. 应用化学, 2006(8): 930-932.
【16】李博轩, 余坚, 丁运生, 等.［C14MIM］Br离子液体对聚丙烯超临界CO2发泡性能的影响［J］. 高等学校化学学报, 2010(5): 861-863.
【17】XU H, TONG F, YU J, et al. Synergistic effect of 1-Dodecyl-3-methylimidazolium hexafluorophosphate ionic liquid and montmorillonite on microcellular foaming behavior of poly(methyl methacrylate) by supercritical CO2［J］. Industrial & Engineering Chemistry Research, 2013, 52(34): 11988-11995.
【18】MOK M M, LIU X, BAI Z, et al. Effect of concentration on the glass transition and viscoelastic properties of poly(methyl methacrylate)/ionic liquid solutions［J］. Macromolecules, 2011, 44(4): 1016-1025.
【19】SUSAN M A B H, KANEKO T, NODA A, et al. Ion gels prepared by in situ radical polymerization of vinyl monomers in an ionic liquid and their characterization as polymer electrolytes［J］. Journal of the American Chemical Society, 2005, 127(13): 4976-4983.
【20】SEKI S, SUSAN M A B H, KANEKO T, et al. Distinct difference in ionic transport behavior in polymer electrolytes depending on the matrix polymers and incorporated salts［J］. The Journal of Physical Chemistry B, 2005, 109(9): 3886-3892.
【21】UENO K, INABA A, KONDOH M, et al. Colloidal stability of bare and polymer-grafted silica nanoparticles in ionic liquids［J］. Langmuir, 2008, 24(10): 5253-5259.
【22】LUNSTROOT K, DRIESEN K, NOCKEMANN P, et al. Luminescent ionogels based on europium-doped ionic liquids confined within silica-derived networks［J］. Chemistry of Materials, 2006, 18(24): 5711-5715.
【23】LUNSTROOT K, DRIESEN K, NOCKEMANN P, et al. Ionic liquid as plasticizer for europium (III)-doped luminescent poly (methyl methacrylate) films［J］. Physical Chemistry Chemical Physics, 2010, 12(8): 1879-1885.
【24】XIE Z L, XU H B, KUMKE M U, et al. A transparent, flexible, ion conductive, and luminescent PMMA ionogel based on a Pt/Eu bimetallic complex and the ionic liquid［Bmim］［N(Tf)2］［J］. Journal of Materials Chemistry, 2012, 22(16): 8110-8116.
【25】XIE Z L, JELICIC A, WANG F P, et al. Transparent, flexible, and paramagnetic ionogels based on PMMA and the iron-based ionic liquid 1-butyl-3-methylimidazolium tetrachloroferrate(iii)［Bmim］［FeCl4］［J］. Journal of Materials Chemistry, 2010, 20(42): 9543-9549.
【26】XIE Z L, HUANG X, TAUBERT A. DyeIonogels: proton-responsive ionogels based on a dye-ionic liquid exhibiting reversible color change［J］. Advanced Functional Materials, 2014, 24(19): 2837-2843.
【27】WANG H, WANG Y, ZHANG L, et al. Transparent and luminescent ionogels based on lanthanide-containing ionic liquids and poly(methyl methacrylate) prepared through an environmentally friendly method［J］. RSC Advances, 2013, 3(22): 8535-8540.
【28】张普玉, 彭李超, 李文斌, 等. 离子液体［bmim］PF6对聚乳酸的增塑作用［J］. 精细化工, 2008(6): 587-590.
【29】XU P, GUI H G, DING Y S. Effect of ionic liquid on chain segment motion and charge detrapping in poly(l-lactide)/ionic liquid composites［J］. Ionics, 2013, 19(11): 1579-1585.
【30】余芸, 桂豪冠, 何飞, 等. ILs-MPEG对PLA玻璃化转变温度和热稳定性的影响［J］. 工程塑料应用, 2012(6): 6-9.
【31】CHEN B K, WU T Y, CHANG Y M, et al. Ductile polylactic acid prepared with ionic liquids［J］. Chemical Engineering Journal, 2013, 215/216: 886-893.
【32】RAHMAN M, BRAZEL C S. Ionic liquids: new generation stable plasticizers for poly(vinyl chloride)［J］. Polymer Degradation and Stability, 2006, 91(12): 3371-3382.
【33】RAHMAN M, SHOFF HUGH W, BRAZEL CHRISTOPHER S. Ionic liquids as alternative plasticizers for poly(vinyl chloride): flexibility and stability in thermal, leaching, and UV environments［M］//Ionic Liquids in Polymer Systems.［S.l.］: American Chemical Society, 2005: 103-118.
【34】HOU L, WANG S. Study on ionic liquid［bmim］PF6 and［hmim］PF6 as plasticizer for PVC paste resin［J］. Polymer Bulletin, 2011, 67(7): 1273-1283.
【35】DIAS A M A, MARCENEIRO S, BRAGA M E M, et al. Phosphonium-based ionic liquids as modifiers for biomedical grade poly(vinyl chloride)［J］. Acta Biomaterialia, 2012, 8(3): 1366-1379.
【36】GIZLI N, NARL S, DEMIRCIOLU M. Characterization of poly(vinylchloride) (PVC) based cation exchange membranes prepared with ionic liquid［J］. Separation and Purification Technology, 2012, 97: 96-107.
【37】WANG N, ZHANG X X, LIU H H, et al. 1-Allyl-3-methylimidazolium chloride plasticized-corn starch as solid biopolymer electrolytes［J］. Carbohydrate Polymers, 2009, 76(3): 482-484.
【38】WANG N, ZHANG X X, LIU H H, et al. Ionically conducting polymers based on ionic liquid-plasticized starch containing lithium chloride［J］. Polymers & Polymer Composites, 2010, 18(1): 53-58.
【39】SANKRI A, ARHALIASS A, DEZ I, et al. Thermoplastic starch plasticized by an ionic liquid［J］. Carbohydrate Polymers, 2010, 82(2): 256-263.
【40】LEROY E, JACQUET P, COATIVY G, et al. Compatibilization of starch-zein melt processed blends by an ionic liquid used as plasticizer［J］. Carbohydrate Polymers, 2012, 89(3): 955-963.
【41】MARTINS M, CRAVEIRO R, PAIVA A, et al. Supercritical fluid processing of natural based polymers doped with ionic liquids［J］. Chemical Engineering Journal, 2014, 241: 122-130.
【42】陶长元, 彭敏, 牟天明, 等. 离子液体对聚合物增塑作用的研究进展［J］. 化工进展, 2011(增刊1): 207-211.
【2】张锁江, 徐春明, 吕兴梅, 等. 离子液体与绿色化学［M］. 北京: 科学出版社, 2009.
【3】张锁江, 刘晓敏, 姚晓倩, 等. 离子液体的前沿、进展及应用［J］. 中国科学: B辑, 2009, 39(10): 1134-1144.
【4】SHEA K M. Pediatric exposure and potential toxicity of phthalate plasticizers［J］. Pediatrics, 2003, 111(6): 1467-1474.
【5】SINGH S, LI S S L. Phthalates: toxicogenomics and inferred human diseases［J］. Genomics, 2011, 97(3): 148-157.
【6】丁运生, 王僧山, 余章普, 等. 咪唑基离子液体对聚丙烯抗静电性能的影响［J］. 高分子材料科学与工程, 2006(6): 99-101.
【7】唐海欧, 丁运生, 吴淑莹, 等. 咪唑基离子液体［C14mim］Br对LLDPE结构与性能的影响［J］. 高分子材料科学与工程, 2009(11): 83-85.
【8】DING Y, WANG P, WANG Z, et al. Magnesium hydroxide modified by 1-n-tetradecyl-3-carboxymethyl imidazolium chloride and its effects on the properties of LLDPE［J］. Polymer Engineering & Science, 2011, 51(8): 1519-1524.
【9】唐海欧, 丁运生, 李博轩. 咪唑基离子液体Br［C14im］(CH2)4［C14im］Br对PP结构与性能的影响［J］. 高分子学报, 2009(2): 191-194.
【10】张效敏, 丁运生, 吴淑莹, 等. 咪唑基离子液体修饰蒙脱土/聚丙烯复合材料的耐热老化性能［J］. 高分子材料科学与工程, 2009(6): 82-84.
【11】丁运生, 王僧山, 查敏, 等. 有机阳离子［C18mim］+在蒙脱土层间的物理化学吸附与聚集状态［J］. 物理化学学报, 2006(5): 548-551.
【12】SCOTT M P, BRAZEL C S, BENTON M G, et al. Application of ionic liquids as plasticizers for poly (methyl methacrylate)［J］. Chemical Communications, 2002, 13(13): 1370-1371.
【13】SCOTT M P, RAHMAN M, BRAZEL C S. Application of ionic liquids as low-volatility plasticizers for PMMA［J］. European Polymer Journal, 2003, 39(10): 1947-1953.
【14】SCOTT MARK P, BENTON MICHAEL G, RAHMAN M, et al. Plasticizing effects of imidazolium salts in PMMA: high-temperature stable flexible engineering materials［C］//Acs Symposium Series.［S.l.］: ［s.n.］, 2009: 468-477.
【15】娄帅, 刘晓霞, 李文斌, 等. 离子液体对PMMA绿色增塑性能［J］. 应用化学, 2006(8): 930-932.
【16】李博轩, 余坚, 丁运生, 等.［C14MIM］Br离子液体对聚丙烯超临界CO2发泡性能的影响［J］. 高等学校化学学报, 2010(5): 861-863.
【17】XU H, TONG F, YU J, et al. Synergistic effect of 1-Dodecyl-3-methylimidazolium hexafluorophosphate ionic liquid and montmorillonite on microcellular foaming behavior of poly(methyl methacrylate) by supercritical CO2［J］. Industrial & Engineering Chemistry Research, 2013, 52(34): 11988-11995.
【18】MOK M M, LIU X, BAI Z, et al. Effect of concentration on the glass transition and viscoelastic properties of poly(methyl methacrylate)/ionic liquid solutions［J］. Macromolecules, 2011, 44(4): 1016-1025.
【19】SUSAN M A B H, KANEKO T, NODA A, et al. Ion gels prepared by in situ radical polymerization of vinyl monomers in an ionic liquid and their characterization as polymer electrolytes［J］. Journal of the American Chemical Society, 2005, 127(13): 4976-4983.
【20】SEKI S, SUSAN M A B H, KANEKO T, et al. Distinct difference in ionic transport behavior in polymer electrolytes depending on the matrix polymers and incorporated salts［J］. The Journal of Physical Chemistry B, 2005, 109(9): 3886-3892.
【21】UENO K, INABA A, KONDOH M, et al. Colloidal stability of bare and polymer-grafted silica nanoparticles in ionic liquids［J］. Langmuir, 2008, 24(10): 5253-5259.
【22】LUNSTROOT K, DRIESEN K, NOCKEMANN P, et al. Luminescent ionogels based on europium-doped ionic liquids confined within silica-derived networks［J］. Chemistry of Materials, 2006, 18(24): 5711-5715.
【23】LUNSTROOT K, DRIESEN K, NOCKEMANN P, et al. Ionic liquid as plasticizer for europium (III)-doped luminescent poly (methyl methacrylate) films［J］. Physical Chemistry Chemical Physics, 2010, 12(8): 1879-1885.
【24】XIE Z L, XU H B, KUMKE M U, et al. A transparent, flexible, ion conductive, and luminescent PMMA ionogel based on a Pt/Eu bimetallic complex and the ionic liquid［Bmim］［N(Tf)2］［J］. Journal of Materials Chemistry, 2012, 22(16): 8110-8116.
【25】XIE Z L, JELICIC A, WANG F P, et al. Transparent, flexible, and paramagnetic ionogels based on PMMA and the iron-based ionic liquid 1-butyl-3-methylimidazolium tetrachloroferrate(iii)［Bmim］［FeCl4］［J］. Journal of Materials Chemistry, 2010, 20(42): 9543-9549.
【26】XIE Z L, HUANG X, TAUBERT A. DyeIonogels: proton-responsive ionogels based on a dye-ionic liquid exhibiting reversible color change［J］. Advanced Functional Materials, 2014, 24(19): 2837-2843.
【27】WANG H, WANG Y, ZHANG L, et al. Transparent and luminescent ionogels based on lanthanide-containing ionic liquids and poly(methyl methacrylate) prepared through an environmentally friendly method［J］. RSC Advances, 2013, 3(22): 8535-8540.
【28】张普玉, 彭李超, 李文斌, 等. 离子液体［bmim］PF6对聚乳酸的增塑作用［J］. 精细化工, 2008(6): 587-590.
【29】XU P, GUI H G, DING Y S. Effect of ionic liquid on chain segment motion and charge detrapping in poly(l-lactide)/ionic liquid composites［J］. Ionics, 2013, 19(11): 1579-1585.
【30】余芸, 桂豪冠, 何飞, 等. ILs-MPEG对PLA玻璃化转变温度和热稳定性的影响［J］. 工程塑料应用, 2012(6): 6-9.
【31】CHEN B K, WU T Y, CHANG Y M, et al. Ductile polylactic acid prepared with ionic liquids［J］. Chemical Engineering Journal, 2013, 215/216: 886-893.
【32】RAHMAN M, BRAZEL C S. Ionic liquids: new generation stable plasticizers for poly(vinyl chloride)［J］. Polymer Degradation and Stability, 2006, 91(12): 3371-3382.
【33】RAHMAN M, SHOFF HUGH W, BRAZEL CHRISTOPHER S. Ionic liquids as alternative plasticizers for poly(vinyl chloride): flexibility and stability in thermal, leaching, and UV environments［M］//Ionic Liquids in Polymer Systems.［S.l.］: American Chemical Society, 2005: 103-118.
【34】HOU L, WANG S. Study on ionic liquid［bmim］PF6 and［hmim］PF6 as plasticizer for PVC paste resin［J］. Polymer Bulletin, 2011, 67(7): 1273-1283.
【35】DIAS A M A, MARCENEIRO S, BRAGA M E M, et al. Phosphonium-based ionic liquids as modifiers for biomedical grade poly(vinyl chloride)［J］. Acta Biomaterialia, 2012, 8(3): 1366-1379.
【36】GIZLI N, NARL S, DEMIRCIOLU M. Characterization of poly(vinylchloride) (PVC) based cation exchange membranes prepared with ionic liquid［J］. Separation and Purification Technology, 2012, 97: 96-107.
【37】WANG N, ZHANG X X, LIU H H, et al. 1-Allyl-3-methylimidazolium chloride plasticized-corn starch as solid biopolymer electrolytes［J］. Carbohydrate Polymers, 2009, 76(3): 482-484.
【38】WANG N, ZHANG X X, LIU H H, et al. Ionically conducting polymers based on ionic liquid-plasticized starch containing lithium chloride［J］. Polymers & Polymer Composites, 2010, 18(1): 53-58.
【39】SANKRI A, ARHALIASS A, DEZ I, et al. Thermoplastic starch plasticized by an ionic liquid［J］. Carbohydrate Polymers, 2010, 82(2): 256-263.
【40】LEROY E, JACQUET P, COATIVY G, et al. Compatibilization of starch-zein melt processed blends by an ionic liquid used as plasticizer［J］. Carbohydrate Polymers, 2012, 89(3): 955-963.
【41】MARTINS M, CRAVEIRO R, PAIVA A, et al. Supercritical fluid processing of natural based polymers doped with ionic liquids［J］. Chemical Engineering Journal, 2014, 241: 122-130.
【42】陶长元, 彭敏, 牟天明, 等. 离子液体对聚合物增塑作用的研究进展［J］. 化工进展, 2011(增刊1): 207-211.
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