稀土掺杂氟氧化物微晶玻璃的研究进展
Research Progress of Rare Earth Doped Oxy-fluoride Glass Ceramics
摘 要
稀土掺杂氟氧化物微晶玻璃由于兼具氟化物和氧化物的优点, 在上转换三基色发光、光纤放大器、近红外发光器材等方面应用前景广阔。综述了稀土掺杂氟氧化物微晶玻璃在组成、性能及应用等方面的研究进展, 并对该领域存在的问题和未来发展趋势进行了探讨。
析出相
光学性能
应用
oxy-fluoride glass ceramic
precipitation phase
optical property
application
Abstract
Rare earth doped oxy-fluoride glass ceramics have greater prospects in the application of up-conversion color light-emitting material, fiber amplifier and near-infrared light-emitting materials, due to its advantages of both fluorides and oxides. The research progress on the composition, properties and applications of the rare earth doped oxy-fluoride glass ceramics are reviewed, and the existed problems and development trend in this field are also discussed.
中图分类号 TQ174 DOI 10.11973/jxgccl201608001
所属栏目
基金项目
收稿日期 2015/5/11
修改稿日期 2016/7/8
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备注李梦萱(1991-), 女, 贵州贵阳人, 硕士研究生。
引用该论文: LI Meng-xuan,GUO Ying-kui,ZHANG Yu. Research Progress of Rare Earth Doped Oxy-fluoride Glass Ceramics[J]. Materials for mechancial engineering, 2016, 40(8): 1～6
李梦萱,郭英奎,张 宇. 稀土掺杂氟氧化物微晶玻璃的研究进展[J]. 机械工程材料, 2016, 40(8): 1～6
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参考文献
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【21】MURAKAMI T, TANABE S. Preparation and 1.3 μm emission of Pr3+doped transparent nano-glass ceramics containing SrF2［J］. J Ceram Soc Jpn,2013,115(1346): 605-607.
【22】BISWAS K,BALAJI S,GHOSH D, et al. Near-infrared frequency down-conversion and cross-relaxation in Eu2+/Eu3+-Yb3+doped transparent oxyfluoride glass and glass-ceramics［J］. J Alloy Compd, 2014,608: 266-271.
【23】KATSUMATA T, YOSHIMURA T, KANAZAWA K, et al.Growth of lithium borate crystals from the vitreous state［J］. J Mater Res, 1994, 9(8): 2051-2056.
【24】HUANG Y D, MORTIER M, AUZEL F. Stark level analysis for Er3+-doped ZBLAN glass ［J］. Opt Mater, 2009, 17(4): 501-511.
【25】ZHAO L J, YANG J, SUN L D, et al. The saturation of the green up-conversion intensity in oxyfluoride glass-ceramics［J］.J Optoelectron: Las, 2011,12(12): 1236-1240.
【26】陈晓波,李美仙,SAWANOBORI N, 等.掺Er3+氟氧化物玻璃陶瓷的直接上转换敏化发光［J］.物理学报,2010,49(12): 2482-2487.
【27】MELTZER R S, YEN W M, ZHENG H, et al. Effect of the matrix on the radiative lifetimes of rare earth doped nano-particles embedded in matrices［J］. J Lumin, 2001, 217: 94-96.
【28】MELTZER R S,YEN W M,ZHENG H, et al. Evidence for long-range interactions between rare-earth impurity ions in nanocrystals embedded in matrices with the two-level system of the matrix［J］.Phys Rev B,2002,64(10): 101-105.
【29】GAO G J, WONDRACZEK L. Near-infrared downconversion in Pr3+/Yb3+co-doped boro-aluminosilicate glasses and LaBO3 glass ceramics［J］. Opt Mater Exps, 2013, 3(5): 633-644.
【30】LI D H,CHEN Y J,HUANG J H, et al.Near-infrared down-conversion in Pr3+-Yb3+ co-doped transparent glass ceramic containing Ca5(PO4)3F nanocrystals［J］. Phy B: Cond Mater, 2014, 446: 12-16.
【31】CLIFFORD A, HILL R G, TOWLER M R, et al. The crystallization of glasses from the ternary CaF2-CaAl2Si2O8-P2O5 system［J］.J Mater Sci,2001,36(16): 3955-3961.
【32】LAI Y Q,ZHANG J J,YU C L. Novel Tm3+-doped transparent fluorozirconate glass-ceramic containing nano-crystalline［J］.Chin Opt Lett,2006,4(10): 592-594.
【33】HU Y B,QIU J B,ZHOU D C, et al.Spectroscopic properties and mechanism of Tm3+-Er3+-Yb3+co-doped oxyfluoro germanate glass ceramic containing BaF2 nanocrystals ［J］. Chin Phys B, 2014, 23(2): 024205-1- 024205-6.
【34】TICK P A, BORRELLI N F,CORNELIUS L K, et al. Transparent glass ceramic for 1300nm amplifier applications［J］.J Appl Phys,1995,78(11): 6367-6374.
【35】KANG U K,CHUVAEVA T I,ONUSHCHENKO A A, et al. Radiative properties of Nd-doped transparent glass-ceramics in the lithium aluminosilicate system ［J］. J Non-Cryst Solids, 2000, 278(1/2/3): 75-84.
【36】HU Z J,MA E,WANG Y S, et al. Fluorescence property investigations on Er3+ doped oxyfluoride glass ceramics containing LaF3 nanocrystals［J］. Mater Chem and Phys,2006,100(2/3): 308-312.
【37】MENDEZ-RAMOS J,LAVEN V,MARTIN I R, et al. Optical properties of Er3+ ions in transparent glass ceramics［J］.J Alloy Compd,2001,323/324: 753-758.
【38】HUANG X Y,ZHANG Q Y. Efficient near-infrared quantum cutting in Zn2SiO4∶Tb3+, Yb3+ thin-film［J］. J Appl Phys, 2009,105(5): 53-58.
【39】YUAN J L,ZENG X Y,ZHAO J T, et al. Energy transfer mechanisms in Tb3+, Yb3+ codoped Y2O3 down conversion phosphor ［J］. J Phys D: App Phys,2008,41: 105-109.
【40】LAKSHMINARAYANA G, QIU J R. Near-infrared quantum cutting in RE3+/Yb3+ (RE=Pr,Tb,Tm): GeO2-B2O3-ZnO-LaF3 glasses via down conversion［J］. J Alloy and Compd, 2009, 481(1/2): 582-589.
【2】陆燕玲, 王俊, 孙宝德. 2 μm波段激光晶体研究进展［J］.无机材料学报, 2011, 20(3): 513-521.
【3】TICK P A,BORRELLI N F,CORNELIUS L K, et al. Transparent glass ceramics for 1 300 nm amplifier applications［J］. J Appl Phys, 2000,78(11): 6367-6374.
【4】WANG Y,OHWAKI J. New transparent vitroceramics codoped with Er3+and Yb3+ for efficient frequency upconversion［J］. Appl Phys Lett,1993,63(24): 3268-3270.
【5】DEJNEKA M J. The luminescence and structure of novel transparent oxyfluoride glass-ceramic［J］.J Non-Cryst Solids,1998,239(1): 149-155.
【6】DOWING E,HESSELINK L,RALSON J,et al. A three-color solidate, three dimensional display［J］. Science, 2000, 273(5279): 1185-1189.
【7】王轶敏.掺钕透明氟氧化物玻璃陶瓷激光材料的研究［D］.长春: 长春理工大学, 2007.
【8】何琛娟,陈晓波,SAWANOBORI N, 等.Ho3+在氟氧化物玻璃陶瓷中的光谱性质［J］. 量子电子学报, 2008, 19(2): 109-114.
【9】MNDEZ-RAMOS J, LAVN V, MARTN I R, et al. Role of the Eu3+ ions in the formation of transparent oxyfluoride glass ceramics［J］. J Appl Phys, 2001,89(10): 5307-5310.
【10】MORTIER M, AUZEL F. Rare-earth doped transparent glass-ceramics with high cross-sections［J］. J non-cryst solids, 1999,256: 361-365.
【11】KATAYAMA Y,TANABE S. Spectroscopy and 1 μm luminescence by visible quantum cutting in Pr3+-Yb3+ codoped glass［J］. Materials,2010,3(4): 2405-2411.
【12】CHEN Q J,ZHANG W J,QIAN Q, et al. Spectroscopic investigation of 2.02 μm emission in Ho3+/Tm3+ codoped transparent glass ceramic containing CaF2 nanocrystals［J］. J Appl Phys, 2010, 107(9): 093511.
【13】BABU P,JANG K H,RAO C S,et al. White light generation in Dy3+-doped oxyfluoride glass and transparent glass-ceramics containing CaF2 nanocrystals［J］. Opt Mater Exps, 2011, 19(3): 1836-1841.
【14】MORTIER M,GOLDNER P,CHATEAU C, et al.Erbium doped glass-ceramics: concentration effect on crystal structure and energy transfer between active ions［J］.J Alloy Compd, 2001, 32(4): 245-249.
【15】LEDEMI Y,TRUDEL A A,RIVERA V A G, et al. White light and multicolor emission tuning in triply doped Yb3+/Tm3+/Er3+ novel fluoro-phosphate transparent glass-ceramics［J］. J Mater Chem C, 2014, 2(25): 5046-5056.
【16】KOCHANOWICZ M,DOROSZ D,ZMOJDA J, et al.Up-conversion luminescence of Tb3+ ions in germanate glasses under diode-laser excitation of Yb3+［J］. Opt Mater Exps, 2014, 4(5): 1050-1056.
【17】唐彬, 王政, 羊毅, 等. 掺铒透明氧氟锗酸盐微晶玻璃的制备及发光性能研究［J］.光学学报, 2010, 30(8): 2344-2349.
【18】邱先念, 任国仲, 林乐静,等. 共掺Na+(K+)/Er3+50SiO2-30PbO-20PbF2-0.8ErF3玻璃陶瓷的上转换光谱性质［J］. 材料研究学报, 2011, 25(5): 545-549.
【19】ZHANG L L, XU J, HU Y C, et al. Near-infrared quantum cutting in Pr3+-Yb3+ co-doped oxyfluoride glass ceramics containing CaF2 nanocrystals［J］. J Wuhan Univ Technol Mater Sci, 2013, 28(3): 455-459.
【20】CHEN D Q,YU Y L,WANG Y S, et al.Cooperative energy transfer up-conversion and quantum cutting down-conversion in Yb3+: TbF3 nanocrystals embedded glass ceramics［J］. J Phys Chem C, 2010, 113(16): 6406-6410.
【21】MURAKAMI T, TANABE S. Preparation and 1.3 μm emission of Pr3+doped transparent nano-glass ceramics containing SrF2［J］. J Ceram Soc Jpn,2013,115(1346): 605-607.
【22】BISWAS K,BALAJI S,GHOSH D, et al. Near-infrared frequency down-conversion and cross-relaxation in Eu2+/Eu3+-Yb3+doped transparent oxyfluoride glass and glass-ceramics［J］. J Alloy Compd, 2014,608: 266-271.
【23】KATSUMATA T, YOSHIMURA T, KANAZAWA K, et al.Growth of lithium borate crystals from the vitreous state［J］. J Mater Res, 1994, 9(8): 2051-2056.
【24】HUANG Y D, MORTIER M, AUZEL F. Stark level analysis for Er3+-doped ZBLAN glass ［J］. Opt Mater, 2009, 17(4): 501-511.
【25】ZHAO L J, YANG J, SUN L D, et al. The saturation of the green up-conversion intensity in oxyfluoride glass-ceramics［J］.J Optoelectron: Las, 2011,12(12): 1236-1240.
【26】陈晓波,李美仙,SAWANOBORI N, 等.掺Er3+氟氧化物玻璃陶瓷的直接上转换敏化发光［J］.物理学报,2010,49(12): 2482-2487.
【27】MELTZER R S, YEN W M, ZHENG H, et al. Effect of the matrix on the radiative lifetimes of rare earth doped nano-particles embedded in matrices［J］. J Lumin, 2001, 217: 94-96.
【28】MELTZER R S,YEN W M,ZHENG H, et al. Evidence for long-range interactions between rare-earth impurity ions in nanocrystals embedded in matrices with the two-level system of the matrix［J］.Phys Rev B,2002,64(10): 101-105.
【29】GAO G J, WONDRACZEK L. Near-infrared downconversion in Pr3+/Yb3+co-doped boro-aluminosilicate glasses and LaBO3 glass ceramics［J］. Opt Mater Exps, 2013, 3(5): 633-644.
【30】LI D H,CHEN Y J,HUANG J H, et al.Near-infrared down-conversion in Pr3+-Yb3+ co-doped transparent glass ceramic containing Ca5(PO4)3F nanocrystals［J］. Phy B: Cond Mater, 2014, 446: 12-16.
【31】CLIFFORD A, HILL R G, TOWLER M R, et al. The crystallization of glasses from the ternary CaF2-CaAl2Si2O8-P2O5 system［J］.J Mater Sci,2001,36(16): 3955-3961.
【32】LAI Y Q,ZHANG J J,YU C L. Novel Tm3+-doped transparent fluorozirconate glass-ceramic containing nano-crystalline［J］.Chin Opt Lett,2006,4(10): 592-594.
【33】HU Y B,QIU J B,ZHOU D C, et al.Spectroscopic properties and mechanism of Tm3+-Er3+-Yb3+co-doped oxyfluoro germanate glass ceramic containing BaF2 nanocrystals ［J］. Chin Phys B, 2014, 23(2): 024205-1- 024205-6.
【34】TICK P A, BORRELLI N F,CORNELIUS L K, et al. Transparent glass ceramic for 1300nm amplifier applications［J］.J Appl Phys,1995,78(11): 6367-6374.
【35】KANG U K,CHUVAEVA T I,ONUSHCHENKO A A, et al. Radiative properties of Nd-doped transparent glass-ceramics in the lithium aluminosilicate system ［J］. J Non-Cryst Solids, 2000, 278(1/2/3): 75-84.
【36】HU Z J,MA E,WANG Y S, et al. Fluorescence property investigations on Er3+ doped oxyfluoride glass ceramics containing LaF3 nanocrystals［J］. Mater Chem and Phys,2006,100(2/3): 308-312.
【37】MENDEZ-RAMOS J,LAVEN V,MARTIN I R, et al. Optical properties of Er3+ ions in transparent glass ceramics［J］.J Alloy Compd,2001,323/324: 753-758.
【38】HUANG X Y,ZHANG Q Y. Efficient near-infrared quantum cutting in Zn2SiO4∶Tb3+, Yb3+ thin-film［J］. J Appl Phys, 2009,105(5): 53-58.
【39】YUAN J L,ZENG X Y,ZHAO J T, et al. Energy transfer mechanisms in Tb3+, Yb3+ codoped Y2O3 down conversion phosphor ［J］. J Phys D: App Phys,2008,41: 105-109.
【40】LAKSHMINARAYANA G, QIU J R. Near-infrared quantum cutting in RE3+/Yb3+ (RE=Pr,Tb,Tm): GeO2-B2O3-ZnO-LaF3 glasses via down conversion［J］. J Alloy and Compd, 2009, 481(1/2): 582-589.
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