低碳钢表面复合硅烷膜的制备与防腐蚀性能
Preparation and Anti-corrosion Behaviour of Hybrid Silane Coating on Surface of Mild Steel
摘 要
在碳钢表面制备了BTSPA、BTSE、γ-APS复合硅烷膜，采用电化学方法和红外吸收光谱法研究了水解时间和固化温度对复合硅烷膜耐蚀性的影响。结果表明：水解时间为9 h，固化温度为90 ℃时所制备的硅烷膜的耐蚀性最优。
水解时间
固化温度
低碳钢
hybrid silane coating
hydrolysis time
curing temperature
mild steel
Abstract
BTSPA, BTSE, γ-APS composite silylanization films were prepared on the surface of carbon steel. Electrochemical methods and infrared spectroscopy were used to study the effect of hydrolysis time and curing temperature on the corrosion resistance of the composite silylanization films. The results showed that anti-permeability of the hybrid silane coating was excellent while the curing temperature was 90 ℃ and the hydrolysis time was 9 h.
中图分类号 TG174.4 DOI 10.11973/fsyfh-201609004
所属栏目 试验研究
基金项目
收稿日期 2015/10/29
修改稿日期
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备注李天一(1970-)，副教授，从事金属表面防护方面的研究。
引用该论文: LI Tian-yi,ZHU Xiao-fei. Preparation and Anti-corrosion Behaviour of Hybrid Silane Coating on Surface of Mild Steel[J]. Corrosion & Protection, 2016, 37(9): 711
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参考文献
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【2】VAN O W J,ZHU D. Corrosion protection properties of organofunctional silanes an overview[J]. Tsinghua Science & Technology,2005,10(6):639-664.
【3】FRANQUET A,TERRYN H,VEREECKEN J S I. Phosphonic acid/silica-based films:A potential treatment for corrosion protection[J]. Corrosion Science,2012,60:173-180.
【4】PU Z,VAN O W J,MARK J E J. Corrosion behaviour of sol-gel treated and painted AA2024 aluminium alloy[J]. Progress in Organic Coatings,2010,69(2):133-142.
【5】宋义全,杜翠薇,李晓刚,等. 有机涂层厚度对低碳钢腐蚀规律的影响[J]. 腐蚀与防护,2003,24(10):432-434.
【6】NAJMEH A,REZA N,MOHSEN S. Effect of curing conditions on the protective performance of an ecofriendly hybrid silane sol-gel coating with clay nanoparticles applied on mild steel[J]. Industrial and Engineering Chemistry Research,2014,53(26):10644-10652.
【7】YANG L X,ZHANG Y X,LEI X L,et al. Effect of solution concentration on the structures and corrosion inhibition behavior of γ-APS films fabricated on surface of low carbon steel[J]. Wuhan University of Technology-Mater,2012,28(2):224-230.
【8】SONG J,VAN O W J. Bonding and corrosion protection mechanisms of γ-APS and BTSE silane films on aluminum substrates[J]. Adhesion Science Technology,2003,17(16):2191-2221.
【9】XUE D C,WILLIAN J V O. Corrosion performance improvement of hot-dipped galvanized (HDG) steels by electro-deposition of epoxy-resin-ester modified bis-\[triethoxysilyl\] ethane (BTSE) coatings[J]. Progress in Organic Coatings,2013,76(7):1095-1102.
【10】MOTTEA C,POELMANA M,ROOBROECKA A,et al. Improvement of corrosion protection offered to galvanized steel by incorporation of lanthanide modified nanoclays in silane layer[J]. Progress in Organic Coatings,2012,74(4):326-333.
【11】张微啸,李成涛, 陈建军, 等. 304L不锈钢在硼酸水溶液中的腐蚀行为[J]. 腐蚀与防护,2015,36(1):68-70.
【12】FEDEL M,OLIVIER M,POELMAN M,et al. Corrosion protection properties of silane pre-treated powder coated galvanized steel[J]. Progress in Organic Coatings,2009,66(2):118-128.
【13】WOO H,REUCRPOFT P J,JACOB R J J. Polybenzoxazine/SiO2 nanocomposite coatings for corrosion protectionof mild steel[J]. Corrosion Science,2014,80:269-275.
【14】XIAN X C,CHEN M L,LI L X,et al. Key factors influencing the stability of silane solution during long-term surface treatment on carbon steel[J]. Corrosion Science,2013,74:283-289.
【15】VAN O W J,ZHU D. Electrochemical impedance spectroscopy of bis-\[triethoxysilypropyl\] tetrasulfide on Al 2024-T3 substrates[J]. Corrosion Science,2001,57(5):413-427.
【16】VAN O W J,ZHU D,STACY M,et al. Corrosion protection properties of organofunctional silanes: an overview[J]. Tsinghua Science and Technology,2005,10(6):639-665.
【17】张鉴清. 交流阻抗法评价有机涂层[J]. 腐蚀科学与防护技术,1989,3(1):15-20.
【18】ZHOU C L,LU X,ZHONG X,et al. Polybenzoxazine/SiO2 nanocomposite coatings for corrosion protection of mild steel[J]. Corrosion Science,2014,80:269-275.
【19】周学华,陈秋荣,卫中领,等. 镁合金化学转化膜[J]. 腐蚀与防护,2004,11(25):468-472.
【20】WANG Y B,LI Y N,WANG F. Polymeric organo-silane coatings for aluminum alloy corrosion protection by self-assembled method[J]. E-Journal of Chemistry,2012,9(1):435-442.
【21】崔航,谭澄宇,郑勇,等. 铜经BTA和MBT钝化处理后在NaCl溶液中电化学行为分析[J]. 中南大学学报(自然科学版),2011,42(11):3336-3341.
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