黏结相组成对Ti(C,N)基金属陶瓷高温氧化行为的影响
Effects of Binder Components on High-Temperature Oxidation Behavior of Ti(C, N)-based Cermets
摘 要
以Co-Ni、Co-Ni-Fe、Co-Ni-RE、Co-Ni-Cr合金和AlCoCrFeNi合金为黏结相制备了Ti(C,N)基金属陶瓷, 研究了这五种金属陶瓷在1 100 ℃静态空气中的氧化行为, 分析了黏结相对其高温氧化行为的影响。结果表明: 以前四种合金为黏结相的金属陶瓷的氧化动力学曲线均基本符合扩散过程控制的抛物线规律, 且氧化速率常数都是分阶段变化的; 以多主元AlCoCrFeNi高熵合金为黏结相则大大提高了Ti(C,N)基金属陶瓷的抗高温氧化性能, 这主要归因于黏结相组元中铝元素的活性较强, 易于形成较稳定、氧化层致密的, 从而使得氧的传输被极大地抑制。
黏结相
高温氧化行为
高熵合金
Ti(C,N)-based cermet
binder
high-temperature oxidation behavior
high-entropy alloy
Abstract
Five kinds of Ti(C,N)-based cermets were prepared by taking Co-Ni, Co-Ni-Fe,Co-Ni-RE, Co-Ni-Cr and AlCoCeFeNi alloys as binders, and then the oxidation behavior of the five kinds of Ti(C,N)-based cermets with different binders at 1 100 ℃ in static air was studied, and then the effect of binders on high-temperature oxidation behavior was analyzed. The results show that the oxidation kinetics curves of four Ti(C,N)-based cermets which use the first four alloys as binder followed a parabolic-like law, and their oxidation rate constants changed by stages. The addition of multi-component AlCoCrFeNi high-entropy alloy increased the high-temperature oxidation resistance of Ti(C,N)-based cermet, because the activity of Al element was relatively strong and easy to form a steady and dense oxide scale, which is effective to impede the oxygen transport.
中图分类号 TG148 DOI 10.11973/jxgccl201611016
所属栏目 材料性能及应用
基金项目 国家自然科学基金资助项目(51164015); 稀贵金属先进材料协同创新中心协同创新基金项目(2014XT01); 稀贵金属综合利用新技术国家重点实验室开放课题项目(SKL-SPM-201546)
收稿日期 2015/7/30
修改稿日期 2016/9/16
网络出版日期
作者单位点击查看
备注朱刚(1986-), 男, 云南昭通人, 助理研究员, 博士。
引用该论文: ZHU Gang,XIE Ming,CHEN Jia-lin,JIA Hai-long,LI Zai-jiu,LIU Man-men. Effects of Binder Components on High-Temperature Oxidation Behavior of Ti(C, N)-based Cermets[J]. Materials for mechancial engineering, 2016, 40(11): 75～80
朱 刚,谢 明,陈家林,贾海龙,李再久,刘满门. 黏结相组成对Ti(C,N)基金属陶瓷高温氧化行为的影响[J]. 机械工程材料, 2016, 40(11): 75～80
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参考文献
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【2】PASTOR H. Titanium carbonitride-based hard alloy for cutting tools［J］. Mater Sci Eng A,1988, 105: 401-409.
【3】BOLOGNINI S, FEUSIER G, MARI D,et al. High temperature mechanical behaviour of Ti(C, N)-Mo-Co cermets［J］. Int J Refract Met Hard Mater,1998, 16: 257-268.
【4】D′ERRICO G E, BUGLIOSI S, GUGLIELMI E. Tool-life reliability of cermet inserts in milling tests［J］. J Mater Process Tech,1998, 77: 337-343.
【5】MONTEVERDE F, BELLOSI A. Oxidation behaviour of titanium carbonitride based materials［J］.Corros Sci, 2002, 44: 1967-1982.
【6】PARK D S, PARK C, LEE Y D. Oxidation of Ti(C,N)-based ceramics at 1373K in air［J］.J Am Ceram Soc,2000,83: 672-674.
【7】GMEZ B, JIMNEZ-SUAREZ A, GORDO E. Oxidation and tribological behaviour of an Fe-based MMC reinforced with TiCN particles［J］. Int J Refract Met Hard Mater, 2009, 27: 360-366.
【8】陈明昆, 熊惟皓, 范畴, 等.不同方法制备TiC/Ni3Al金属陶瓷的组织与性能［J］.机械工程材料, 2014, 38(12): 10-14.
【9】YANG Qing-qing, XIONG Wei-hao, LI Shi-qi,et al. Early high temperature oxidation behaviour of Ti(C,N)-based cermets in air［J］.Corros Sci, 2010, 52: 3205-3211.
【10】YANG Qing-qing, XIONG Wei-hao, LI Shi-qi,et al. Characterization of oxide scales to evaluate high temperature oxidation behavior of Ti(C,N)-based cermets in static air［J］. J Alloys Compd, 2010, 506: 461-467.
【11】EVANS U R.金属的腐蚀和氧化［M］. 北京: 机械工业出版社, 1976: 695.
【12】ROY T K, BALASUBRAMANIAM R, GHOSH A. High-temperature oxidation of Ti3Al-based titanium aluminides in oxygen［J］. Metallurgical and Material Transactions A,1996,27: 3993-4002.
【13】BIRKS N, MEIER G H. Introduction to high temperature oxidation of metals［M］. London: ［s.n.］, 1998: 42.
【14】郑海忠. Laves相NbCr2基合金的制备、增韧及高温氧化行为与机理研究［D］. 南京: 南京航空航天大学, 2009.
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