Determination of Au in Ores Based on the Transfer of Fluorescence Resonance Energy Between Carbon Quantum Dots and Eosin Y
摘 要
在聚乙烯醇存在下的pH 6.6磷酸氢二钠-柠檬酸钠缓冲溶液中,碳量子点与曙红Y(EY)的荧光共振能量转移,使EY的荧光增强。在该体系中,碳量子点作为能量供体,EY作为能量受体。当加入Au3+后,体系中EY的荧光发生猝灭。且测得金的线性范围为0.34~39.20 mg·L-1,方法的检出限(3s/k)为0.17 mg·L-1。据此,将该反应体系应用于矿石中金量的测定。用标准加入法测定了该方法的回收率及精密度,测得回收率在98.8%~104%之间,测定值的相对标准偏差(n=6)在0.13%~0.17%之间。
Abstract
In a phosphate and citrate buffer medium of pH 6.6 and in the presence of polyvinyl alcohol, intensity of fluorescence of eosin Y (EY) was enhanced due to the transfer of fluorescence resonance energy between carbon quantum dots (CQDs) and EY, during which the CQDs acted as energy donor while EY acted as energy receptor. However, the fluorescence intensity of the system was quenched in the presence of Au3+; and it was shown that linearity range was found between 0.34 mg·L-1 and 39.20 mg·L-1 of Au3+, with detection limit (3s/k) of 0.17 mg·L-1. Based on these facts, a fluorescence spectrometric method was proposed for determination of gold in ores. Recovery and precision of the method were tested by standard addition method, giving values of recovery and RSD′s (n=6) in the ranges of 98.8%-104% and 0.13%-0.17% respectively.
中图分类号 O657.3 DOI 10.11973/lhjy-hx201612011
所属栏目 工作简报
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收稿日期 2015/12/30
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联系人作者陶慧林(thl@glut.edu.cn)
备注陶慧林(1961-)女,广西贺州人,教授,主要从事分析化学研究工作。
引用该论文: TAO Hui-lin,SUN Chao,LIAO Xiu-fen,LIANG Xiao-qian. Determination of Au in Ores Based on the Transfer of Fluorescence Resonance Energy Between Carbon Quantum Dots and Eosin Y[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2016, 52(12): 1408~1413
陶慧林,孙超,廖秀芬,梁小倩. 基于碳量子点与曙红Y荧光共振能量的转移测定矿石中金[J]. 理化检验-化学分册, 2016, 52(12): 1408~1413
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参考文献
【1】黄仁忠.碘量法测定金的工作实践[J].福建分析测试, 2008,17(2):34-35.
【2】刘海珂.固相分光光度法测定痕量金属元素的研究与应用[D].呼和浩特:内蒙古大学, 2014.
【3】KHALIFA H, ISMAIL I A, ZAKY M. Determination of gold(Ⅲ) alone or in some mixtures and alloys by potentiometric titration of iodide[J]. Microchemical Journal, 1984,30(3):327-333.
【4】MALLAH A, MEMON S Q, SOLANGI A R. Separation and determination of chromium(Ⅲ) chromium(Ⅵ), gold(Ⅲ) and arsenic(Ⅴ) by capillary zone electrophoresis using 2-acetylpyridine-4-phenylthiosemicarbazone as complexing reagent[J]. Chem Soc Pak, 2014,36(2):255-262.
【5】ASHKENANI H, TAHER M A. Use of ionic liquid in simultaneous microextraction procedure for determination of gold and silver by ETAAS[J]. Microchemical Journal, 2012,103:185-190.
【6】OZDEMIR C, SACMACI S, KARTALO S, et al. Determination of gold and palladium in environmental samples by FAAS after dispersive liquid-liquid microextraction pretreatment[J]. Journal of Industrial and Engineering Chemistry, 2014,20:4059-4065.
【7】OZDES D, DURAN C, SERENCAM H, et al. Selective separation, preconcentration, and determination of Au(Ⅲ) ions in environmental samples by coprecipitation with a 1,2,4-triazole derivative[J]. Atomic Spectroscopy, 2013,34(5):164-169.
【8】王立平,杨明灵.泡沫塑料动态吸附-火焰原子吸收光谱法测定金[J].化工时刊, 2012,26(6):29-31.
【9】BAYAT M, BEYKI M H, SHEMIRANI F. One-step and biogenic synthesis of magnetic Fe3O4-Fir sawdust composite: application for selective preconcentration and determination of gold ions[J]. Journal of Industrial and Engineering Chemistry, 2015,21(1):912-919.
【10】CUBUK S, KAHRAMAN M V, YETIMOGLU E K, et al. Photocured thiolene based optical fluorescence sensor for determination of gold(Ⅲ)[J]. Analytica Chimica Acta, 2014,812:215-221.
【11】MAHPISHANIAN S, SHEMIRANI F. Ionic liquid-based modified cold-induced aggregation microextraction (M-CIAME) as a novel solvent extraction method for determination of gold in saline solutions[J]. Minerals Engineering, 2010,23:823-825.
【12】BEHBAHANI M, GORJI T, MAHYARI M, et al. Application of polypropylene amine dendrimers (POPAM)-grafted MWCNTs hybrid materials as a new sorbent for solid-phase extraction and trace determination of gold(Ⅲ) and palladium(Ⅱ) in food and environmental samples[J]. Food Analytical Methods, 2013,7(5):957-966.
【13】韩晓峰,王丽,陈伟,等.中国化学会第28届学术年会第九分会场摘要集[C].北京:中国化学会, 2012.
【14】GUO Y M, WANG Z, SHAO H W, et al. Hydrothermal synthesis of highly fluorescent carbon nanoparticles from sodium citrate and their use for the detection of mercury ions[J]. Carbon, 2013,5(2):583-589.
【15】徐学涛,杜志云,卢宇靖,等.一种具有双重功能的可视化pH荧光探针的合成及光谱研究[J].分析测试学报, 2011,30(10):1183-1186.
【16】葛艳梅.王水溶样-火焰原子吸收光谱法直接测定高品位金矿石的金量[J].岩石分析, 2014,33(4):491-496.
【17】羊波,杨新周,李银科,等.石墨炉原子吸收光谱法测定矿石中铂、钯、铑、铱[J].理化检验-化学分册, 2012,48(5):583-585.
【2】刘海珂.固相分光光度法测定痕量金属元素的研究与应用[D].呼和浩特:内蒙古大学, 2014.
【3】KHALIFA H, ISMAIL I A, ZAKY M. Determination of gold(Ⅲ) alone or in some mixtures and alloys by potentiometric titration of iodide[J]. Microchemical Journal, 1984,30(3):327-333.
【4】MALLAH A, MEMON S Q, SOLANGI A R. Separation and determination of chromium(Ⅲ) chromium(Ⅵ), gold(Ⅲ) and arsenic(Ⅴ) by capillary zone electrophoresis using 2-acetylpyridine-4-phenylthiosemicarbazone as complexing reagent[J]. Chem Soc Pak, 2014,36(2):255-262.
【5】ASHKENANI H, TAHER M A. Use of ionic liquid in simultaneous microextraction procedure for determination of gold and silver by ETAAS[J]. Microchemical Journal, 2012,103:185-190.
【6】OZDEMIR C, SACMACI S, KARTALO S, et al. Determination of gold and palladium in environmental samples by FAAS after dispersive liquid-liquid microextraction pretreatment[J]. Journal of Industrial and Engineering Chemistry, 2014,20:4059-4065.
【7】OZDES D, DURAN C, SERENCAM H, et al. Selective separation, preconcentration, and determination of Au(Ⅲ) ions in environmental samples by coprecipitation with a 1,2,4-triazole derivative[J]. Atomic Spectroscopy, 2013,34(5):164-169.
【8】王立平,杨明灵.泡沫塑料动态吸附-火焰原子吸收光谱法测定金[J].化工时刊, 2012,26(6):29-31.
【9】BAYAT M, BEYKI M H, SHEMIRANI F. One-step and biogenic synthesis of magnetic Fe3O4-Fir sawdust composite: application for selective preconcentration and determination of gold ions[J]. Journal of Industrial and Engineering Chemistry, 2015,21(1):912-919.
【10】CUBUK S, KAHRAMAN M V, YETIMOGLU E K, et al. Photocured thiolene based optical fluorescence sensor for determination of gold(Ⅲ)[J]. Analytica Chimica Acta, 2014,812:215-221.
【11】MAHPISHANIAN S, SHEMIRANI F. Ionic liquid-based modified cold-induced aggregation microextraction (M-CIAME) as a novel solvent extraction method for determination of gold in saline solutions[J]. Minerals Engineering, 2010,23:823-825.
【12】BEHBAHANI M, GORJI T, MAHYARI M, et al. Application of polypropylene amine dendrimers (POPAM)-grafted MWCNTs hybrid materials as a new sorbent for solid-phase extraction and trace determination of gold(Ⅲ) and palladium(Ⅱ) in food and environmental samples[J]. Food Analytical Methods, 2013,7(5):957-966.
【13】韩晓峰,王丽,陈伟,等.中国化学会第28届学术年会第九分会场摘要集[C].北京:中国化学会, 2012.
【14】GUO Y M, WANG Z, SHAO H W, et al. Hydrothermal synthesis of highly fluorescent carbon nanoparticles from sodium citrate and their use for the detection of mercury ions[J]. Carbon, 2013,5(2):583-589.
【15】徐学涛,杜志云,卢宇靖,等.一种具有双重功能的可视化pH荧光探针的合成及光谱研究[J].分析测试学报, 2011,30(10):1183-1186.
【16】葛艳梅.王水溶样-火焰原子吸收光谱法直接测定高品位金矿石的金量[J].岩石分析, 2014,33(4):491-496.
【17】羊波,杨新周,李银科,等.石墨炉原子吸收光谱法测定矿石中铂、钯、铑、铱[J].理化检验-化学分册, 2012,48(5):583-585.
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