TiO2压敏陶瓷电性能的研究现状
Research Status of TiO2 Based Varistor Ceramics
摘 要
综述了粉体尺寸、烧结温度、保温时间、掺杂剂的选择及含量等对TiO2压敏陶瓷压敏电压、非线性系数、介电损耗和介电常数等电性能以及晶体微观结构影响的研究现状，并指出TiO2压敏陶瓷在小型化和多功能化等方面的发展是今后重要的研究方向。
压敏陶瓷
制备工艺
电性能
titanium dioxide
varistor ceramic
preparation process
electrical property
Abstract
The effects of some experiment parameters, such as powder size, sintering temperature, soaking time, the type of dopant and their content on electrical properties of TiO2 varistor ceramics are summarized, as well as their crystal microstructures. The electrical properties include varistor voltage, nonlinear coefficient, dielectric loss, dielectric constant and so on. It is pointed that the research focus is on the development tendency in miniaturization and multi-functionalization of TiO2 varistor ceramics.
中图分类号 TN304 DOI 10.11973/jxgccl201701001
所属栏目 综述
基金项目 上海市优秀技术带头人计划资助项目（14XD1425400）
收稿日期 2015/10/27
修改稿日期 2016/11/29
网络出版日期
作者单位点击查看
备注王宇(1992-),男,江苏扬州人,硕士研究生。
引用该论文: WANG Yu,ZHANG Ke-min,LI Wen-ge,YAO Wei-hua. Research Status of TiO2 Based Varistor Ceramics[J]. Materials for mechancial engineering, 2017, 41(1): 1～6
王宇,张可敏,李文戈,尧巍华. TiO2压敏陶瓷电性能的研究现状[J]. 机械工程材料, 2017, 41(1): 1～6
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】袁明军, 崔文权, 李苹,等. TiO2压敏电阻的研究与应用[J]. 材料科学与工艺, 2008(6):751-754.
【2】SANTANA M A A, SANTORS F S N D, SOUSA V C,et al. Variability sources of DC voltage-current measurements in the study of TiO2-based varistors[J]. Measurement, 2008, 41(10):1105-1112.
【3】FU Q, CHEN T, YE X,et al. ZnO varistor ceramics prepared by the reduction-reoxidation method[J]. Journal of the European Ceramic Society, 2015, 35(11):3025-3031.
【4】海参威, 李文戈, 尧巍华,等. 表面活性剂SPAN80对水热法制备SrTiO3粉体物相、形貌与极性的影响[J]. 机械工程材料, 2014, 38(12):65-68.
【5】WANG N Z, LI J Y, NING J,et al. Effect of Mn, Si on varistor-dielectric characteristics of Nb-doped SrTiO3 ceramics[J]. Applied Mechanics & Materials, 2012, 239/240:1604-1608.
【6】ZOU M, WANG Y, CHEN Y Y,et al. Influences of donor additives on properties of TiO2-based varistor[J]. Advanced Materials Research, 2010, 105/106:320-323.
【7】KANG K Y, GAN G Y, YAN J K,et al. Effect of Ge-GeO2 Co-doping on non-ohmic behaviour of TiO2-V2O5-Y2O3 varistor ceramics[J]. Journal of Semiconductors, 2015, 36(7):073005.
【8】SOUSA V C, OLIVERIRA M M, ORLANDI M O,et al. Microstructure and electrical properties of (Ta, Co, Pr) doped TiO2 based electroceramics[J]. Journal of Materials Science Materials in Electronics, 2010, 21(3):246-251.
【9】梁忠. V5+、Y3+掺杂TiO2压敏陶瓷的制备及性能研究[D]. 昆明:昆明理工大学, 2014.
【10】WANG T G, QIN Q, ZHANG W J. Effect of TiO2 nano powder on the microstructure and electrical properties of TiO2 capacitor-varistor ceramics[J]. Advanced Materials Research, 2011, 341/342:94-97.
【11】LIN C, FAN Z W, XU Z,et al. Influence of different nano titania on microstructure and electrical properties of low voltage zinc oxide varistors[J].Journal of Electroceramics,2008, 21:423-426.
【12】BADEV A, MARINEL S, HEUGUET R, et al. Sintering behavior and non-linear properties of ZnO varistors processed in microwave electric and magnetic fields at 2.45 GHz[J]. Acta Materialia, 2013, 61(20):7849-7858.
【13】ZHAO J, WANG B, LU K. Influence of Ta2O5 doping and microwave sintering on TiO2-based varistor properties[J]. Ceramics International, 2014, 40(9):14229-14234.
【14】KHARCHOUCHE F, SAVARY E, THUAULT A,et al. Effects of microwave sintering on intrinsic defects concentrations in ZnO-based varistors[J]. Ceramics International, 2014, 40(8):13697-13701.
【15】CONG L, BO W, ZHENG X,et al. Densification and electrical properties of zinc oxide varistors microwave-sintered under different oxygen partial pressures[J]. Journal of Electronic Materials, 2012, 41(11):3119-3124.
【16】LIN C. Densification and grain growth of microwave sintered ZnO varistors[J]. Journal of Inorganic Materials, 2007, 22(5):917-921.
【17】孙质彬, 王昕, 尹衍升,等. 叠层方式烧结对TiO2环形压敏电阻电性能的影响[J]. 机械工程材料, 2013, 37(2):86-89.
【18】NAGAOKA K, JENTYS A, LERCHER J A. Methane autothermal reforming with and without ethane over mono- and bimetal catalysts prepared from hydrotalcite precursors[J]. Journal of Catalysis, 2005, 229(1):185-196.
【19】严继康, 甘国友, 陈海芳,等. 烧结温度对TiO2压敏陶瓷结构和性能的影响[J]. 压电与声光, 2008, 37(3):332-334.
【20】WANG T G, QIN Q, ZHANG W J. Effect of temperature on microstructure and electrical properties of (Y, Ta)-doped TiO2 capacitor-varistor ceramics[J].Advanced Materials Research,2011,214:173-177.
【21】CHEN Y Y, ZOU M, WANG Y,et al. Influences of sintering temperature on microstructure and electrical properties of TiO2 varistor ceramics[J].Advanced Materials Research,2010,105/106:317-319.
【22】MENG F M, AUN Z Q. Influence of soaking time on semi-conductivity and nonlinear electrical properties of TiO2-based varistor ceramics[J]. Journal of Chongqing University(English Edition), 2008,7(4):297-301.
【23】王晓青. TiO2基低压压敏陶瓷材料的制备与性能研究[D]. 广州:华南理工大学, 2012.
【24】FOLLADOR N R, SOUZA E, ANDRADE A,et al. Influence of Nb2O5 on the varistor behavior of TiO2-Cr2O3 system[J]. Journal of Materials Science Materials in Electronics, 2013, 24(3):938-944.
【25】SOUSA V C D, OLICEIRA M M, ORLANDI M,et al. (Ta, Cr)-doped TiO2 electroceramic systems[J]. Journal of Materials Science Materials in Electronics, 2006, 17(1):79-84.
【26】SOUSA V C, OLICEIRA M M, ORLANDI M O,et al. Microstructure and electrical properties of (Ta, Co, Pr)-doped TiO2 based electroceramics[J]. Journal of Materials Science Materials in Electronics, 2010, 21(3):246-251.
【27】LUO S, TANG Z, LI J, et al. Effect of Ta2O5 in (Ca, Si, Ta)-doped TiO2ceramic varistors[J]. Ceramics International, 2008, 34(5):1345-1347.
【28】GONG Y, CHU R, XU Z,et al. Electrical properties of Ta2O5-doped TiO2 varistor ceramics sintered at low-temperature[J]. Ceramics International, 2015, 41(7):9183-9187.
【29】SHANNON R D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides[J]. Acta Crystallographica, 1976, 32(5):751-767.
【30】朱道云, 周方桥, 丁志文,等. Nb2O5掺杂及TiO2压敏陶瓷埋烧工艺的研究[J]. 华中科技大学学报(自然科学版), 2004(2):54-57.
【31】孟凡明, 傅刚, 胡素梅,等. Ta2O5与Nb2O5对TiO2基压敏陶瓷电性能的影响[J].硅酸盐学报, 2004(12):1496-1499.
【32】DELBRVCKE T, SCHMIDT I, CAVA S,et al. Electrical properties of a TiO2-SrO varistor system[J]. Advanced Materials Research, 2014, 975:168-172.
【33】WANG Q, LIAN G, DCIKEY E C. Grain boundary segregation in yttrium-doped polycrystalline TiO2[J]. Acta Materialia, 2004, 52(4):809-820.
【34】YAN J, GAN G, DU J,et al. Second phases of (La,Nb)-Codoped TiO2 varistor ceramic[C]//Journal of Physics Conference Series Journal of Physics Conference Series.[S.l.]:[s.n.], 2009.
【35】BOMIO M R D, SOUSA V C, LEITO E R,et al. Nonlinear behavior of TiO2·Ta2O5·MnO2 material doped with BaO and Bi2O3[J]. Materials Chemistry & Physics, 2004, 85(1):96-103.
【36】李莉, 屈晓田. Bi2O3对TiO2系压敏陶瓷性能的影响[J]. 电子元件与材料, 2007(3):49-51.
【37】PENG Z J, RUICHAO G, FENG J,et al. Microstructure and nonohmic properties of SnO2-Ta2O5-TiO2 varistor system doped with CuO[J]. International Journal of Modern Physics B, 2014, 28(15):817-824.
【2】SANTANA M A A, SANTORS F S N D, SOUSA V C,et al. Variability sources of DC voltage-current measurements in the study of TiO2-based varistors[J]. Measurement, 2008, 41(10):1105-1112.
【3】FU Q, CHEN T, YE X,et al. ZnO varistor ceramics prepared by the reduction-reoxidation method[J]. Journal of the European Ceramic Society, 2015, 35(11):3025-3031.
【4】海参威, 李文戈, 尧巍华,等. 表面活性剂SPAN80对水热法制备SrTiO3粉体物相、形貌与极性的影响[J]. 机械工程材料, 2014, 38(12):65-68.
【5】WANG N Z, LI J Y, NING J,et al. Effect of Mn, Si on varistor-dielectric characteristics of Nb-doped SrTiO3 ceramics[J]. Applied Mechanics & Materials, 2012, 239/240:1604-1608.
【6】ZOU M, WANG Y, CHEN Y Y,et al. Influences of donor additives on properties of TiO2-based varistor[J]. Advanced Materials Research, 2010, 105/106:320-323.
【7】KANG K Y, GAN G Y, YAN J K,et al. Effect of Ge-GeO2 Co-doping on non-ohmic behaviour of TiO2-V2O5-Y2O3 varistor ceramics[J]. Journal of Semiconductors, 2015, 36(7):073005.
【8】SOUSA V C, OLIVERIRA M M, ORLANDI M O,et al. Microstructure and electrical properties of (Ta, Co, Pr) doped TiO2 based electroceramics[J]. Journal of Materials Science Materials in Electronics, 2010, 21(3):246-251.
【9】梁忠. V5+、Y3+掺杂TiO2压敏陶瓷的制备及性能研究[D]. 昆明:昆明理工大学, 2014.
【10】WANG T G, QIN Q, ZHANG W J. Effect of TiO2 nano powder on the microstructure and electrical properties of TiO2 capacitor-varistor ceramics[J]. Advanced Materials Research, 2011, 341/342:94-97.
【11】LIN C, FAN Z W, XU Z,et al. Influence of different nano titania on microstructure and electrical properties of low voltage zinc oxide varistors[J].Journal of Electroceramics,2008, 21:423-426.
【12】BADEV A, MARINEL S, HEUGUET R, et al. Sintering behavior and non-linear properties of ZnO varistors processed in microwave electric and magnetic fields at 2.45 GHz[J]. Acta Materialia, 2013, 61(20):7849-7858.
【13】ZHAO J, WANG B, LU K. Influence of Ta2O5 doping and microwave sintering on TiO2-based varistor properties[J]. Ceramics International, 2014, 40(9):14229-14234.
【14】KHARCHOUCHE F, SAVARY E, THUAULT A,et al. Effects of microwave sintering on intrinsic defects concentrations in ZnO-based varistors[J]. Ceramics International, 2014, 40(8):13697-13701.
【15】CONG L, BO W, ZHENG X,et al. Densification and electrical properties of zinc oxide varistors microwave-sintered under different oxygen partial pressures[J]. Journal of Electronic Materials, 2012, 41(11):3119-3124.
【16】LIN C. Densification and grain growth of microwave sintered ZnO varistors[J]. Journal of Inorganic Materials, 2007, 22(5):917-921.
【17】孙质彬, 王昕, 尹衍升,等. 叠层方式烧结对TiO2环形压敏电阻电性能的影响[J]. 机械工程材料, 2013, 37(2):86-89.
【18】NAGAOKA K, JENTYS A, LERCHER J A. Methane autothermal reforming with and without ethane over mono- and bimetal catalysts prepared from hydrotalcite precursors[J]. Journal of Catalysis, 2005, 229(1):185-196.
【19】严继康, 甘国友, 陈海芳,等. 烧结温度对TiO2压敏陶瓷结构和性能的影响[J]. 压电与声光, 2008, 37(3):332-334.
【20】WANG T G, QIN Q, ZHANG W J. Effect of temperature on microstructure and electrical properties of (Y, Ta)-doped TiO2 capacitor-varistor ceramics[J].Advanced Materials Research,2011,214:173-177.
【21】CHEN Y Y, ZOU M, WANG Y,et al. Influences of sintering temperature on microstructure and electrical properties of TiO2 varistor ceramics[J].Advanced Materials Research,2010,105/106:317-319.
【22】MENG F M, AUN Z Q. Influence of soaking time on semi-conductivity and nonlinear electrical properties of TiO2-based varistor ceramics[J]. Journal of Chongqing University(English Edition), 2008,7(4):297-301.
【23】王晓青. TiO2基低压压敏陶瓷材料的制备与性能研究[D]. 广州:华南理工大学, 2012.
【24】FOLLADOR N R, SOUZA E, ANDRADE A,et al. Influence of Nb2O5 on the varistor behavior of TiO2-Cr2O3 system[J]. Journal of Materials Science Materials in Electronics, 2013, 24(3):938-944.
【25】SOUSA V C D, OLICEIRA M M, ORLANDI M,et al. (Ta, Cr)-doped TiO2 electroceramic systems[J]. Journal of Materials Science Materials in Electronics, 2006, 17(1):79-84.
【26】SOUSA V C, OLICEIRA M M, ORLANDI M O,et al. Microstructure and electrical properties of (Ta, Co, Pr)-doped TiO2 based electroceramics[J]. Journal of Materials Science Materials in Electronics, 2010, 21(3):246-251.
【27】LUO S, TANG Z, LI J, et al. Effect of Ta2O5 in (Ca, Si, Ta)-doped TiO2ceramic varistors[J]. Ceramics International, 2008, 34(5):1345-1347.
【28】GONG Y, CHU R, XU Z,et al. Electrical properties of Ta2O5-doped TiO2 varistor ceramics sintered at low-temperature[J]. Ceramics International, 2015, 41(7):9183-9187.
【29】SHANNON R D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides[J]. Acta Crystallographica, 1976, 32(5):751-767.
【30】朱道云, 周方桥, 丁志文,等. Nb2O5掺杂及TiO2压敏陶瓷埋烧工艺的研究[J]. 华中科技大学学报(自然科学版), 2004(2):54-57.
【31】孟凡明, 傅刚, 胡素梅,等. Ta2O5与Nb2O5对TiO2基压敏陶瓷电性能的影响[J].硅酸盐学报, 2004(12):1496-1499.
【32】DELBRVCKE T, SCHMIDT I, CAVA S,et al. Electrical properties of a TiO2-SrO varistor system[J]. Advanced Materials Research, 2014, 975:168-172.
【33】WANG Q, LIAN G, DCIKEY E C. Grain boundary segregation in yttrium-doped polycrystalline TiO2[J]. Acta Materialia, 2004, 52(4):809-820.
【34】YAN J, GAN G, DU J,et al. Second phases of (La,Nb)-Codoped TiO2 varistor ceramic[C]//Journal of Physics Conference Series Journal of Physics Conference Series.[S.l.]:[s.n.], 2009.
【35】BOMIO M R D, SOUSA V C, LEITO E R,et al. Nonlinear behavior of TiO2·Ta2O5·MnO2 material doped with BaO and Bi2O3[J]. Materials Chemistry & Physics, 2004, 85(1):96-103.
【36】李莉, 屈晓田. Bi2O3对TiO2系压敏陶瓷性能的影响[J]. 电子元件与材料, 2007(3):49-51.
【37】PENG Z J, RUICHAO G, FENG J,et al. Microstructure and nonohmic properties of SnO2-Ta2O5-TiO2 varistor system doped with CuO[J]. International Journal of Modern Physics B, 2014, 28(15):817-824.
相关信息
