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基于植物模板法制备高性能石墨烯/氧化锰复合材料及其电化学性能
          
Preparation of High-Performance Graphene/MnO2 Composite by Plant Biotemplate Method and Its Electrochemical Property

摘    要
以植物膜作为碳源和模板,通过浸渍氯化锰溶液并经两次煅烧合成了石墨烯/氧化锰复合材料,分析了该复合材料的微观形貌、物相组成以及表面性能;将该复合材料制成电极,通过循环伏安和恒流充放电方法测试了其电化学性能。结果表明:石墨烯/氧化锰复合材料中不存在氧化石墨烯,其石墨烯为褶皱状片层结构,厚度约1.449 nm,其上负载着大量粒径为10~40 nm的氧化锰颗粒;该复合材料的BET比表面积约为202.5 m2·g-1,孔径分布于5~30 nm;该复合材料的电化学反应可逆性优良,比电容为245 F·g-1,远高于市购碳粉(25~26 F·g-1)和植物膜煅烧制备石墨烯(45~50 F·g-1)的。
标    签 石墨烯/氧化锰复合材料   植物模板   表面性能   比电容   graphene/MnO2 composite   plant biotemplate   surface property   specific capacitance  
 
Abstract
A graphene/MnO2 composite was prepared after dipping a plant membrane, which was used as both a carbon source and a template, into the manganese chloride solution and then calcining twice. The micromorphology, phase composition and surface property of the composite were analyzed. Then the composite was pressed to be an electrode and the electrochemical property was measured by cyclic voltammetry and constant current charge-discharge tests. The results show that there was no graphene oxide in the graphene/MnO2 composite. The graphene showed a lamellar structure with wrinkles on it, whose thickness was 1.449 nm; there were lots of MnO2 particles with the size of 10-40 nm and loaded on the graphene. The BET specific surface area of the composite was 202.5 m2·g-1 and the pore size was 5-30 nm. The composite had an excellent electrochemical reversibility with the specific capacitance of 245 F·g-1, which was much higher than that of commercial carbon powder (25-26 F·g-1) and synthesized graphene by the plant membrane calcination (45-50 F·g-1).

中图分类号 TB33   DOI 10.11973/jxgccl201701007

 
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所属栏目 试验研究

基金项目 江苏省高校自然科学研究重大项目(14KJA430004)

收稿日期 2015/5/22

修改稿日期 2016/10/3

网络出版日期

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备注何凤娟(1989-),女,江苏南京人,硕士研究生。

引用该论文: HE Feng-juan,QIAN Jun-chao,LIU Cheng-bao,CHEN Zhi-gang,LI Ping. Preparation of High-Performance Graphene/MnO2 Composite by Plant Biotemplate Method and Its Electrochemical Property[J]. Materials for mechancial engineering, 2017, 41(1): 34~37
何凤娟,钱君超,刘成宝,陈志刚,李萍. 基于植物模板法制备高性能石墨烯/氧化锰复合材料及其电化学性能[J]. 机械工程材料, 2017, 41(1): 34~37


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