Preparation of High-Performance Graphene/MnO2 Composite by Plant Biotemplate Method and Its Electrochemical Property
摘 要
以植物膜作为碳源和模板,通过浸渍氯化锰溶液并经两次煅烧合成了石墨烯/氧化锰复合材料,分析了该复合材料的微观形貌、物相组成以及表面性能;将该复合材料制成电极,通过循环伏安和恒流充放电方法测试了其电化学性能。结果表明:石墨烯/氧化锰复合材料中不存在氧化石墨烯,其石墨烯为褶皱状片层结构,厚度约1.449 nm,其上负载着大量粒径为10~40 nm的氧化锰颗粒;该复合材料的BET比表面积约为202.5 m2·g-1,孔径分布于5~30 nm;该复合材料的电化学反应可逆性优良,比电容为245 F·g-1,远高于市购碳粉(25~26 F·g-1)和植物膜煅烧制备石墨烯(45~50 F·g-1)的。
Abstract
A graphene/MnO2 composite was prepared after dipping a plant membrane, which was used as both a carbon source and a template, into the manganese chloride solution and then calcining twice. The micromorphology, phase composition and surface property of the composite were analyzed. Then the composite was pressed to be an electrode and the electrochemical property was measured by cyclic voltammetry and constant current charge-discharge tests. The results show that there was no graphene oxide in the graphene/MnO2 composite. The graphene showed a lamellar structure with wrinkles on it, whose thickness was 1.449 nm; there were lots of MnO2 particles with the size of 10-40 nm and loaded on the graphene. The BET specific surface area of the composite was 202.5 m2·g-1 and the pore size was 5-30 nm. The composite had an excellent electrochemical reversibility with the specific capacitance of 245 F·g-1, which was much higher than that of commercial carbon powder (25-26 F·g-1) and synthesized graphene by the plant membrane calcination (45-50 F·g-1).
中图分类号 TB33 DOI 10.11973/jxgccl201701007
所属栏目 试验研究
基金项目 江苏省高校自然科学研究重大项目(14KJA430004)
收稿日期 2015/5/22
修改稿日期 2016/10/3
网络出版日期
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备注何凤娟(1989-),女,江苏南京人,硕士研究生。
引用该论文: HE Feng-juan,QIAN Jun-chao,LIU Cheng-bao,CHEN Zhi-gang,LI Ping. Preparation of High-Performance Graphene/MnO2 Composite by Plant Biotemplate Method and Its Electrochemical Property[J]. Materials for mechancial engineering, 2017, 41(1): 34~37
何凤娟,钱君超,刘成宝,陈志刚,李萍. 基于植物模板法制备高性能石墨烯/氧化锰复合材料及其电化学性能[J]. 机械工程材料, 2017, 41(1): 34~37
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【3】付猛,岳艳娟,祝雅娟,等.水热法制备石墨烯及其表征[J].机械工程材料,2013,37(6):84-88.
【4】ZHANG F, ZHANG T, YANG X, et al. A high-performance supercapacitor-battery hybrid energy storage device based on graphene-enhanced electrode materials with ultrahigh energy density[J]. Energy & Environmental Science, 2013, 6(5):1623-1632.
【5】YU D, YAO J, QIU L, et al. In situ growth of Co3O4 nanoparticles on α-MnO2 nanotubes:a new hybrid for high-performance supercapacitors[J]. Journal of Materials Chemistry A, 2014, 2(22):8465-8471.
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【7】付猛,张婷婷,龚利云,等.化学分散法制备少数层石墨烯及其表征[J].机械工程材料,2011,35(12):89-92.
【8】HE Y, CHEN W, LI X, et al. Freestanding three-dimensional graphene/MnO2 composite networks as ultralight and flexible supercapacitor electrodes[J]. ACS Nano, 2012, 7(1):174-182.
【9】DING Y S, SHEN X F, GOMEZ S, et al. Hydrothermal growth of manganese dioxide into three-dimensional hierarchical nanoarchitectures[J]. Advanced Functional Materials, 2006, 16(4):549-555.
【10】LEE H, KANG J, CHO M S, et al. MnO2/graphene composite electrodes for supercapacitors:the effect of graphene intercalation on capacitance[J]. Journal of Materials Chemistry, 2011, 21(45):18215-18219.
【11】WEI C, YU L, CUI C, et al. Ultrathin MnO2 nanoflakes as efficient catalysts for oxygen reduction reaction[J]. Chemical Communications, 2014, 50(58):7885-7888.
【12】LEI Z, ZHANG J, ZHAO X S. Ultrathin MnO2 nanofibers grown on graphitic carbon spheres as high-performance asymmetric supercapacitor electrodes[J]. Journal of Materials Chemistry, 2012, 22(1):153-160.
【13】LI N, CAO M, HU C. Review on the latest design of graphene-based inorganic materials[J]. Nanoscale, 2012, 4(20):6205-6218.
【14】ALLEN M J, TUNG V C, KANER R B. Honeycomb carbon:A review of graphene[J]. Chemical Reviews, 2009, 110(1):132-145.
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