镀锌钢板硅烷钝化膜的制备及其电化学性能
Preparation and Electrochemical Behaviour of Silane Films on Galvanised Steel Substrate
摘 要
在镀锌钢板基体上制备了硅烷膜和CeO2纳米颗粒改性γ-（甲基丙烯酰氧）丙基三甲氧基硅烷膜。采用电化学阻抗谱（EIS）技术研究了水解液中甲醇和CeO2纳米颗粒加入量对钝化膜电化学性能的影响；采用扫描电子显微镜（SEM）观察n种硅烷膜的微观形貌和结构。结果表明：甲醇含量对硅烷水解有重要影响，当甲醇含量为10%（质量分数）时，制得硅烷膜的阻抗最大，为1×103.7 Ω·cm2，单纯纳米颗粒CeO2的添加对钝化膜的耐蚀性影响不大。
电化学阻抗谱
耐蚀性
钝化膜
silane
EIS
corrosion resistance
passive film
Abstract
Silane film and γ-methacryl oxypropyltrimethoxy silane film modified by CeO2 nanoparticles were prepared on the surface of galvanized steel. EIS was used to investigate the effect of the content of methanol and CeO2 nanoparticle in hydrolysate on the electrochemical performance of silence films. SEM was used to observe the micro-morphology and structure of several silane films. The results showed that the film the concentration of methanols played an important role in silane hydrolyzation, and the Rct of silane film reached 1×103.7 Ω·cm2 when 10% methanols was added in the hydrolysate. The addition of CeO2 nanoparticles had no remarkable effect on the corrosion resistance of silane films.
中图分类号 TG174.4 DOI 10.11973/fsyfh-201701004
所属栏目 试验研究
基金项目 南通市产学研协同创新计划项目（BC2014010）
收稿日期 2015/9/10
修改稿日期
网络出版日期
作者单位点击查看
引用该论文: ZHAO Qi-liang,ZHANG Jun-liang,ZHONG Qing-dong,GUO Wei,SHI Xi. Preparation and Electrochemical Behaviour of Silane Films on Galvanised Steel Substrate[J]. Corrosion & Protection, 2017, 38(1): 17
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】易德莲,王静,李宇鹏,等. 镀锌板的复合钝化[J]. 腐蚀与防护,2010,31(2):142-145.
【2】KASTEN L S,GRANT J T,GREBASCH N,et al. An XPS study of cerium dopants in sol-gel coatings for aluminum 2024-T3[J]. Surface and Coatings Technology,2001,140(1):11-15.
【3】PHANI A R,GAMMEL F J,HACK T,et al. Enhanced corrosioon resistance by sol-gel-based ZrO2-CeO2 coatings on magnesium alloys[J]. Mat Corros,2005,56(2):77-82.
【4】SHCHUKIN D G,ZHELUDKEVICH M,YASAKAU K,et al. Layer-by-layer assembled nanocontainers for self-healing corrosion protection[J]. Advanced Materials,2006,18(3):1672-1678.
【5】CIESLIK M,ENGVALL K,PAN J S,et al. Silane-parylene coating for improving corrosion resistance of stainless steel 316L implant material[J]. Corrosion Science,2011,53(1):296-301.
【6】SIMOES A M P,CARBONARI R O,DI SARLI A R,et al. An environmentally acceptable primer for galvanized steel:formulation and evaluation by SVET[J]. Corrosion Science,2011,53(1):464-472.
【7】MEAGHER K,PRESCOTT T L,KELLY T L,et al. High performance non-chrome pretreatment for can-end stock aluminum:CN-US6881279[P]. 2005-03-18.
【8】PALANIVEL V,ZHU D Q,VAN OOIJ W J. Nanoparticle-filled silane films as chromate replacements for aluminum alloys[J]. Progress in Orgaqnic Coatings,2003,47(3):384-392.
【9】ZHU D Q,VAN OOIJ W J. Enhanced corrosion resistance of AA2024-T3 and hot-dip galvanized steel using a mixture of bis (triethoxysilylpropyl) tetrasul-fide and propylamine[J]. Electrochimica Acta,2009,49(7):1113-1125.
【10】MONTEMOR M F,CABRAL A M,ZHELUDKEVICH M L,et al. The corrosion resistance of hot dip galvanized steel pretreated with Bis-functional silanes modified with microsilica[J]. Surface and Coatings Technology,2006,200(9):2875-2885.
【11】MONTEMOR M F,FERREIRA M G S. Cerium salt activated nanoparticles as fillers for silane films:evaluation of the corrosion inhibition performance on galvanised steel substrates[J]. Electrochimica Acta,2007,52(24):6976-6987.
【12】MONTEMOR M F,FERREIRA M G S. Analytical characterization of silane films modified with cerium activated nanoparticles and its relation with the corrosion protection of galvanised steel substrates[J]. Progress in Organic Coatings,2008,63(3):330-337.
【13】徐丽萍,胡丰,杨兴亮,等. 无机-有机硅烷复合钝化膜的性能[J]. 材料保护,2011,44(12):8-11.
【14】王雷,刘长升. 镀锌层无机物与有机物复合无铬钝化研究进展[J]. 电镀与精饰,2011,33(3):22-26.
【15】韩利华,马庆国,冯晓健,等. 镀锌层表面KH-560硅烷膜耐蚀性能研究[J]. 材料工程,2010(6):45-49.
【16】吴海江,杨飞英. 热镀锌钢表面硅烷膜的腐蚀电化学性能[J]. 中国表面工程,2009,22(5):66-69.
【2】KASTEN L S,GRANT J T,GREBASCH N,et al. An XPS study of cerium dopants in sol-gel coatings for aluminum 2024-T3[J]. Surface and Coatings Technology,2001,140(1):11-15.
【3】PHANI A R,GAMMEL F J,HACK T,et al. Enhanced corrosioon resistance by sol-gel-based ZrO2-CeO2 coatings on magnesium alloys[J]. Mat Corros,2005,56(2):77-82.
【4】SHCHUKIN D G,ZHELUDKEVICH M,YASAKAU K,et al. Layer-by-layer assembled nanocontainers for self-healing corrosion protection[J]. Advanced Materials,2006,18(3):1672-1678.
【5】CIESLIK M,ENGVALL K,PAN J S,et al. Silane-parylene coating for improving corrosion resistance of stainless steel 316L implant material[J]. Corrosion Science,2011,53(1):296-301.
【6】SIMOES A M P,CARBONARI R O,DI SARLI A R,et al. An environmentally acceptable primer for galvanized steel:formulation and evaluation by SVET[J]. Corrosion Science,2011,53(1):464-472.
【7】MEAGHER K,PRESCOTT T L,KELLY T L,et al. High performance non-chrome pretreatment for can-end stock aluminum:CN-US6881279[P]. 2005-03-18.
【8】PALANIVEL V,ZHU D Q,VAN OOIJ W J. Nanoparticle-filled silane films as chromate replacements for aluminum alloys[J]. Progress in Orgaqnic Coatings,2003,47(3):384-392.
【9】ZHU D Q,VAN OOIJ W J. Enhanced corrosion resistance of AA2024-T3 and hot-dip galvanized steel using a mixture of bis (triethoxysilylpropyl) tetrasul-fide and propylamine[J]. Electrochimica Acta,2009,49(7):1113-1125.
【10】MONTEMOR M F,CABRAL A M,ZHELUDKEVICH M L,et al. The corrosion resistance of hot dip galvanized steel pretreated with Bis-functional silanes modified with microsilica[J]. Surface and Coatings Technology,2006,200(9):2875-2885.
【11】MONTEMOR M F,FERREIRA M G S. Cerium salt activated nanoparticles as fillers for silane films:evaluation of the corrosion inhibition performance on galvanised steel substrates[J]. Electrochimica Acta,2007,52(24):6976-6987.
【12】MONTEMOR M F,FERREIRA M G S. Analytical characterization of silane films modified with cerium activated nanoparticles and its relation with the corrosion protection of galvanised steel substrates[J]. Progress in Organic Coatings,2008,63(3):330-337.
【13】徐丽萍,胡丰,杨兴亮,等. 无机-有机硅烷复合钝化膜的性能[J]. 材料保护,2011,44(12):8-11.
【14】王雷,刘长升. 镀锌层无机物与有机物复合无铬钝化研究进展[J]. 电镀与精饰,2011,33(3):22-26.
【15】韩利华,马庆国,冯晓健,等. 镀锌层表面KH-560硅烷膜耐蚀性能研究[J]. 材料工程,2010(6):45-49.
【16】吴海江,杨飞英. 热镀锌钢表面硅烷膜的腐蚀电化学性能[J]. 中国表面工程,2009,22(5):66-69.
相关信息
