C/C复合材料高温抗烧蚀涂层的研究进展
Research Progress of Anti-ablation Coatings for Carbon/Carbon Composites at High Temperature
摘 要
C/C复合材料在高温燃气高速冲刷环境中的严重氧化烧蚀限制了其在航空航天等领域的广泛应用，采用抗烧蚀涂层技术是目前提高该材料高温抗烧蚀性能的有效方法。综述了近年来国内外C/C复合材料高温抗烧蚀涂层在玻璃涂层、金属涂层、陶瓷涂层等体系方面的研究进展，总结并评价了C/C复合材料抗烧蚀涂层的抗烧蚀性能测试技术及其研究成果，提出了C/C复合材料高温抗烧蚀涂层在未来研究中潜在的重点发展方向。
抗烧蚀性能
涂层
carbon/carbon composite
anti-ablation
coating
Abstract
The serious ablation of carbon/carbon (C/C) composites restricts their applications in the field of aeronautics and aerospace in the ultra-high temperature plume with high-speed gas flow. The anti-ablation coating is one of the most effective methods for the improvement of ablation resistance of C/C composites. The recent development of several oxidation resistant coatings including glass, metal and ceramic coatings for C/C composites is reviewed in this paper. Besides, the current method and research achievement of ablation simulation test are introduced. The potential important development of the ablation resistant coatings for C/C composites in the future research is also proposed.
中图分类号 TB332 DOI 10.11973/fsyfh-201703001
所属栏目 专论
基金项目 广东省自然基金（2016A030312015）；广东省科技项目（2013B050800031；2013B010102023；2014B050502008）
收稿日期 2016/4/19
修改稿日期
网络出版日期
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引用该论文: HAN Wei,LIU Min,DENG Chun-ming,MAO Jie,ZENG De-chang. Research Progress of Anti-ablation Coatings for Carbon/Carbon Composites at High Temperature[J]. Corrosion & Protection, 2017, 38(3): 163
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参考文献
【1】李贺军. 炭/炭复合材料[J]. 新型炭材料,2001,16(2):79-80.
【2】WESTWOOD M E,WEBSTER J D,DAY R J,et al. Oxidation protection for carbon fiber composites[J]. J Mater Sci,1996,31:1389-1394.
【3】任富建,刘红娟,沈毅. C/C复合材料高温抗氧化性的研究进展[J]. 中国陶瓷工业,2007,14(5):28-31.
【4】付前刚,张佳平,李贺军. 抗烧蚀C/C复合材料研究进展[J]. 新型炭材料,2015,30(2):97-105.
【5】BUCKLEY J D,DDIE D D. Carbon-carbon material and composites[M]. New Jersey:Noyes Publications,1993.
【6】BUCHANAN F J,LITTLE J A. Glass sealants for carbon-carbon composites[J]. Journal of material science,1993,28:2324-2330.
【7】BUCHANAN F J,LITTLE J A. Particulate-containing glass sealants for carbon-carbon composites[J]. Carbon,1995,33(4):491-498.
【8】DELAVAL R,PALAVIT G,REY J,et al. Method for protecting porous carbon-containing material from oxidation,and material obtained thereby:5714244[P],1998-02-03.
【9】SMEACETTO F,FERRARIS M,SALVO M. Multilayer coating with self-sealing properties for carbon-carbon composites[J]. Carbon,2003,41(11):2105-2111.
【10】CHEN Z F,WU W P,CHENG H,et al. Microstructure and evolution of iridium coating on the C/C composites ablated by oxyacetylene torch[J]. Acta Astronautica,2010(66):682-687.
【11】TERENTIEVA V S,BOGACHKOVA O P,GORIATCHEVA E V. Method for protecting products made of a refractory material against oxidation,and resulting producted products:5677060[P],1997-10-14.
【12】ZHANG Y L,HU Z X,LI H J,et al. Ablation resistance of ZrB2-SiC coating prepared by supersonic atmosphere plasma spraying for SiC-coated carbon/carbon composites[J]. Ceramics International,2014,40:14749-14755.
【13】WANG Y L,XIONG X,ZHAO X J. Structural evolution and ablation mechanism of a hafnium carbide coating on a C/C composite in an oxyacetylene torch environment[J]. Corrosion Science,2012,61:156-161.
【14】WANG Y J,LI H J,FU Q G,et al. Ablation behaviour of a TaC coating on SiC coated C/C composites at different temperatures[J]. Ceramics International,2013,39:359-365.
【15】ZHANG J P,FU Q G,LI H J,et al. Ablation behavior of Y2SiO5/SiC coating for C/C composites under oxyacetylene torch[J]. Corrosion Science,2014,87(7):472-478.
【16】LI Z Q,LI H J,LI W,et al. Preparation and ablation properties of ZrC-SiC coating for carbon/carbon composites by solid phase infiltration[J]. Applied Surface Science,2011,258:565-571.
【17】FENG T,LI H J,FU Q G,et al. High-temperature erosion resistance and aerodynamic oxidation mechanism of multi-layer MoSi2-CrSi2-Si/SiC coated carbon/carbon composites in a wind tunnel at 1873K[J]. Carbon,2012,50(6):2171-2178.
【18】苏哲安,杨鑫,黄启忠,等. SiC涂层对C/C复合材料高温氧乙炔焰烧蚀性能影响[J]. 中国有色金属学报,2011,21(11):2838-2845.
【19】TANG S F,DENG J Y,WANG S J,et al. Ablation behaviors of ultra-high temperature ceramic composites[J]. Materials Science and Engineering:A,2007,465:1-7.
【20】SUN W,XIONG X,HUANG B Y,et al. ZrC ablation protective coating for carbon/carbon composites[J]. Carbon,2009,47(3):3368-3371.
【21】张勇,周声劢,夏金童. 炭/炭复合材料高温抗氧化研究进展[J]. 炭素技术,2004,23(4):20-25.
【22】WEN B,MA Z,LIU Y B. Supersonic flame ablation resistance of W/ZrC coating deposited on C/SiC composites by atmosphere plasma spraying[J]. Ceramics International,2014,40:11825-11830.
【23】YE Y C,ZHANG H,TONG Y G,et al. HfC-based coating prepared by reactive melt infiltration on C/C composite substrate[J]. Ceramics International,2013,3:1-7.
【24】WUCHINA E,OPEKA M,CAUSEY S,et al. Designing for ultrahigh-temperature applications:the mechanical and thermal properties of HfB2,HfCx,HfNx and αHf(N)[J]. Journal of Materials Science,2004,39(19):5939-5949.
【25】ZHANG Y L,LI H J,QIANG X F,et al. C/SiC/MoSi2-Si multilayer coatings for carbon/carbon composites for protection against oxidation[J]. Corrosion Science,2011,53(11):3840-3844.
【26】符文彬. C/C复合材料表面SiC/MoSi2涂层的制备及其高温抗氧化性能研究[D]. 湖南:中南大学,2015.
【27】毛金元,刘敏,毛杰,等. 等离子喷涂制备ZrB2-MoSi2复合涂层及其抗氧化性能[J]. 无机材料学报,2015,30(3):282-286.
【28】袁海根,曾金芳,杨杰,等. 防热抗烧蚀复合材料研究进展[J]. 化学推进剂与高分子材料,2006,4(1):21-25.
【29】GJB 323A-1996烧蚀材料烧蚀试验方法[S].
【30】高守臻,魏化震,李大勇,等. 烧蚀材料综述[J]. 化工新型材料,2009,37(2):19-21. 试验研究
【31】LI H J,FENG T,FU Q G,et al. Oxidation and erosion resistance of MoSi2-CrSi2-Si/SiC coated C/C composites in static and aerodynamic oxidation environment[J]. Carbon,2010,48(5):1636-1642.
【32】姚栋嘉,李贺军,张守阳,等. C/C复合材料SiC涂层强冲蚀环境的烧蚀性能研究[J]. 中国材料进展,2015,34(7/8):610-614.
【33】查柏林,黄定园,乔素磊,等. C/C复合材料烧蚀试验及烧蚀机理研究[J]. 固体火箭技术,2013,36(5):692-696.
【2】WESTWOOD M E,WEBSTER J D,DAY R J,et al. Oxidation protection for carbon fiber composites[J]. J Mater Sci,1996,31:1389-1394.
【3】任富建,刘红娟,沈毅. C/C复合材料高温抗氧化性的研究进展[J]. 中国陶瓷工业,2007,14(5):28-31.
【4】付前刚,张佳平,李贺军. 抗烧蚀C/C复合材料研究进展[J]. 新型炭材料,2015,30(2):97-105.
【5】BUCKLEY J D,DDIE D D. Carbon-carbon material and composites[M]. New Jersey:Noyes Publications,1993.
【6】BUCHANAN F J,LITTLE J A. Glass sealants for carbon-carbon composites[J]. Journal of material science,1993,28:2324-2330.
【7】BUCHANAN F J,LITTLE J A. Particulate-containing glass sealants for carbon-carbon composites[J]. Carbon,1995,33(4):491-498.
【8】DELAVAL R,PALAVIT G,REY J,et al. Method for protecting porous carbon-containing material from oxidation,and material obtained thereby:5714244[P],1998-02-03.
【9】SMEACETTO F,FERRARIS M,SALVO M. Multilayer coating with self-sealing properties for carbon-carbon composites[J]. Carbon,2003,41(11):2105-2111.
【10】CHEN Z F,WU W P,CHENG H,et al. Microstructure and evolution of iridium coating on the C/C composites ablated by oxyacetylene torch[J]. Acta Astronautica,2010(66):682-687.
【11】TERENTIEVA V S,BOGACHKOVA O P,GORIATCHEVA E V. Method for protecting products made of a refractory material against oxidation,and resulting producted products:5677060[P],1997-10-14.
【12】ZHANG Y L,HU Z X,LI H J,et al. Ablation resistance of ZrB2-SiC coating prepared by supersonic atmosphere plasma spraying for SiC-coated carbon/carbon composites[J]. Ceramics International,2014,40:14749-14755.
【13】WANG Y L,XIONG X,ZHAO X J. Structural evolution and ablation mechanism of a hafnium carbide coating on a C/C composite in an oxyacetylene torch environment[J]. Corrosion Science,2012,61:156-161.
【14】WANG Y J,LI H J,FU Q G,et al. Ablation behaviour of a TaC coating on SiC coated C/C composites at different temperatures[J]. Ceramics International,2013,39:359-365.
【15】ZHANG J P,FU Q G,LI H J,et al. Ablation behavior of Y2SiO5/SiC coating for C/C composites under oxyacetylene torch[J]. Corrosion Science,2014,87(7):472-478.
【16】LI Z Q,LI H J,LI W,et al. Preparation and ablation properties of ZrC-SiC coating for carbon/carbon composites by solid phase infiltration[J]. Applied Surface Science,2011,258:565-571.
【17】FENG T,LI H J,FU Q G,et al. High-temperature erosion resistance and aerodynamic oxidation mechanism of multi-layer MoSi2-CrSi2-Si/SiC coated carbon/carbon composites in a wind tunnel at 1873K[J]. Carbon,2012,50(6):2171-2178.
【18】苏哲安,杨鑫,黄启忠,等. SiC涂层对C/C复合材料高温氧乙炔焰烧蚀性能影响[J]. 中国有色金属学报,2011,21(11):2838-2845.
【19】TANG S F,DENG J Y,WANG S J,et al. Ablation behaviors of ultra-high temperature ceramic composites[J]. Materials Science and Engineering:A,2007,465:1-7.
【20】SUN W,XIONG X,HUANG B Y,et al. ZrC ablation protective coating for carbon/carbon composites[J]. Carbon,2009,47(3):3368-3371.
【21】张勇,周声劢,夏金童. 炭/炭复合材料高温抗氧化研究进展[J]. 炭素技术,2004,23(4):20-25.
【22】WEN B,MA Z,LIU Y B. Supersonic flame ablation resistance of W/ZrC coating deposited on C/SiC composites by atmosphere plasma spraying[J]. Ceramics International,2014,40:11825-11830.
【23】YE Y C,ZHANG H,TONG Y G,et al. HfC-based coating prepared by reactive melt infiltration on C/C composite substrate[J]. Ceramics International,2013,3:1-7.
【24】WUCHINA E,OPEKA M,CAUSEY S,et al. Designing for ultrahigh-temperature applications:the mechanical and thermal properties of HfB2,HfCx,HfNx and αHf(N)[J]. Journal of Materials Science,2004,39(19):5939-5949.
【25】ZHANG Y L,LI H J,QIANG X F,et al. C/SiC/MoSi2-Si multilayer coatings for carbon/carbon composites for protection against oxidation[J]. Corrosion Science,2011,53(11):3840-3844.
【26】符文彬. C/C复合材料表面SiC/MoSi2涂层的制备及其高温抗氧化性能研究[D]. 湖南:中南大学,2015.
【27】毛金元,刘敏,毛杰,等. 等离子喷涂制备ZrB2-MoSi2复合涂层及其抗氧化性能[J]. 无机材料学报,2015,30(3):282-286.
【28】袁海根,曾金芳,杨杰,等. 防热抗烧蚀复合材料研究进展[J]. 化学推进剂与高分子材料,2006,4(1):21-25.
【29】GJB 323A-1996烧蚀材料烧蚀试验方法[S].
【30】高守臻,魏化震,李大勇,等. 烧蚀材料综述[J]. 化工新型材料,2009,37(2):19-21. 试验研究
【31】LI H J,FENG T,FU Q G,et al. Oxidation and erosion resistance of MoSi2-CrSi2-Si/SiC coated C/C composites in static and aerodynamic oxidation environment[J]. Carbon,2010,48(5):1636-1642.
【32】姚栋嘉,李贺军,张守阳,等. C/C复合材料SiC涂层强冲蚀环境的烧蚀性能研究[J]. 中国材料进展,2015,34(7/8):610-614.
【33】查柏林,黄定园,乔素磊,等. C/C复合材料烧蚀试验及烧蚀机理研究[J]. 固体火箭技术,2013,36(5):692-696.
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