Microstructure and High-temperature Corrosion Behavior of Fe-Cr-B-C-Al Coating Prepared by High Velocity Arc Spraying
摘 要
采用高速电弧喷涂技术在20G钢基体上制备了Fe-Cr-B-C-Al涂层。采用光学显微镜、扫描电镜、能谱仪、X射线衍射仪、万能材料试验机以及硬度计研究了涂层的微观组织结构和力学性能;然后在650 ℃条件下进行了涂层的高温腐蚀试验,并与20G钢进行了对比,研究了涂层的耐高温腐蚀机理。结果表明:高速电弧喷涂Fe-Cr-B-C-Al涂层呈典型的层状结构,与基体的结合力较强,涂层内氧化物和孔隙较少;在650 ℃腐蚀100 h后,20G钢的腐蚀增重约为涂层的13倍;在高温腐蚀过程中,涂层表面生成了具有保护作用的氧化膜,提高了涂层的耐高温腐蚀性能。
Abstract
The Fe-Cr-B-C-Al coating was prepared on 20G steel substrate by high velocity arc spraying (HVAS) technology. The microstructure and mechanical properties of the coating were analyzed by optical microscope (OM), scanning election microscope (SEM), energy dispersive spectrometer (EDS), X-ray diffractometer (XRD), universal tensile testing machine and Vickers hardness tester. The high temperature corrosion test was done at 650 ℃ and compared with 20G steel to study the high-temperature corrosion resistance of the coating. The results show that the HVAS Fe-Cr-B-C-Al coating had the typical lamellar structure and combined well with the substrate. There were few oxides and pores in the coating. After corrosion at 650 ℃ for 100 h, the mass gain of the 20G steel was about 13 times of that of the coating. In the process of high-temperature corrosion, the protective oxide film was formed on the surface of the coating, which improved the high-temperature corrosion resistance of the coating.
中图分类号 TG174.44 DOI 10.11973/lhjy-wl201704003
所属栏目 试验与研究
基金项目
收稿日期 2016/12/2
修改稿日期
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联系人作者吴玉萍(wuyphhu@163.com)
备注李柏涛(1991—),男,硕士,主要从事金属涂层制备及其性能研究.
引用该论文: LI Bai-tao,SHI Wei,QIAO Lei,WU Yu-ping. Microstructure and High-temperature Corrosion Behavior of Fe-Cr-B-C-Al Coating Prepared by High Velocity Arc Spraying[J]. Physical Testing and Chemical Analysis part A:Physical Testing, 2017, 53(4): 240~243
李柏涛,师玮,乔磊,吴玉萍. 高速电弧喷涂Fe-Cr-B-C-Al涂层的组织结构及其高温腐蚀行为[J]. 理化检验-物理分册, 2017, 53(4): 240~243
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【2】吴东亮,刘洪洋.电站锅炉产生高温硫腐蚀机理及预防措施[J].华北电力技术,2007(12):52-54.
【3】陈红菊,陈文彤,孙艳华.火电厂锅炉水冷壁热腐蚀机理的研究现状[J].电力建设,2000,21(2):17-20,36.
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【5】WANG B Q,LEE S W. Elevated temperature erosion of several thermal-sprayed coatings under the simulated erosion conditions of in-bed tubes in a fluidized bed combustor[J]. Wear,1997,203:580-587.
【6】高文文,吴玉萍,杜海清,等.纳米Al2O3封孔对电弧喷涂3Cr13涂层耐腐蚀性能的影响[J].理化检验-物理分册,2013,49(12):785-789.
【7】罗来马,罗娟,刘少光,等.高速电弧喷涂FeMnCrAl/Cr3C2涂层的组织及抗高温氧化性能[J].材料热处理学报,2010,31(12):139-142.
【8】田浩亮,魏世丞, 陈永雄,等.高速电弧喷涂FeAlCr涂层的组织与耐磨性研究[J].稀有金属材料与工程,2014,43(1):135-139.
【9】胡军志,陈学荣,马世宁,等.FeCrAl/WC复合涂层650 ℃的热腐蚀行为[J].材料保护,2005,38(6):45-47,60.
【10】沈伟,吴玉萍,郭文敏,等.温度对高速电弧喷涂FeNiBSi/Cr3C2复合涂层热腐蚀性能的影响[J].焊接学报,2015,36(2):101-104.
【11】LI Z,CUI L,WANG J,et al.Preparation and properties of high hardness and oxidation resisting coating using electric arc spray[J].Transactions of Materials and Heat Treatment,2004,25(5):984-987.
【12】钱玲,吴玉萍,沈伟,等.高速电弧喷涂FeNiCrTiB/Cr3C2涂层的组织结构及其高温氧化行为[J].理化检验-物理分册,2014,50(5):334-337,340.
【13】徐维普,徐滨士,张伟,等.高速电弧喷涂技术在工程中的应用与展望[J].焊接技术,2004,33(1):18-19.
【14】徐维普,徐滨士.高速电弧喷涂FeAlCrNi/Cr3C2复合涂层的组织及高温性能[J].粉末冶金材料科学与工程,2008,13(6):340-345.
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