Influence of SO42- on Corrosion Behavior of X80 Steel in Simulated Acid Red Soil Solution
摘 要
采用动电位极化曲线、电化学阻抗谱(EIS)及三维视频显微镜技术研究了在酸性红壤模拟溶液中SO42-对X80管线钢腐蚀行为的影响。结果表明:随着酸性红壤模拟液中SO42-含量的增加,X80钢的腐蚀呈现出先减缓后明显加剧的趋势;在含5%(质量分数,下同)SO42-的模拟溶液中,X80钢的腐蚀失重量最低、腐蚀电流密度最小。结合EIS分析表明:SO42-的含量会影响X80钢的腐蚀行为,1%~5% SO42-会阻碍Cl-在电极表面的吸附,减缓腐蚀;高含量的SO42-会破坏电极表面膜的形成,使腐蚀加速。
Abstract
The influence of SO42- on corrosion behavior of X80 pipeline steel in simulated acid red soil solution was investigated by analysis of potentiodynamic polarization curve, electrochemical impedance spectroscopy (EIS) and three-dimensional video microscopy. The results show that the corrosion rate of X80 steel firstly decreased and then substantially increased with the increase of SO42- concentration; when the mass fraction of SO42- was 5%, the weight loss and the corrosion current density of X80 pipeline steel were minimum. EIS results show that the concentration of SO42- could affect the corrosion behavior of X80 steel. When the mass fraction of SO42- was 1%~5%, SO42- blocked the adsorption of Cl- on the electrode surface, and slowed down the corrosion; the concentration of SO42- could damaged the film forming on the electrode surface, and then accelerated the corrosion rate.
中图分类号 TG179 DOI 10.11973/fsyfh-201705001
所属栏目 管道防护技术
基金项目 国家自然科学基金项目(51161021)
收稿日期 2016/10/24
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联系人作者杜楠(d_unan@sina.com)
引用该论文: DENG Danping,DU Nan,WANG Shuaixing,HU Yanqing,WANG Liqiang. Influence of SO42- on Corrosion Behavior of X80 Steel in Simulated Acid Red Soil Solution[J]. Corrosion & Protection, 2017, 38(5): 327
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【4】LIU Z Y,ZHAI G L,DU C W,et al. Stress corrosion behavior of X70 pipeline steel in simulated solution of acid soil[J]. Acta Metall Sin,2008,44(2):209-214.
【5】XU C M,HUO C Y,XIONG Q R,et al. Corrosion behavior of X80 pipeline steel in simulated acid soil solution[J]. Mater Mech Eng,2009,33(5):29-32.
【6】易博,林德源,陈云翔,等. Cl-和SO42-对模拟混凝土孔隙液中钢筋腐蚀行为的影响[J]. 腐蚀科学与防护技术,2016,28(2):101-102.
【7】王海,李旺东,梁全胜,等. 温度、HCO3-和Cl-对J55钢在安塞油田采出水中腐蚀行为的影响[J]. 腐蚀科学与防护技术,2016,28(2):119-120.
【8】孙擎擎,周文辉,谢跃煌,等. 微量Cl-和温度对7150-T76铝合金电化学腐蚀性能的影响[J]. 中国腐蚀与防护学报,2016,36(2):122-129.
【9】HUANG I W,BELINDA L H,FAN Y,et al. Dependence on temperature, pH, and Cl- in the uniform corrosion of aluminum alloys 2024-T3, 6061-T6, and 7075-T6[J]. Electrochimica Acta,2016,199:251-252.
【10】卢云飞,阳靖峰,董俊华,等. NiCu低合金钢在含Cl-的除氧NaHCO3溶液中的腐蚀行为研究[J]. 金属学报,2015,51(4):440-442.
【11】张秀云,石志强,王彦芳,等. X100管线钢在盐渍土壤模拟溶液中的腐蚀行为[J]. 中国腐蚀与防护学报,2015,35(1):33-37.
【12】朴楠,陈吉,尹成江,等. 超细晶304L不锈钢在含Cl-溶液中点蚀行为的研究[J]. 金属学报,2015,51(9):1077-1083.
【13】魏亮,庞晓露,高克玮. X65钢在含超临界CO2的NaCl溶液中腐蚀机制的讨论[J]. 金属学报,2015,51(6):701-711.
【14】石志强,张秀云,王彦芳,等. SO42-对X100管线钢在盐渍性溶液中点蚀行为的影响[J]. 材料保护,2016,40(1):128-132.
【15】梁平,杜翠薇,李晓刚,等. SO42-对X80管线钢在含Cl-的NaHCO3溶液中点蚀行为影响[J]. 腐蚀与防护,2010,31(5):362-364.
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