高温高压CO2腐蚀环境中含Cr低合金钢耐蚀机理的研究进展
Research Progress of Corrosion Resistance Mechanism for Low Alloy Steels Containing Cr in High Temperature, High Pressure and CO2 Corrosion Environments
摘 要
阐述了含Cr低合金钢耐CO2腐蚀的机理，并介绍了如何通过极化曲线来确定含Cr低合金钢是否耐蚀的方法，同时也列举了含Cr低合金钢腐蚀产物膜沉积机制的最新进展，并提出了含Cr低合金钢耐蚀机理研究中亟待解决的问题。
CO2腐蚀
耐蚀机理
极化曲线
腐蚀产物膜
low alloy steel containing Cr
CO2 corrosion
corrosion resistance mechanism
polarization curve
corrosion product scale
Abstract
The corrosion resistance mechanism of low alloy steels containing Cr is summarized. The method of determining the corrosion resistance of low alloy steels containing Cr through polarization curves is introduced. The latest progress in the growth mechanism of corrosion product scales is listed. And the urgent issues of corrosion resistance mechanism research of low alloy steels containing Cr are put forward.
中图分类号 TG174.2 DOI 10.11973/fsyfh-201706010
所属栏目 专论
基金项目 国家科技支撑计划（2012BAK13B04）
收稿日期 2015/11/27
修改稿日期
网络出版日期
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引用该论文: ZHANG Jin,XU Lining,ZHU Jinyang,WANG Bei. Research Progress of Corrosion Resistance Mechanism for Low Alloy Steels Containing Cr in High Temperature, High Pressure and CO2 Corrosion Environments[J]. Corrosion & Protection, 2017, 38(6): 456
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参考文献
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【2】路民旭,白真权. 油气采集储运中的腐蚀现状及典型案例[J]. 腐蚀与防护,2002,23(3):105-113.
【3】陈长风,路民旭,赵国仙,等. N80钢CO2腐蚀产物膜研究[J]. 中国腐蚀与防护学报,2002,22(3):143-147.
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【5】郝敏,宋永臣. 利用CO2提高石油采收率技术研究现状[J]. 钻采工艺,2010,33(4):59-63.
【6】王彬,杜敏,张静. 油气田中抑制CO2腐蚀缓蚀剂的应用及其研究进展[J]. 腐蚀与防护,2010,31(7):503-507.
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【8】张忠铧,黄子阳,孙元宁,等. 3Cr抗CO2和H2S腐蚀系列油套管开发[J]. 宝钢技术,2006(3):5-8.
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【14】陈长风,路民旭,赵国仙,等. 腐蚀产物膜覆盖条件下油套管钢CO2腐蚀电化学特征[J]. 中国腐蚀与防护学报,2003,23(3):139-143.
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【16】陈太辉,许立宁,常炜,等. 耐CO2腐蚀低Cr管线钢的研究进展[J]. 腐蚀科学与防护技术,2011,23(5):451-452.
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【21】BOCKRIS J O M,DRAZIC D. The kinetics of deposition and dissolution of iron:effect of alloying impurities[J]. Electrochimica Acta,1962,7(3):293-313.
【22】GAO M,PANG X,GAO K. The growth mechanism of CO2 corrosion product films[J]. Corrosion Science,2011,53(2):557-568.
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【26】CHEN C F,LU M X,ZHAO G X,et al. The ion passing selectivity of CO2 corrosion scale on N80 tube steel[C]//Corrosion 2003. San Diego:NACE,2003:342.
【27】GUO S Q,XU L N,ZHANG L,et al. Corrosion of alloy steels containing 2% chromium in CO2 environments[J]. Corrosion Science,2012,63:246-258.
【28】ZHU J,XU L,LU M. Electrochemical impedance spectroscopy study of the corrosion of 3Cr pipeline steel in simulated CO2-saturated oilfield formation waters[J]. Corrosion,2015,71(7):854-864.
【29】陈太辉. 3% Cr管线钢CO2腐蚀的影响因素及耐蚀机理研究[D]. 北京:北京科技大学,2010.
【30】MURAKI T,HARA T,ASAHI H. Effects of chromium content up to 5% and dissolved oxygen on CO2 corrosion[C]//Corrosion 2002. Denver:NACE,2002:272.
【31】UEDA M,TAKABE H. The formation behavior of corrosion protective films of low Cr bearing steels in CO2 environments[C]//Corrosion 2001. Houston:NACE,2001:66.
【32】BROOKS A R,CLAYTON C R,DOSS K,et al. On the role of Cr in the passivity of stainless steel[J]. Journal of the Electrochemical Society,1986,133(12):2459-2464.
【33】王磊. CO2腐蚀产物膜微观结构与离子选择性研究[D]. 北京:中国石油大学,2007.
【34】许立宁,朱金阳,谢云,等. 含Cr管线钢的力学性能和耐蚀性能[J]. 北京科技大学学报,2014,36(2):200-205.
【35】XU L N,GUO S Q,GAO C L,et al. Influence of microstructure on mechanical properties and corrosion behavior of 3% Cr steel in CO2 environment[J]. Materials and Corrosion,2012,63(11):997-1003.
【36】GUO S Q,XU L N,CHANG W,et al. The anti-pitting mechanism of low Cr alloy steel in CO2 corrosion environment[C]//Corrosion 2012. Salt Lake City:NACE,2012:1357.
【37】ZHU J Y,XU L N,LU M X,et al. Interaction effect between Cr(OH)3 passive layer formation and inhibitor adsorption on 3Cr steel surface[J]. RSC Advances,2015,5(24):18518-18522.
【38】GULBRANDSEN E,NESIC S,STANGELAND A,et al. Effect of pre-corrosion on the performance of inhibitors for CO2 corrosion of carbon steel[C]//Corrosion 1998. Houston:NACE,1998:13.
【39】MULLIN J W. Crystallization[M]. 3版. 北京:世界图书出版社公司北京公司,2000:123-129.
【40】SÖHNEL O,MULLIN J W. Interpretation of crystallization induction periods[J]. Journal of Colloid and Interface Science,1988,123(1):43-50.
【41】TANTAYAKOM V,SREETHAWONG T,FOGLER H S,et al. Scale inhibition study by turbidity measurement[J]. Journal of Colloid and Interface Science,2005,284(1):57-65.
【42】NIELSEN A E. Kinetics of precipitation[M]. Oxford:Pergamon Press,1964.
【43】DRELA I,FALEWICZ P,KUCZKOWSKA S. New rapid test for evaluation of scale inhibitors[J]. Water Research,1998,32:3188-3191.
【44】DUGSTAD A. Mechanism of protective film formation during CO2 corrosion of carbon steel[C]//Corrosion 1998. San Diego:NACE,1998:31.
【45】CHOKSHI K,SUN W,NESIC S. Iron carbonate scale growth and the effect of inhibition in CO2 corrosion of mild steel[C]//Corrosion 2005. Houston:NACE,2005:285.
【2】路民旭,白真权. 油气采集储运中的腐蚀现状及典型案例[J]. 腐蚀与防护,2002,23(3):105-113.
【3】陈长风,路民旭,赵国仙,等. N80钢CO2腐蚀产物膜研究[J]. 中国腐蚀与防护学报,2002,22(3):143-147.
【4】NESIC S,NYBORG R,STANGELAND A,et al. Mechanistic modeling for CO2 corrosion with protective iron carbonate films[C]//Corrosion 2001. Houston:NACE,2001:40.
【5】郝敏,宋永臣. 利用CO2提高石油采收率技术研究现状[J]. 钻采工艺,2010,33(4):59-63.
【6】王彬,杜敏,张静. 油气田中抑制CO2腐蚀缓蚀剂的应用及其研究进展[J]. 腐蚀与防护,2010,31(7):503-507.
【7】潘一,孙林,杨双春,等. 国内外管道腐蚀与防护研究进展[J]. 腐蚀科学与防护技术,2014,26(1):77-80.
【8】张忠铧,黄子阳,孙元宁,等. 3Cr抗CO2和H2S腐蚀系列油套管开发[J]. 宝钢技术,2006(3):5-8.
【9】NOSE K,ASAHI H,NICE P I,et al. Corrosion properties of 3% Cr steels in oil and gas environments[C]//Corrosion 2001. Houston:NACE,2001:82.
【10】SMITH L M,JORDAN D E. Ensuring corrosion properties of CRA welds meet requirements for the oil and gas industry[C]//Corrosion 2003. San Diego:NACE,2003:91.
【11】LINNNE C P,BLANCHARD F,GUNTZ G C,et al. Corrosion performances of modified 13Cr for OCTG in oil and gas environments[C]//Corrosion 1997. New Orleans:NACE,1997:28.
【12】KERMANI B,GONZALES J C,TURCONI G L,et al. In-field corrosion performance of 3% Cr steels in sweet and sour downhole production and water injection[C]//Corrosion 2004. New Orleans:NACE,2004:111.
【13】孙建波,柳伟,路民旭. 成分和组织影响钢CO2腐蚀的研究进展[J]. 中国腐蚀与防护学报,2008,28(4):246-248.
【14】陈长风,路民旭,赵国仙,等. 腐蚀产物膜覆盖条件下油套管钢CO2腐蚀电化学特征[J]. 中国腐蚀与防护学报,2003,23(3):139-143.
【15】胡丽华,俞曼丽,常炜,等. Cr含量对低合金管线钢CO2腐蚀性能的影响[J]. 腐蚀科学与防护技术,2011,23(3):256-260.
【16】陈太辉,许立宁,常炜,等. 耐CO2腐蚀低Cr管线钢的研究进展[J]. 腐蚀科学与防护技术,2011,23(5):451-452.
【17】ZHANG G A,CHENG Y F. Corrosion of X65 steel in CO2-saturated oilfield formation water in the absence and presence of acetic acid[J]. Corrosion Science,2009,51(8):1589-1595.
【18】PALACIOS C A,SHADLEY J R. CO2 corrosion of N80 steel at 71℃ in a two-phase flow system[J]. Corrosion,1993,49(8):686-693.
【19】OGUNDELE G I,WHITE W E. Some observations on corrosion of carbon steel in aqueous environments containing carbon dioxide[J]. Corrosion,1986,42(2):71-78.
【20】CHENG Y F,NIU L. Mechanism for hydrogen evolution reaction on pipeline steel in near-neutral pH solution[J]. Electrochemistry Communications,2007,9(4):558-562.
【21】BOCKRIS J O M,DRAZIC D. The kinetics of deposition and dissolution of iron:effect of alloying impurities[J]. Electrochimica Acta,1962,7(3):293-313.
【22】GAO M,PANG X,GAO K. The growth mechanism of CO2 corrosion product films[J]. Corrosion Science,2011,53(2):557-568.
【23】DUGSTAD A. Fundamental aspects of CO2 metal loss corrosion-part 1:mechanism[C]//Corrosion 2006. San Diego:NACE,2006:111.
【24】CHEN C F,LU M X,SUN D B,et al. Effect of chromium on the pitting resistance of oil tube steel in a carbon dioxide corrosion system[J]. Corrosion,2005,61(6):594-601.
【25】CHEN T H,XU L N,LU M X,et al. Study on factors affecting low Cr alloy steels in a CO2 corrosion system[C]//Corrosion 2011. Houston:NACE,2011:74.
【26】CHEN C F,LU M X,ZHAO G X,et al. The ion passing selectivity of CO2 corrosion scale on N80 tube steel[C]//Corrosion 2003. San Diego:NACE,2003:342.
【27】GUO S Q,XU L N,ZHANG L,et al. Corrosion of alloy steels containing 2% chromium in CO2 environments[J]. Corrosion Science,2012,63:246-258.
【28】ZHU J,XU L,LU M. Electrochemical impedance spectroscopy study of the corrosion of 3Cr pipeline steel in simulated CO2-saturated oilfield formation waters[J]. Corrosion,2015,71(7):854-864.
【29】陈太辉. 3% Cr管线钢CO2腐蚀的影响因素及耐蚀机理研究[D]. 北京:北京科技大学,2010.
【30】MURAKI T,HARA T,ASAHI H. Effects of chromium content up to 5% and dissolved oxygen on CO2 corrosion[C]//Corrosion 2002. Denver:NACE,2002:272.
【31】UEDA M,TAKABE H. The formation behavior of corrosion protective films of low Cr bearing steels in CO2 environments[C]//Corrosion 2001. Houston:NACE,2001:66.
【32】BROOKS A R,CLAYTON C R,DOSS K,et al. On the role of Cr in the passivity of stainless steel[J]. Journal of the Electrochemical Society,1986,133(12):2459-2464.
【33】王磊. CO2腐蚀产物膜微观结构与离子选择性研究[D]. 北京:中国石油大学,2007.
【34】许立宁,朱金阳,谢云,等. 含Cr管线钢的力学性能和耐蚀性能[J]. 北京科技大学学报,2014,36(2):200-205.
【35】XU L N,GUO S Q,GAO C L,et al. Influence of microstructure on mechanical properties and corrosion behavior of 3% Cr steel in CO2 environment[J]. Materials and Corrosion,2012,63(11):997-1003.
【36】GUO S Q,XU L N,CHANG W,et al. The anti-pitting mechanism of low Cr alloy steel in CO2 corrosion environment[C]//Corrosion 2012. Salt Lake City:NACE,2012:1357.
【37】ZHU J Y,XU L N,LU M X,et al. Interaction effect between Cr(OH)3 passive layer formation and inhibitor adsorption on 3Cr steel surface[J]. RSC Advances,2015,5(24):18518-18522.
【38】GULBRANDSEN E,NESIC S,STANGELAND A,et al. Effect of pre-corrosion on the performance of inhibitors for CO2 corrosion of carbon steel[C]//Corrosion 1998. Houston:NACE,1998:13.
【39】MULLIN J W. Crystallization[M]. 3版. 北京:世界图书出版社公司北京公司,2000:123-129.
【40】SÖHNEL O,MULLIN J W. Interpretation of crystallization induction periods[J]. Journal of Colloid and Interface Science,1988,123(1):43-50.
【41】TANTAYAKOM V,SREETHAWONG T,FOGLER H S,et al. Scale inhibition study by turbidity measurement[J]. Journal of Colloid and Interface Science,2005,284(1):57-65.
【42】NIELSEN A E. Kinetics of precipitation[M]. Oxford:Pergamon Press,1964.
【43】DRELA I,FALEWICZ P,KUCZKOWSKA S. New rapid test for evaluation of scale inhibitors[J]. Water Research,1998,32:3188-3191.
【44】DUGSTAD A. Mechanism of protective film formation during CO2 corrosion of carbon steel[C]//Corrosion 1998. San Diego:NACE,1998:31.
【45】CHOKSHI K,SUN W,NESIC S. Iron carbonate scale growth and the effect of inhibition in CO2 corrosion of mild steel[C]//Corrosion 2005. Houston:NACE,2005:285.
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