Galvanic Corrosion and Electrical Insulation between High Strength Steel and Typical Piping Materials B10 and TA2
摘 要
采用电偶腐蚀试验研究了某高强钢与铜镍合金(B10)和工业纯钛(TA2)在面积比为1:1条件下的电偶腐蚀倾向以及腐蚀程度,通过改变两电偶对材料间串联绝缘电阻值,研究绝缘电阻对电偶腐蚀的影响规律。结果表明:高强钢与典型管系材料B10和TA2在海水中具有较强的电偶腐蚀倾向,偶接后高强钢作为阳极,腐蚀加剧;试验条件下,两电偶对材料间绝缘电阻高于10 kΩ时,可有效控制电偶腐蚀的发生。
Abstract
Galvanic corrosion test was used to study the corrosion tendency and the extent of corrosion of high strength steel contacted with copper-nickel alloy (B10) or commercially pure titanium (TA2) at the area ratio of one to one.By gradually increasing the resistance between two galvanic materials,the influence rule of insulation resistance on galvanic corrosion was studied.The results show that the high-strength steel had an obvious galvanic corrosion tendency no matter it was contacted with B10 or TA2 in seawater,and the corrosion of high strength steel as an anode was aggravated after coupling.In the condition of test,galvanic corrosion rate of high strength steel decreased with the galvanic insulation resistance increasing,when the galvanic insulation resistance value between the two basic materials was higher than 10 kΩ,the extent of galvanic corrosion was controled effectively.
中图分类号 TG172 DOI 10.11973/fsyfh-201708004
所属栏目 试验研究
基金项目 海洋腐蚀与防护国防科技重点实验室基金项目(XK20140401)
收稿日期 2015/12/1
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引用该论文: PAN Dawei,YAN Yonggui,GAO Xinxin,LIU feng,LI Xiangbo. Galvanic Corrosion and Electrical Insulation between High Strength Steel and Typical Piping Materials B10 and TA2[J]. Corrosion & Protection, 2017, 38(8): 589
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参考文献
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【6】孙保库,杜敏,李相波,等. 铜镍合金B10和黄铜H62在海水中的电偶腐蚀及电绝缘研究[J]. 装备环境工程,2009,6(2):22-26.
【7】王虹斌,方志刚. 舰船海水管系异金属电偶腐蚀的控制[J]. 腐蚀科学与防护技术,2007,19(2):145-147.
【8】陈世红. 海水管系电绝缘技术的应用[J]. 广船科技,2004(4):37-38.
【9】金蓓,沈伟杰. 舰船海水管系电绝缘技术[J]. 机电设备,2006(5):28-30.
【10】王虹斌,方志刚. 舰船海水管系异金属电偶腐蚀的控制[J]. 腐蚀科学与防护技术,2007,19(2):145-147.
【11】林乐耘,徐杰,赵月红. 国产B10铜镍合金腐蚀行为研究[J]. 中国腐蚀与防护学报,2000,20(6):361-367.
【12】CROUSIER J,BECCARIA A M. Behaviors of Cu-Ni alloys in natural sea water and NaCl solution[J]. Werkstoffe and Corrosion,1990,41(4):185-190.
【13】SEWART W C,LAQUE F L. Corrosion resisting characteristics of iron modified cupro-nickel alloy[J]. Corrosion,1952,8(8):259-277.
【14】CONTU F,ELSENER B,BOHNI H. Serum effect on the electrochemical behaviour of titanium,Ti6Al4V and Ti6Al7Nb alloys in sulphuric acid and sodium hydroxide[J]. Corrosion Science,2004,46(9):2241-2254.
【15】BROSSIA C S,CRAGNOLINO G A,BROSSIA C S,et al. Effect of palladium on the corrosion behavior of titanium[J]. Corrosion Science,2004,46(7):1693-1711.
【16】SCHULTZE J W,LOHRENGEL M M. Stability,reactivity and breakdown of passive films. Problems of recent and future research[J]. Electrochimica Acta,2000,45(15):2499-2513.
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