ICP-AES Determination of Potassium in Oil Field Oil Sludge
摘 要
采用电感耦合等离子体原子发射光谱法测定油田含油污泥中钾的含量。采用索氏提取法分离油田含油污泥样品中的水、油、渣(加热回流时间为当萃取液澄清后继续回流1 h),再用盐酸、硝酸、氢氟酸和高氯酸消解剩余残渣。钾的质量浓度在1.0~80 mg·L-1内与其对应的发射强度呈线性关系,检出限(3s)为3.03 μg·L-1。以ZW站和T83站的含油污泥样品为基体进行加标回收试验,所得回收率分别为98.4%,102%,测定值的相对标准偏差(n=5)分别为0.69%,0.63%。
Abstract
ICP-AES was applied to the determination of potassium in oil field oil sludge. The water,oil and slag in the oil field oil sludge sample were separated with Soxhlet extraction (heating reflux time found was 1 h after clarification of the extract), and then the slag was digested with hydrochloric acid, nitric acid, hydrofluoric acid and perchloric acid. Linear relationship between values of emission intensity and mass concentration of potassium was obtained in the range of 1.0-80 mg·L-1, with detection limit (3s) of 3.03 μg·L-1. On the base of oil sludge samples from station of ZW and T83, test for recovery was made by standard addition method and values of recovery found were 98.4%, 102% respectively, with RSD's (n=5) of 0.69%, 0.63% respectively.
中图分类号 O657.31 DOI 10.11973/lhjy-hx201708006
所属栏目 工作简报
基金项目 中石化江苏油田科研项目(JS15020);扬州市-扬州大学合作基金项目(2014-1);江苏省前瞻性联合研究项目(BY2015061-09)
收稿日期 2016/8/10
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备注郭鹏(1972-),男,山东曹县人,高级工程师,主要从事油田化学及污水、污泥处理、防腐、防垢等技术研究,guopeng.jsyt@sinopec.com
引用该论文: GUO Peng,TENG Zhenyuan,LIU Songlin,WANG Chengyin,LIN Gang,ZHUANG Jianquan. ICP-AES Determination of Potassium in Oil Field Oil Sludge[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2017, 53(8): 894~897
郭鹏,滕镇远,刘松林,王赪胤,林刚,庄建全. 电感耦合等离子体原子发射光谱法测定油田含油污泥中钾[J]. 理化检验-化学分册, 2017, 53(8): 894~897
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参考文献
【1】刘志林,完石光,于莹.石化含油污泥的资源化利用[J].环境保护与循环经济, 2010(12):58-61.
【2】金浩,石丰,刘鹏,等.含油污泥的干燥研究[J].石油与天然气化工, 2011,40(5):522-526.
【3】HU G J, LI J B, ZENG G M. Recent development in the treatment of oily sludge from petroleum industry:A review[J]. J Hazard Mater, 2013,261(8):470-490.
【4】ZHANG J, LI J B, THRING R W, et al. Oil recovery from refinery oily sludge via ultrasound and freeze/thaw[J]. J Hazard Mater, 2012,203/204:195-203.
【5】OUYANG W, LIU H, MURYGINA V, et al. Comparison of bio-augmentation and composting for remediation of oily sludge:A field-scale study in China[J]. Process Biochem, 2005,40(12):3763-3768.
【6】JANSSENS F, PEERERS A, TALLOWIN J R B, et al. Relationship between soil chemical factors and grassland diversity[J]. Plant Soil, 1998,202(1):69-78.
【7】沈瑞之.钾对植物的生理作用[J].上海农业科技, 1982(5):32-34.
【8】PAL P K, KUMAR R, GULERIA V, et al. Crop-ecology and nutritional variability influence growth and secondary metabolites of stevia rebaudiana bertoni[J]. BMC Plant Biology, 2015,15(67):3-16.
【9】朱嘉卉.含油污泥的理化特性研究与分析[D].杭州:浙江大学, 2014.
【10】LEHOTAY S J, COOKJ J M. Sampling and sample processing in pesticide residue analysis[J]. Agric Food Chem, 2015,63(18):4395-4404.
【11】齐文启,汪志国,孙宗光.土壤污染分析中样品采集与前处理方法探讨[J].现代科技论文, 2007(1):55-58.
【12】JOHN W O. Elemental analysis using ICP-OES and ICP/MS[J]. Anal Chem, 1991,63(1):12-21.
【2】金浩,石丰,刘鹏,等.含油污泥的干燥研究[J].石油与天然气化工, 2011,40(5):522-526.
【3】HU G J, LI J B, ZENG G M. Recent development in the treatment of oily sludge from petroleum industry:A review[J]. J Hazard Mater, 2013,261(8):470-490.
【4】ZHANG J, LI J B, THRING R W, et al. Oil recovery from refinery oily sludge via ultrasound and freeze/thaw[J]. J Hazard Mater, 2012,203/204:195-203.
【5】OUYANG W, LIU H, MURYGINA V, et al. Comparison of bio-augmentation and composting for remediation of oily sludge:A field-scale study in China[J]. Process Biochem, 2005,40(12):3763-3768.
【6】JANSSENS F, PEERERS A, TALLOWIN J R B, et al. Relationship between soil chemical factors and grassland diversity[J]. Plant Soil, 1998,202(1):69-78.
【7】沈瑞之.钾对植物的生理作用[J].上海农业科技, 1982(5):32-34.
【8】PAL P K, KUMAR R, GULERIA V, et al. Crop-ecology and nutritional variability influence growth and secondary metabolites of stevia rebaudiana bertoni[J]. BMC Plant Biology, 2015,15(67):3-16.
【9】朱嘉卉.含油污泥的理化特性研究与分析[D].杭州:浙江大学, 2014.
【10】LEHOTAY S J, COOKJ J M. Sampling and sample processing in pesticide residue analysis[J]. Agric Food Chem, 2015,63(18):4395-4404.
【11】齐文启,汪志国,孙宗光.土壤污染分析中样品采集与前处理方法探讨[J].现代科技论文, 2007(1):55-58.
【12】JOHN W O. Elemental analysis using ICP-OES and ICP/MS[J]. Anal Chem, 1991,63(1):12-21.
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