Preparation and Properties of Nitrile Rubber Composite
摘 要
通过物理共混法制备出各组分分散均匀的丁腈橡胶复合材料,研究了硫化剂、防老剂、耐寒增塑剂的种类及用量对丁腈橡胶复合材料性能的影响。结果表明:当防老剂体系为4010NA/RD/AW/NBC/石蜡,用量分别为1,1,1.5,2,1 质量份时,丁腈橡胶复合材料具有优异的耐热空气和耐臭氧老化性能;当耐寒增塑剂为DOA且其用量为6 质量份时,丁腈橡胶复合材料具有良好的耐低温和耐油老化性能;采用复合硫化体系DCP/S/DM/CZ且用量分别为2.5,0.5,0.3,0.5 质量份时,丁腈橡胶复合材料的耐热空气老化和耐低温性能较好;当NBR(35%)/NBR(26%)、ZnO、SA、N550、S、DM、CZ、DCP、DOA、4010NA、RD、NBC、AW、石蜡的加入量分别为50/50,5,1.5,60,0.5,0.3,0.5,2.5,6,1.5,1,1,1.5,1质量份时,丁腈橡胶复合材料具有优异的综合性能。
Abstract
The nitrile rubber composites with component dispersed uniformly was prepared by physical blending method. The effect of vulcanizing agent, antioxidant and cold-resistant plasticizer on the properties of nitrile rubber composite was studied. The results show that when the antioxidant system was 4010NA/RD/AW/NBC/paraffin and dosages were 1, 1, 1.5, 2, 1 phr, respectively, nitrile rubber composite had excellent hot air and ozone aging resistance. When the cold-resistant plasticizer was DOA and its dosage was 6 phr, nitrile rubber composite had excellent low temperature resistance and good oil resistance. When the compound vulcanization system DCP/S/DM/CZ was used and dosages were 2.5, 0.5, 0.3, 0.5 phr, respectively, nitrile rubber composite had better hot air aging resistance and low temperature resistance. When the dosages of NBR (35%)/NBR (26%), ZnO, SA, N550, S, DM, CZ, DCP, DOA, 4010NA, RD, NBC, AW, paraffin were 50/50, 5, 1.5, 60, 0.5, 0.3, 0.5, 2.5, 6, 1.5, 1, 1, 1.5, 1 phr, nitrile rubber composites had the excellent comprehensive properties.
中图分类号 TQ333.7 DOI 10.11973/jxgccl201709011
所属栏目 新材料 新工艺
基金项目
收稿日期 2016/12/20
修改稿日期 2017/8/1
网络出版日期
作者单位点击查看
备注陈永军(1988-),男,河南信阳人,硕士研究生
引用该论文: CHEN Yongjun,ZOU Hua,WU Shemao,ZHANG Liqun. Preparation and Properties of Nitrile Rubber Composite[J]. Materials for mechancial engineering, 2017, 41(9): 61~67
陈永军,邹华,伍社毛,张立群. 丁腈橡胶复合材料的制备与性能[J]. 机械工程材料, 2017, 41(9): 61~67
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参考文献
【1】王立彦.丁腈橡胶的应用[J].弹性体,2000,10(3),41-44.
【2】谢遂志,刘登祥,周鸣峦.橡胶工业手册第一分册:生胶与骨架材料[M].北京:化学工业出版社,1989:387-476.
【3】于清溪.橡胶老化及防老化体系配合的优化设计[J].世界橡胶工业,2014,41(1):1-4.
【4】谢彦飞,张友南,唐先贺,等.耐寒丁腈橡胶密封制品配方的研究[J].特种橡胶制品,2004,25(5):15-19.
【5】赵艳芳,王久模,赵银梅,等. 丁腈橡胶共混改性研究概况[J]. 弹性体,2011,21(1):89-97.
【6】LIU H, ZHANG X D, ZHU X G. Influence of the rubber particle spatial distribution in poly(vinylchloride)/nitrile rubber blends[J].Polymer,1998,39(21):5035-5045.
【7】IBNELWALEED A. Study of the miscibility and mechanical properties of NBC/HNBR blends[J]. Polymer Engineering and Science, 2004, 44(12):2346-2352.
【8】HASHIMOTO K, TODANIO Y. Handbook of elastomers[M]. New York:Marcel Dekker Inc. 1988:741-757.
【9】王志远.丁腈橡胶的配合和并用研究[D].广州:广东工业大学,2006.
【10】郑长伟.日本瑞翁公司氢化丁腈橡胶的性能及应用介绍[J].橡胶工业,1995,42(6):342-344.
【11】廖俊杰,陈福林,岑兰,等.丁腈橡胶的应用研究进展[J].特种橡胶制品,2007,28(5):41-45.
【2】谢遂志,刘登祥,周鸣峦.橡胶工业手册第一分册:生胶与骨架材料[M].北京:化学工业出版社,1989:387-476.
【3】于清溪.橡胶老化及防老化体系配合的优化设计[J].世界橡胶工业,2014,41(1):1-4.
【4】谢彦飞,张友南,唐先贺,等.耐寒丁腈橡胶密封制品配方的研究[J].特种橡胶制品,2004,25(5):15-19.
【5】赵艳芳,王久模,赵银梅,等. 丁腈橡胶共混改性研究概况[J]. 弹性体,2011,21(1):89-97.
【6】LIU H, ZHANG X D, ZHU X G. Influence of the rubber particle spatial distribution in poly(vinylchloride)/nitrile rubber blends[J].Polymer,1998,39(21):5035-5045.
【7】IBNELWALEED A. Study of the miscibility and mechanical properties of NBC/HNBR blends[J]. Polymer Engineering and Science, 2004, 44(12):2346-2352.
【8】HASHIMOTO K, TODANIO Y. Handbook of elastomers[M]. New York:Marcel Dekker Inc. 1988:741-757.
【9】王志远.丁腈橡胶的配合和并用研究[D].广州:广东工业大学,2006.
【10】郑长伟.日本瑞翁公司氢化丁腈橡胶的性能及应用介绍[J].橡胶工业,1995,42(6):342-344.
【11】廖俊杰,陈福林,岑兰,等.丁腈橡胶的应用研究进展[J].特种橡胶制品,2007,28(5):41-45.
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