Anticorrosion Effects of EB104/EB202 Coating on 904L Stainless Steel
摘 要
通过点蚀试验、缝隙腐蚀试验和盐雾试验,研究了904L不锈钢表面未涂覆、半涂覆和全涂覆EB104/EB202涂层试样在不同含量的FeCl3溶液中的腐蚀行为。结果表明:随着FeCl3含量的增加,未涂覆EB104/EB202涂层试样的点蚀程度和缝隙腐蚀程度不断加剧。对于半涂覆EB104/EB202涂层试样,其缝隙区、未涂覆区和涂覆区的腐蚀程度依次降低;缝隙区出现严重的点蚀和缝隙腐蚀,且腐蚀程度也随着FeCl3含量的增加而加剧。全涂覆EB104/EB202涂层试样具有良好的耐点蚀、缝隙腐蚀和盐雾腐蚀性能。
Abstract
Using pitting corrosion, crevice corrosion and salt-spray tests, the corrosion behavior of 904L stainless steel samples with the surfaces uncoated, half-coated and full-coated with EB104/EB202 was investigated in FeCl3 solution with different FeCl3 concentrations. The results show that the corrosion degree of the EB104/EB202 uncoated samples became worse with the increase of FeCl3 concentration both in pitting corrosion and in crevice corrosion. For the EB104/EB202 half-coated samples, the corrosion degree declined in the crevice zone, uncoated zone and full-coated zone in sequence. Pitting and crevice corrosion appeared together in the crevice zone, and the corrosion degree of the half-coated samples also became worse with the increase of FeCl3 concentration. The EB104/EB202 full-coated samples exhibited good resistance to pitting corrosion, crevice corrosion and salt-spray corrosion.
中图分类号 TG174 DOI 10.11973/fsyfh-201710001
所属栏目 试验研究
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收稿日期 2017/6/22
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引用该论文: HUANG Dejun,WANG Shaowei,LI Chengtao,WU Xiangfeng,LUO Yue,FANG Kewei. Anticorrosion Effects of EB104/EB202 Coating on 904L Stainless Steel[J]. Corrosion & Protection, 2017, 38(10): 741
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参考文献
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【6】饶丹,杜学武,李孝华. 贝尔佐纳高分子修复材料在真空泵修复中的应用[J]. 安徽化工,2003(4):37-38.
【7】张丛,张超. 高分子修复技术在蝶阀密封面修复中的应用[J]. 中国电业(技术版),2015(5):43-45.
【8】HOAR T P,MEARS D C,ROTHWELL G P. The relationships between anodic passivity,brightening and pitting[J]. Corrosion Science,1965,5(4):279-289.
【9】STREHBLOW H H. Nucleation and repassivation of corrosion pits for pitting on iron and nickel[J]. Materials and Corrosion,1976,27(11):792-799.
【10】MARCUS P,HERBELIN J M. The entry of chloride ions into passive films on nickel studied by spectroscopic (ESCA) and nuclear (36Cl radiotracer) methods[J]. Corrosion Science,1993,34(7):1123-1145.
【11】潘莹,张三平,周建龙,等. 金属材料点蚀形核过程研究进展[J]. 装备环境工程,2010,7(4):67-70.
【12】MARCUS P,MAURICE V,STREHBLOW H H. Localized corrosion (pitting):a model of passivity breakdown including the role of the oxide layer nanostructure[J]. Corrosion Science,2008,50(9):2698-2704.
【13】ZHENG S J,WANG Y J,ZHANG B,et al. Identification of MnCr2O4 nano-octahedron in catalyzing pitting corrosion of austenitic stainless steels[J]. Acta Materialia,2010,58(15):5070-5085.
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【15】WANG Y F,CHENG G X,WU W,et al. Effect of pH and chloride on the micro-mechanism of pitting corrosion for high strength pipeline steel in aerared NaCl solutions[J]. Applied Surface Science,2015,349(15):746-756.
【16】石林,郑志军,高岩. 不锈钢的点蚀机理及研究方法[J]. 材料导报,2015,29(23):79-85.
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